• Title/Summary/Keyword: MFI

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The Effect of Pore Structure of Zeolites on their Product Distribution and Deactivation in the Catalytic Cracking of n-Octane (n-옥탄의 촉매 분해반응에서 제올라이트의 세공구조가 생성물 분포와 활성저하에 미치는 영향)

  • Min, Byung Goo;Lee, Jae Youl;Song, Yo Soon;Seo, Gon
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.547-553
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    • 2007
  • The catalytic cracking of n-octane over FER, MFI, MOR and BEA zeolites was studied by the protolytic cracking mechanism in order to understand the effect of pore structure of zeolites on their product composition and deactivation. The selectivities for $C_3$ and $C_3{^=}$ were high over the zeolites with medium pores due to additional cracking, while those for $C_4$ and $C_4{^=}$, the initial products, were high over the zeolites with large pores. MFI zeolite showed slow deactivation due to small carbon deposit, while FER zeolite with small pores deactivated rapidly with severe carbon deposit. The deactivation of BEA zeolite was slow even with a large amount of carbon deposit, but MOR zeolite showed a rapid deactivation even with a small amount of carbon deposit. The conversion measured along with the time on stream on these zeolite catalysts was simulated by a mechanism based on the simplified reaction path of n-octane cracking and the deactivation related to the pore blockage by carbon deposit.

A Study on the physicochemical Properties and Palatability of Hanwoo Beef Loin in $1^+$ Grade (한우 $1^+$ 등급육의 이화학적 특성과 기호성에 관한 연구)

  • 문윤희;김미숙;김대진;양종범;강세주
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.6
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    • pp.1288-1292
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    • 1999
  • The physicochemical properties and palatability of Hanwoo(cow, steer, and bull) beef loin(1+ carcass grade) were studied. pH(5.56~5.69), moisture content(67.6~69.0%), crude protein content(17.8~18.7%), and crude fat content(11.9~13.8%) of Hanwoo beef loin did not show significant difference between the types of Hanwoo. L(44.5~46.9), a(19.9~20.6), and b(10.3~11.6) color parameters, water holding capacity (69.4~70.5%), volatile basic nitrogen content(9.86~11.28mg%), thiobarbituric acid value(0.148~0.158 mg malonaldehyde/kg), and cooking loss(26.3~27.9%) of beef loin did not show significant difference between the types of Hanwoo either. Hardness, myofibrillar fragmentation index(MFI), and chewiness of beef loin were 6.1~6.9 dyne/cm2, 50.3~54.9, and 39.5~ 52.0g, respectively. No differences were found in hardness and MFI between the types of Hanwoo, while chewiness of cow was much lower than that of steer and bull(p<0.05). Cow was the best in palatability.

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Synthesis of nanosized MFI zeolite using TEOS and TPAOH precursors (TEOS 와 TPAOH 출발물질을 이용한 나노 크기의 제올라이트 합성)

  • Bae, Hye Jin;Choi, Byung Ho;Cho, Seong Hoon;Won, Soo Hyun;Lee, Bo Kyung;Ok, Hae Ryul
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.13 no.3
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    • pp.22-27
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    • 2014
  • Nanosized zeolite was prepared in an autoclave at a hydrothermal temperature range of 100 to $170^{\circ}C$. In TEM and particle-size analyses, the size of the nanosized powders was found to be 10-300 nm, and its distribution is uniform and spherical, depending on the hydrothermal temperature. XRD confirms that the nanosized powder is MFI zeolite.

Effects of Hot Boning and Soy Sauce on the Processing Properties of Semi-dried Beef Jerky

  • Han, Doo-Jeong;Lee, Eui-Soo;Lee, Si-Kyung;Kim, Cheon-Jei
    • Food Science of Animal Resources
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    • v.31 no.4
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    • pp.497-505
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    • 2011
  • The objective of this study was to examine the effect of hot-boning and soy sauce as a curing agent on the processing properties of beef jerky. Beef jerky was prepared under the following four treatment conditions; Beef jerky with cold-boned beef and salt solution, beef jerky with cold-boned beef and soy sauce solution, beef jerky with hot-boned beef and salt solution, and beef jerky with hot-boned beef and soy sauce solution. Cured meat and jerky containing hot-boned beef had a significantly higher pH, water holding capacity (WHC), moisture content, Myofibrillar fragmentation index (MFI), processing yields, tenderness, and sensorial scores than samples containing cold-boned beef (p<0.05). Regardless of the raw materials, the jerky containing soy sauce had a significantly lower pH, WHC, moisture content, salt content, TBA, CIE $L^*$ and $b^*-$ values, and significantly higher MFI, mechanical tenderness, and sensorial scores (p<0.05). Based on these findings, we concluded that the use of hot-boned meat and soy sauce was the most effective boning method and curing agent during beef jerky processing.

Postmortem Changes in the Physico-Chemical Characteristics of Korean Native Chicken (저장기간에 따른 한국산 토종닭고기의 품질 특성)

  • 성삼경;권연주;김대곤
    • Korean Journal of Poultry Science
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    • v.25 no.2
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    • pp.55-64
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    • 1998
  • This study was carried out to investigate the postmortem changes in physico-chemical characteristics of chicken meat with different breeds. Thigh and breast meats from Korean Native Chicken(KNC, 15-wk old), Wangchoo(15-wk old), and broiler(7-wk old) were stored at 5 ˚C. Differences in postmortem pH changes were not recognized among breeds, and pH showed by the lowest value at the 1st day of postmortem in all breeds. Breast meat had tendency to drop pH faster than thigh meat. Heme pigment contents showed no differences among breeds. KNC showed the lowest cholesterol contents in all breeds, total collagen contents showed the lowest value at the 1st day of postmortem, and thereafter it was gradually increased. Heat soluble collagen contents was lowest in Wangchoo. Water soluble and salt soluble protein showed the lowest extractability at the 1st day of storage. Broiler showed the highest extractability of these proteins and Wangchoo showed the lowest. Water holding capacity(WHC) had increasing tendency whilst cooking loss had decreasing tendency by the ageing. WHC of breast and thigh meat showed the highest values in KNC and broiler, respectively. Myofibrillar fragmentation index (MFI) was significantly increased in all breeds by the ageing. Breast and thigh meat showed almost same MFI in KNC and broiler, and in KNC and Wangchoo, respectively. Hardness of breast meat showed decreasing tendency by the ageing.

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Differences in Muscle Fiber Characteristics and Meat Quality by Muscle Type and Age of Korean Native Black Goat

  • Hwang, Young-Hwa;Bakhsh, Allah;Lee, Jung-Gyu;Joo, Seon-Tea
    • Food Science of Animal Resources
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    • v.39 no.6
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    • pp.988-999
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    • 2019
  • To investigate the relationship between muscle fiber characteristics and meat quality traits by age of Korean native black goat (KNBG), four muscles (longissimus dorsi, LD; psoas major, PM; semimembranosus, SM; gluteus medius, GM) were obtained from five adult goat (AG; 18 months old) and five young goat (YG; 9 months old). PM muscle had the highest fiber number percentage (FNP) and fiber area percentage (FAP) of type I, followed by SM, GM, and LD muscles. FNP and FAP of type IIB were significantly (p<0.001) higher in AG than those in YG. YG had higher L* values but lower b* values than AG. The highest L* and b* values were observed in LD muscle (p<0.001). Age and muscle type had detrimental (p<0.001) effect on shear force and collagen content for all muscle in AG as compared to YG. YG had significantly (p<0.001) higher myofibrillar fragmentation index (MFI) than AG for all four muscles. These results suggest that muscle fiber compositions of different muscle types of KNBG depend on age, resulting in variations of meat color, MFI, collagen content, and shear force.

Synthesis and characterization of microporous TS-1 zeolite(MFI) (Microporous TS-1 Zeolite(MFI)의 합성과 특성)

  • 강선명;이희수;김익진
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.3
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    • pp.309-314
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    • 1999
  • A microporous zeolite-type tianosilicate (TS-1), new catalysis elements, was synthesized by differents of the reactant solution pH. The range of reactant solution pH has from 10.0 to 12.4 TS-1 Zeolite (ETS-10), having a large pore (8~10 ${\AA}$), was synthesized at 10.4 of pH, since TS-1 Zeolite (ETS-4), having a small pore (3~5 ${\AA}$), was synthesized at 11.5 of pH. Also the two materials simultaneously existed at the intermediate pH. Crystallization, physico chemical characteristics of synthesized TS-1 Zeolite were investigated by XRD, XRF, SEM and FT-IR techniques.

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Use of laminar flow water storage tank (LFWS) to mitigate the membrane fouling for reuse of wastewater from wafer processes

  • Sun, Darren Delai;Wu, You
    • Membrane and Water Treatment
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    • v.3 no.4
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    • pp.221-230
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    • 2012
  • This study employed the modified fouling index (MFI) to determine the performance of a two-step recycling system - a membrane filtration integrated laminar flow water storage (LFWS) tank followed by an ion exchange process to reclaim ultrapure water (UPW) from the wastewater generated from semiconductor wafer backgrinding and sawing processes. The first step consisted of the utilization of either ultrafiltration (UF) or nanofiltration (NF) membranes to remove solids in the wastewater where the second step consisted of an ion exchanger to further purify the filtrate. The system was able to produce high purity water in a continuous operating mode. However, higher recycling cost could be incurred due to membrane fouling. The feed wastewater used for this study contained high concentration of fine particles with low organic and ionic contents, hence membrane fouling was mainly attributed to particulate deposition and cake formation. Based on the MFI results, a LFWS tank that was equipped with a turbulence reducer with a pair of auto-valves was developed and found effective in minimizing fouling by discharging concentrated wastewater prior to any membrane filtration. By comparing flux behaviors of the improved system with the conventional system, the former maintained a high flux than the latter at the end of the experiment.

New insights about coke deposition in methanol-to-DME reaction over MOR-, MFI- and FER-type zeolites

  • Migliori, Massimo;Catizzone, Enrico;Aloise, Alfredo;Bonura, Giuseppe;Gomez-Hortiguela, Luis;Frusteri, Leone;Cannilla, Catia;Frusteri, Francesco;Giordano, Girolamo
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.196-208
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    • 2018
  • The effect of channel-system of zeolite on methanol-to-DME reaction was studied. Results revealed that channels size and topology affect catalyst lifetime, type and location of coke precursors. FER and MFI showed the best resistance towards coke deposition, whilst fast deactivation was observed on MOR. Although the higher concentration and strength of acid sites, FER structure formed a lower coke amount, preferably located within the pores, while coke cluster deposited on the external surface of MOR. Analysis of acid sites distribution and strength was performed during deactivation-regeneration process. Coke location assessment was also supported by molecular simulations.

The Effect of Microfinance Services on Women Entrepreneurship: A Case Study in Jordan

  • THAHER, Lubna Mohammad;RADIEAH, Nor Mohd;WAN NORHANIZA, Wan Hasan
    • The Journal of Asian Finance, Economics and Business
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    • v.8 no.5
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    • pp.807-815
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    • 2021
  • Microfinance is seen as a tool for poverty elimination by providing various services characterized as financial and non-financial to minority groups in the society to be included in the mainstream financial system. This paper seeks to examine the effect of microfinance institutions' (MFIs) financial and non-financial services on women's entrepreneurship and empowerment in Jordan as a developing country. To gain a deeper understanding of the effectiveness of microfinance services, the study is undertaken to address the question of what kinds of services are available and whether the MFI services are in line with the actual needs of women entrepreneurs to improve their performance. Hence, a qualitative approach was adopted in this study using semi-structured interview questions to collect data from twenty-four women entrepreneurs in Jordan. The results showed that, as regards financial services, the most important needs of women entrepreneurs include providing adequate financing with necessary financial facilities such as reducing interest, reducing monthly installments, and extending the grace period, while non-financial services should include holding specialized courses, accessing a counseling center, providing incentives and psychological support, marketing support, and monitoring and evaluation. This study concluded that factors associated with MFI play a crucial role to uplift women entrepreneurs and eliminate gender inequality.