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Powder Characteristics and Thermoelectric Properties of Bi2Te3 Alloys Fabricated by Mechanical Alloying Process (기계적 합금화 공정으로 제조한 Bi2Te3계 합금의 분말특성과 열전특성)

  • 김부양;김희정;오태성;현도빈
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.311-352
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    • 1996
  • Peltier 효과를 이용한 열전소자는 열응담 감도가 좋고 선택적 냉각이 가능하며 무소음, 무진동 및 소형화의 장점으로 각종 전자부품의 국부냉각소자로 응용되고 있다. 또한 최근 냉매의 사용없이 냉각이 가능한 열전재료를 이용한 자동차나 가정용 에어컨 및 냉장고 등의 각종 냉방시스템의 개발도 크게 주목을 받고 있다. 기존의 Bi2Te3계 단결정 열전재료는 성능지수는 우수하나, 기계적 취약성에 기인하여 소자가공시 수율 저하가 가장 큰 문제점으로 지적되고 있다. 이와 같은 문제점을 해결하기 위해 최근 단결정에 비해 기계적 강도가 우수한 다결정 열전재료의 제조공정에 관한 연구가 활발히 이루어지고 있으며, 그 일환으로 기계적 합금화법을 이용한 열전재료의 제조공정이 연구되고 있다. 원료금속이 고 에너지 볼-밀 내에서의 연쇄적인 파괴와 압접에 의해 합금분말로 변화되는 기계적 합금화 공정은 상온공정으로 이를 사용하여 다결정 열전재료를 제조시 기존의 다결정 열전재료의 제조공정인 "용해 및 분쇄법'과 비교하여 제조단가를 낮출 수 있는 장점이 있다. 본 연구에서는 전자냉각소자용 열전재료로서 상온부근에서 성능지수가 가장 우수한 p형 (Bi,Sb)2Te3 및 n형 Bi2(Te,Se)3 합금분말을 기계적 합금화 공정으로 제조하여 분말 특성을 분석하였으며, 가압소결 후 열전특성의 변화거동을 연구하였다. 순도 99.99% 이상인 Bi, Sb, Te, Se granule을 (Bi1-xSbx)2Te3 및 Bi2(Te1-ySey)3 조성에 맞게 칭량하여 불과 분말의 무게비 5:1로 강구와 함께 공구강 vial에 장입 후, Spex mixer/mill을 이용하여 기계적 합금화 하였다. 기계적 합금화 공정으로 제조한 분말에 대한 X-선 회절분석과 시차 열분석으로 합금화 정도를 분석하였다. (Bi1-xSbx)2Te3 및 Bi2(Te1-ySey)3 합금분말을 10-5 torr의 진공중에서 300℃∼550℃의 온도로 30분간 가압소결하였다. 가압소결체의 파단면에서의 미세구조를 주사전자현미경으로 관찰하였으며, 상온에서 가압소결체의 열전특성을 측정하였다. (Bi1-xSbx)2Te3의 기계적 합금화에 요구되는 공정시간은 Sb2Te3 함량에 따라 증가하여 x=0.5 조성에서는 4 시간 45분, x=0.75 조성에서는 5 시간, x=1 조성에서는 6 시간 45분의 vibro 밀링이 요구되었다. n형 Bi2(Te1-ySey)3 합금분말의 제조에 요구되는 밀링시간 역시 Bi2Se3 함량 증가에 따라 증가하였으며 Bi2(Te0.95Se0.05)3 합금분말의 제조에는 2시간, Bi2(Te0.9Se0.1)3 및 Bi2(Te0.85Se0.15)3 합금분말의 형성에는 3시간의 bivro 밀링이 요구되었다. 기계적 합금화로 제조한 p형 (Bi0.2Sb0.8)2Te3 및 n형 Bi2(Te0.9Se0.1)3 가압 소결체는 각기 2.9x10-3/K 및 2.1x10-3/K 의 우수한 성능지수를 나타내었다.

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Inorganic Electro-luminescence Device Fabricated with $BaTiO_3$-PVDF Composite Film ($BaTiO_3$-PVDF 복합체로 제작한 무기 EL 소자)

  • Son, Yong-Ho;Jeong, Joon-Seok;Jo, Chan-Woo;Woo, Duck-Hyun;Kim, Young-Min;Kim, Sung-Jin;Yoon, Man-Soon;Ryu, Sung-Lim;Kweon, Soon-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.299-299
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    • 2007
  • 후막형 무기 EL (electro-luminescence) 소자는 제조공정이 간단하고, 얇고, 가볍고, 유연한 동의 많은 장점들 때문에 휴대폰의 키패드 (key-pad) 및 광고용 back-light용으로 사용되고 있다. 이 무기 EL 소자는 비교적 손쉬운 스크린 프린팅 (screen-printing) 법으로 대면적을 제작할 수 있지만, LED (light emitting diode) 등과 비교하여 밝기가 낮아서 그 응용 분야가 제한되고 있다. EL 소자의 형광층은 전면 전극과 후면 전극 사이에 위치한다. EL은 이 형광층에 고 전기장이 걸릴 때, 전기장에 의해 가속된 전자가 형광층 내부에 첨가된 발광 중심의 전자를 여기시키고, 여기된 전자가 다시 바닥상태로 완화될 때 빛이 방출되는 현상이다. 즉, EL 소자는 이러한 전자 발광 현상을 이용한 소자로서, 전압 인가 시 발광 면 전체가 균일하게 발팡하는 평면 광원이다. 이러한 EL 소자에서 휘도의 증가는 후면 전극과 형광층 사이에 삽입되는 유전체 층의 특성과 밀접한 연관성이 있다. 본 연구에서는 고휘도 무기 EL 소자를 제작하기 위하여 이 유전체 층의 특성과 소자의 성능 사이의 관계를 알아보고자 하였다. 유전체 층에 사용하기 위해서 $BaTiO_3$-PVDF (polyvinylidene fluoride)의 복합체 필름을 제조하였다. 먼저 이 복합체 필름을 스크린 프린팅 (screen printing) 법으로 코팅하기 위한 페이스트 제작을 위해서, PVDF 수지를 용제에 녹였다. 그 다음, 일반 혼합기 및 삼단 롤밀 혼합기 (3-roll milling mixer) 등을 이용하여 $BaTiO_3$ 분말과 PVDF 용액을 다양한 비율로 혼합하여 페이스트를 제조하였다. ITO가 증착된 PET Film에 스크린 프린팅 법을 사용하여 형광층, 유전층, 배면 전극 등을 차례로 코팅하였다. $BaTiO_3$ (BT) 분말과 복합체 필름의 XRD 분석 결과, 분말 시료와 복합체 시료 모두 페로브스카이트 구조의 BT 회절선만 관찰되었다. 복합체의 단면 SEM 관찰에서는, BT 분말의 무게비가 증가할수록 더 치밀한 구조를 보여줌을 확인하였다. 또 EL소자의 유전상수와 휘도도 BT 분말의 혼합비가 증가할수록 증가하였다. 본 연구에서 제작한 무기 EL 소자의 최대 휘도는 약 $130\;cd/m^2$ 정도로 측정되었는데, 이는 휴대폰 키패드의 back-light용 광원으로 사용하기 충분하다고 판단되어진다.

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Miniaturized DBS Downconverter MMIC Showing a Low Noise and Low Power Dissipation Characteristic (저잡음ㆍ저소비전력 특성을 가지는 위성방송 수신용 초소형 다운컨버터 MMIC)

  • Yun, Young
    • Journal of Navigation and Port Research
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    • v.27 no.4
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    • pp.443-447
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    • 2003
  • In this work. using 0.2 GaAs modulation doped FET(MODFET), a high performance DBS downconverter MMIC was developed for direct broadcasting satellite (DBS) application. Without LNA, the downconverter MMIC showed a very low noise of 4.8 dB, which is lower by 3 dB than conventional ones. A low LO power of -10 dBm was required for the normal DBS operation of the downconverter MMIC. which reduced the power consumption via a removal of LO amplifier on MMIC. It required only a low power consumption of 175 mW, which is lower than 70 percent of conventional ones. The LO leakage power at IF output was suppressed to a lower level than 30 dBm, which removes a bulky LO rejection filter on a board. The fabricated chip, which include a mixer, If amplifiers. LO rejection filter, and active balun, exhibited a small size of $0.84{\times}0.9\textrm{mm}^2$.

Evaluation of Pilot scale Coagulation system Design for CSOs treatment (CSOs 처리를 위한 실증규모 응집침전시스템의 설계평가)

  • Lee, Seung-Chul;Ha, Sung-Ryong
    • Journal of Wetlands Research
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    • v.15 no.1
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    • pp.1-8
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    • 2013
  • A pilot scale coagulation system, which has a function of physicochemical treatment, was developed to treat Combined sewer overflows(CSOs). This coagulation system requires evaluation of optimum design factors whether it has reflected those of lab scale system, moreover, the pilot scale system can be evaluated differently according to the characteristics of influent CSOs even though it has reflected lab scale's design factors. We conducted an experiment using lab scale system that could treat $1m^3$ of CSOs in a day, and also pilot-scale system with $100m^3/day$ CSOs flowed into the Cheongju sewage treatment plant. Therefore the aim of this study is to evaluate a hydraulic similarity between the design factors of pilot scale and those of lab scale coagulation system, and to evaluate feasibility of the coagulation system for the CSOs treatment with optimum operation conditions. From the result of pilot-test, we drew the optimum operation factors of in line mixer and flocculator having similarities with those of lab scale system as well as the optimum coagulant dose. Finally we confirmed that the coagulation system has feasibility to treat the CSOs with high removal efficiency.

Modified CTAB DNA Methods for efficient DNA extraction from Rice (Oryza sativa L.) (벼 분자육종을 위한 CTAB DNA 추출 시스템 개량)

  • Lee, Jong-Hee;Kwak, Do-Yeon;Yeo, Un-Sang;Kim, Choon-Song;Jeon, Myeong-Gi;Kang, Jong-Rae;Park, Dong-Soo;Shin, Mun-Sik;Oh, Byeong-Geun;Hwang, Hung-goo
    • Korean Journal of Breeding Science
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    • v.40 no.3
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    • pp.286-290
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    • 2008
  • Many important traits have been tagged allowing plant breeders to apply marker assisted selection (MAS) in rice. PCR itself is simple to set up, and requires little hands-on time. However, a crucial limiting step of MAS programs is the reliable and efficient extraction of DNA which can be performed on thousands of individuals. In this study, We describe a modification of the DNA extraction method, in which cetyltrimethylammonium bromide (CTAB) is used to extract DNA from leaf tissues for suitable MAS in rice. We followed the standard 2% CTAB extraction method in all the procedure. In addition we used the 1.2 ml 8-strip tube instead of 1.5 ml E-tubes to fit the 8-multichannel pipette and employ the 96 well plate to use the swing bucket centrifuge. Our modified CTAB DNA extraction method offers several advantages with respect to traditional and simple methods. 1) adult leaf samples collected in paddy field are applicable. 2) 96 leaf samples can be homogenized only one-time by using tungsten carbonate bead and 96well block. 3) semiautomatic loading method using 8-multichannel pipette from DNA extraction to electrophoresis of PCR products. 4) our system can extract about 400 leaf samples per day by only one technicion. Therefore, this method could be useful for marker assisted breeding in rice.

Extraction of Quercetin and Its Glucosides from Onion Edible Part Using Solvent Extraction and Various Extraction Assisting Methods (용매 추출과 병용 추출법을 이용한 양파 과육으로부터 quercetin 관련물질의 추출)

  • Jin, Eun Young;Park, Young-Seo;Jang, Jae Kweon;Chung, Myong-Soo;Park, Hoon;Shim, Kun-Sub;Choi, Young Jin
    • Food Engineering Progress
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    • v.13 no.2
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    • pp.147-153
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    • 2009
  • Quercetin is one of the main flavonoids from onion. To use quercetin as a functional component for onion food products, the effects of various extraction assisting methods such as juicing methods, microwave, ultrasound and enzyme treatments on the yield of quercetin and its glucosides were investigated. For conventional solvent extraction, the highest yield of quercetin and its glycosides was achieved with 0.8 mL/g of 60% methanol at 50$^{\circ}C$ for 15 min. The juicing methods using mixer and screw showed no influence on the yield. Microwave and ultrasound treatments showed 2.14 times and 2.06 times more quercetin yields than non-treated extraction, respectively. For cellulase and viscozyme treatments, the highest yields of quercetin were achieved with 0.5 mL/g of 1% enzyme-0.1M sodium acetate (pH 5.2) buffer solution. Cellulase and viscozyme treatment improved quercetin yield 1.65 times and 2.29 times more than non-treated one, respectively.

Effects of Mixing Method and Storage Period of Dangyuja-Sugar Mixture on Customer Preferences for Dangyuja-tea (당유자청의 제조방법과 냉동 저장기간이 당유자차 기호도에 미치는 영향)

  • Kim, Yun-Jung;Moon, Jeong-Yong;Kim, Jung-Hyon;Kim, Haeng-Geun;Kim, Jae-Hoon;KimCho, So-Mi
    • Food Science and Preservation
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    • v.14 no.2
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    • pp.160-164
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    • 2007
  • This study was performed to investigate the effects of mixing methods, storage period, and dilution ratio of Dangyuja-sugar mixture on the customer preferences for Dangyuja-tea. Most sensory characteristics such as bitterness, flavor, and taste are influenced more by mixing methods of Dangyuja-sugar mixtiue than by storage period. The Dangyuja-sugar mixture prepared by slice cutting is preferred to those prepared by operating electric mixer, The preference test showed that the appearance is not influenced by storage period but by mixing methods, whereas the tne and texture is more affected by storage period in which the 24 month storage is preferred to 12 month storage. therefore, the overall preference fer Dangyuja-tea is the on that prepared with 20% contents of Dangyuja-sugar mixture which is slice-cut and 24 month stored.

Development of self-propelled windrow turner for button mushroom compost (양송이버섯 재배용 자주식 배지교반기 개발)

  • Park, Hwan-Jung;Yu, Byeong-Kee;Lee, Sung-Hyeon;Lee, Chan-Jung;Kim, Yeong-Ho
    • Journal of Mushroom
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    • v.16 no.4
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    • pp.250-256
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    • 2018
  • The windrow turner, widely used for outdoor fermentation of mushrooms in Europe, has been improved by using rice straw instead of wheat straw in accordance with Korea's actual situation. It was compared with conventional excavator work, and the results were as follows. Agitation performance was $81m^3/hr$, which was 2.8 times higher than $28.6m^3/hr$ of excavator. As a result of the temperature distribution in the pile at the end of the fermentation stage, it was found that the temperature at the lower part of the pile was $5^{\circ}C$ higher than that of conventional pile. This was more favorable for aerobic fermentation. Meanwhile, ash ratio of prototype ($30.9{\pm}1.1%$) was higher than that of control $28.4{\pm}1.6%$. In the case of prototype turner agitation, the yield of mushroom cultivation was $880kg/66m^2$, that was 22.9% higher than the conventional control yield of $716kg/66m^2$.

Measurements and Calculation of Injection Mass Rate of LFG for Intake Injection in Spark Ignition Engines (불꽃점화 엔진의 흡기관 분사를 위한 매립지가스 분사량의 측정 및 계산)

  • Kim, Kyoungsu;Choi, Kyungho;Jeon, Wonil;Kim, Bada;Lee, Daeyup
    • Journal of the Korean Institute of Gas
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    • v.25 no.4
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    • pp.36-42
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    • 2021
  • When the landfill gas generated at the landfill site is released into the atmosphere, methane gas with a high global warming potential is emitted, which adversely affects climate change. When methane contained in landfill gas is used as fuel for internal combustion engines and burned to generate electricity, it is emitted into the atmosphere in the form of carbon dioxide, which can contribute to lowering the global warming potential. Therefore, in order to use the landfill gas as fuel for power generation using an internal combustion engine, it is important to increase the thermal efficiency of the engine. Thus, it is necessary to use a fuel supply system in which gas is injected using an electronically controlled injector at an intake port for each cylinder rather than a fuel supply technology using the conventional mixer technology. In order to use the electronically controlled gas injection method, it is important to accurately measure the mass flow rate according to the conditions of using landfill gas. For this, a study was conducted to measure the injection amount and calculate them in order for the intake port gas injection of landfill gas.

An Experimental Study on the Improvement of Quality of Mixed Aggregate Using Recycled Aggregate (순환골재 사용 혼합골재의 품질 개선을 위한 실험적 연구)

  • Kim, Jung-Ho;Sung, Jong-Hyun;Kim, Choong-Gyum;Lee, Sea-Hyun;Kim, Han-Soo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.229-235
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    • 2018
  • In this study, recycled aggregate and natural aggregate were mixed in advance using an aggregate mixing facility that was developed to improve the quality of recycled aggregate concrete. Then the mixed aggregate was applied and concrete characteristics before and after a mix were considered. Based on the findings extracted, this study aimed to suggest a new direction for quality stabilization and application activation of recycled aggregate. The test results of change rates of mortars and coarse aggregates in fresh concrete mixed by a concrete mixer, before and after mixing aggregates showed that the variations of the mortars and coarse aggregates in the concrete mixed with the aggregates beforehand were decreased than those in the concrete before mixing them. The variation of compressive strength and the mean compressive strength at the ages of 3 and 7 days showed similar results before and after the aggregates were mixed, and the strength at the age of 28 days before and after mixing them showed larger deviation than that at the ages of 3 and 7 days. The use of the mixed aggregates after mixing aggregates beforehand reduced the variation in strength and is believed that it is advantageous for long-age strength development. The above results show that the variations of coarse aggregates and compressive strength in the concrete using the mixed aggregates produced by mixing recycled aggregates and natural aggregates beforehand are reduced so it will be possible to produce the homogeneous concrete by mixing aggregates beforehand.