• Title/Summary/Keyword: MO theoretical study

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The ground reaction curve of underwater tunnels considering seepage forces (침투력을 고려한 터널의 지반반응곡선)

  • Shin, Young-Jin;Kim, Byoung-Min;Shin, Jong-Ho;Lee, In-Mo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.9 no.2
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    • pp.183-204
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    • 2007
  • When a tunnel is excavated below groundwater table, the groundwater flows into the excavated wall of tunnel and seepage forces are acting on the tunnel wall. Such seepage forces significantly affect the ground reaction curve which is defined as the relationship between internal pressure and radial displacement of tunnel wall. In this paper, seepage forces arising from the ground water flow into a tunnel were estimated quantitatively. Magnitude of seepage forces was decided based on hydraulic gradient distribution around tunnel. Using these results, the theoretical solutions of ground reaction curve with consideration of seepage forces under steady-state flow were derived. A no-support condition and a supported condition with grouted bolts and shotcrete lining were considered, respectively. The theoretical solution derived in this study was validated by numerical analysis. The changes in the ground reaction curve according to various cover depths and groundwater table conditions were investigated. Based on the results, the application limit of theoretical solutions was suggested.

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Theoretical Study on Antitumor Activity of trans-Platinum(Ⅱ) Complexes with Planar Ligands (Ⅱ) (평면형리간드가 배위된 trans-백금(Ⅱ) 착물의 항암활성에 관한 이론적 연구 (제2보))

  • Song, Young Dae;Kim, Jung Sung;Park, Byung Kak
    • Journal of the Korean Chemical Society
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    • v.41 no.6
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    • pp.277-283
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    • 1997
  • Platinum(II) complexes(where, $[Pt(L)_2X_2]$; L=isoxazole(isox), 3,5-dimethylisoxazole(3,5-diMeisox), 3-methyl,5-phenylisoxazole(3-Me,5-Phisox), and 4-amino-3,5-dimethylisoxazole(4-ADI); X=Cl, Br) with planar ligands are investigated on antitumor activity by MM2 and EHMO calculations. It was found that, the net atomic charges of the halogen atoms in all of cis-, trans-isomers are greater than that of the nitrogen with planar form, indicating that ionic character of Pt-X bond is greater than that of Pt-N. Also, the ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of the interaction between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of X found to be higher than that of between $d_{x2-y2}$ orbital of Pt atom and $p_x$ orbital of N about all the complexes. It is found that bond strength of between Pt and X atom is weaker than that of between Pt and N atom. The ${\sigma}MO$ energy level($E{\sigma}_{(Pt-X)}$) of trans- complexes found to be higher than that of cis- complexes, as a result of bond strength of Pt-X in cis- and trans-complexes, for all the complexes. The degree of dissociation of X atom in Pt-X bond for trans-complexes are related to antitumor activity and the logIA value of inhibitory activity coefficient(IA).

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Nature of the Interfacial Regions in the Antiferromagnetically-coupled Fe/Si Multilayered Films

  • Moon, J.C.;Y.V. Kudryavtsev;J.Y.Rhee;Kim, K.W.;Lee, Y.P.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.174-174
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    • 2000
  • A strong antiferromagnetic coupling in Fe/Si multilayered films (MLF) had been recently discovered and much consideration has been given to whether the coupling in the Fe/Si MLF system has the same origin as the metal/metal MLF. Nevertheless, the nature of the interfacial ron silicide is still controversial. On one hand, a metal/ semiconductor structure was suggested with a narrow band-gap semiconducting $\varepsilon$-FeSi spacer that mediates the coupling. However, some features show that the nature of coupling can be well understood in terms of the conventional metal/metal multilayered system. It is well known that both magneto-optical (MO) and optical properties of a metal depend strongly on their electronic structure that is also correlated with the atomic and chemical ordering. In this study, the nature of the interfacial regions is the Fe/Si multilayers has been investigated by the experimental and computer-simulated MO and optical spectroscopies. The Fe/Si MLF were prepared by rf-sputtering onto glass substrates at room temperature with the number of repetition N=50. The thickness of Fe sublayer was fixed at 3.0nm while the Si sublayer thickness was varied from 1.0 to 2.0 nm. The topmost layer of all the Fe/Si MLF is Fe. In order to carry out the computer simulations, the information on the MO and optical parameters of the materials that may constitute a real multilayered structure should be known in advance. For this purpose, we also prepared Fe, Si, FeSi2 and FeSi samples. The structural characterization of Fe/Si MLF was performed by low- and high -angle x-ray diffraction with a Cu-K$\alpha$ radiation and by transmission electron microscopy. A bulk $\varepsilon$-FeSi was also investigated. The MO and optical properties were measured at room temperature in the 1.0-4.7 eV energy range. The theoretical simulations of MO and optical properties for the Fe/Si MLF were performed by solving exactly a multireflection problem using the scattering matrix approach assuming various stoichiometries of a nonmagnetic spacer separating the antiferromagnetically coupled Fe layers. The simulated spectra of a model structure of FeSi2 or $\varepsilon$-FeSi as the spacer turned out to fail in explaining the experimental spectra of the Fe/Si MLF in both intensity and shape. Thus, the decisive disagreement between experimental and simulated MO and optical properties ruled out the hypothesis of FeSi2 and $\varepsilon$-FeSi as the nonmagnetic spacer. By supposing the spontaneous formation of a metallic ζ-FeSi, a reasonable agreement between experimental and simulated MO and optical spectra was obtained.

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A Study on Zirconia/Metal.Functionally Gradient Materials by Sintering Method(1) (소결법에 의한 $ZrO_2/Metal$계 경사기능재료에 관한 연구(1))

  • 정연길;최성철
    • Journal of the Korean Ceramic Society
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    • v.31 no.3
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    • pp.321-329
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    • 1994
  • Functionally gradient materials(FGM), which have the continuous or stepwise variation in a composition and microstructure, are being noticed as the material that solves problems caused by heterogeneous interface of coating or joining. And these materials also expect new functions occured by gradient composition itself. Therefore, to examine possibility of thermal barrier materials, TZP/Mo·FGM and TZP/Ni·FGM were fabricated by sintering method. As to the sintered specimens, sintering shrinkage, relative density and Vicker's hardness in each composition were examined. The phenomena due to the difference of sintering shrinkage velocity during sintering process and the thermal stress induced through differences of thermal expansion coefficient in FGM were discussed. And the structure changes at interface and microsturcture of FGM were investigated. As a results, the difference of shrinkage between ceramic and metal was about 14% in TZP/Mo and 7% in TZP/Ni. The relative density and hardness were considerably influenced by metal content changes. Owing to unbalance of sintering shrinkage velocity between ceramic and metal, various sintering defects were occured. To control these sintering defects and thermal stress, gradient composition of FGM should be narrow. The microstructure changes of FGM depended on the ceramic or metal volume percents and were analogous to the theoretical design.

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The Effect of Seepage Forces on the Ground Reaction Curve of Tunnel (침투력이 터널의 지반반응곡선에 미치는 영향)

  • Lee Seok-Won;Jung Jong-Won;Nam Seok-Woo;Lee In-Mo
    • Journal of the Korean Geotechnical Society
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    • v.21 no.3
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    • pp.87-98
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    • 2005
  • When a tunnel is excavated below groundwater table, the groundwater flows into the excavated wall of tunnel and seepage forces are acting on the tunnel wall. The ground reaction curve is defined as the relationship between internal pressure and radial displacement of tunnel wall. Therefore, the ground reaction curve is significantly affected by seepage forces. In this study, the theoretical solutions of ground reaction curves were derived for both the dry condition and the seepage forces. The theoretical solutions derived were validated by numerical analysis. The ground reaction curves with the support characteristic curve were also analyzed in various conditions of groundwater table. Finally, the theoretical solutions of the ground reaction curve derived in this study can be utilized easily to determine the appropriate time of support systems, the stiffness of support system and so forth for the reasonable design.

Behavior of Grouted Bolts in Consideration of Seepage Forces (침투수력을 고려한 전면접착형 록볼트의 거동연구)

  • Lee, In-Mo;Kim, Kyung-Hwa;Shin, Jong-Ho;Park, Jong-Kwan
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.1259-1266
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    • 2005
  • In a NATM tunnel, fully grouted bolts are widely used as part of supporting system. Grouted bolts play an important role not as to take some parts of load acting on a tunnel lining but as to reinforce the ground adjacent the tunnel. In conjunction with tunnel construction, the presence of groundwater may pose a number of difficulties. With respect to tunnel design, influences of groundwater on tunnel behavior have been considered in many aspects. However, the effect on grouted bolts has been rarely investigated. In this study, the behavior of grouted bolts, which are affected by the seepage forces, was examined. To investigate the effects of seepage forces, the theoretical solutions for a drained condition were also found. Based on the theoretical solutions, ground reaction curves considering seepage forces were obtained. By comparing the ground reaction curves supported by grouted bolts with those for the unsupported cases, the effect of reinforcement was evaluated. Finally, through comparison between supported ground reaction curves in the drained condition and those in the case of groundwater flow, it was found that the grouted bolts are more structurely beneficial when the seepage occurs towards the tunnel than when there is no groundwater flow.

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The Effects of Open Innovation on Firm Performance: A Capacity Approach

  • Ahn, Joon Mo;Mortara, Letizia;Minshall, Tim
    • STI Policy Review
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    • v.4 no.1
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    • pp.74-93
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    • 2013
  • Although open innovation (OI) has been an important research theme for over a decade, its theoretical framework has been relatively under-researched. As OI involves a wide range of innovation activities, a firm's capacities in the use of the various firm resources play a critical role in OI implementation. However, it is unclear how they affect firms' performances for little is known of OI capacities. Based on a theoretical framework derived from the literature, this study looks into the relationships between six OI capacities (inventive, absorptive, transformative, connective, innovative, and desorptive) and financial performance using the Korean Innovation Survey (KIS) 2008 data. The research model was tested using structural equation modelling (SEM) while potential differences in capacities between different firm groups were also investigated. The results indicate that 1) OI capacities are significantly associated with firms' financial performance; 2) capacities are highly correlated with one another; and 3) some capacities are differently configured between different types of firms. Findings suggest that policy makers should pay more attention to helping firms enhance OI capacities and attempt to develop relevant policies in order to complement inadequate capacities.

A Study on the Correlations Between Ultrasonic Parameters and Fracture Toughness (초음파 파라미터와 파괴인성치의 상관관계에 관한 연구)

  • Kim Jeong-Pyo;Park Jae-Sil;Bae Bong-Kook;Seok Chang-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.29 no.2 s.233
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    • pp.232-238
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    • 2005
  • In this study the four classes of the thermally aged 1Cr-1Mo-0.25V specimens were prepared using an artificially accelerated aging method. Ultrasonic tests were performed to get the correlation with fracture toughness. The modified theoretical Vary's equation, considering nonlinear response due to material degradation, was proposed for the correlations between ultrasonic parameters and fracture toughness. Experimental results indicate that ultrasonic attenuation coefficient, velocity and nonlinear parameters produce the correlations with fracture toughness and yield strength.

A Study on the strength evaluation for T-type Composite Beam (T형 합성보의 내력평가에 관한 연구)

  • Kim, Sang Mo;Kim, Kyu Suk
    • Journal of Korean Society of Steel Construction
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    • v.15 no.4 s.65
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    • pp.467-474
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    • 2003
  • Composite action can be achieved by providing shear connectors between the steel top flange and concrete topping. Composite sections are stiffer than the sum of the individual stiffness of slab and beam. They can therefore carry heavier loads or similar loads with appreciably smaller deflection. They are also less prone to transient vibration. In this study, T-type Steel Composite beam (TSC-beam) was developed and tested. The test results of TSC beam were compared with the theoretical results based on composite actions.

A Philosophical Interpretation for the Corporate Social Responsibility (기업의 사회적 책임에 대한 철학적 해석)

  • Seo, Yong-Mo;Yoon, Inhwan
    • Land and Housing Review
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    • v.9 no.4
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    • pp.19-24
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    • 2018
  • This study is a theoretical study on philosophical thinking for examining the idea of the corporate social responsibility(CSR) of a company. The oriental philosophical thought is to understand the contents of social responsibility of the corporation centering on Mozi's philosophy, which stresses that people should care for everyone equally. In the Western philosophical thought, we tried to understand the contents of corporate social responsibility by focusing on utilitarian thought. It is not merely an actual principle or a moral principle, but a comprehension for mutual benefit. In conclusion, it can be concluded that universal love's approach through the gangbang has many similarities with the realization of the greatest happiness of the number that is uttered in utilitarian thinking. In this way, a sustainable competitiveness of corporations can be achieved through universal love and utilitarian philosophical understanding and practice for the cognition of social responsibility.