• Resources Recycling
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• v.17 no.3
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• pp.29-34
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• 2008

Solvent extraction behaviors of iron(III) from chloride solution at high ionic strength condition between Alamine336 and TBP were compared by using MaCabe-Thiele diagram. Extraction isotherms of iron by the two extractants were obtained by calculating the equilibrium concentrations of iron in both phases from the initial extraction conditions. In calculating the equilibrium concentration of iron, chemical equilibria in the aqueous phase and mass balance together with the solvent extraction reaction were considered. MaCabe-Thiele diagram of iron by 1M Alamine336 indicated that two extraction stages could lead to complete extraction of 0.5M iron from 3M HCl solution at an A/O ratio of 6/5. The extraction power of 1M Alamine336 was found to be the same as 2-3M TBP. MaCabe-Thiele diagram together with the physical properties of the two extractants indicated that Alamine336 is superior to TBP in extracting ferric iron from chloride solution.

• 제어로봇시스템학회:학술대회논문집
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• 1988.10a
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• pp.466-470
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• 1988

A tunable reduced-order distillation model is proposed for real-time applications. To develop the model, a binary distillation column with MaCabe-Thiele assumptions was considered first and then the governing equations for the column were reduced to a simplified vector differential equations using the collocation method combined with cubic spline interpolation function. The final reduced-order model has four tuning parameters, relative volatilities and liquid holdups for rectifying and stripping sections, respectively. To assess the applicability of the developed model,the real-time adjustment of the model was tried by recursively updating the tuning parameters using the BKF algorithm. As a result, it was found that the reduced-model follows the simulated distillation process very closely as the parameters are improved.