• Title/Summary/Keyword: METAL SURFACE

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Heavy Metal Adsorption of Anodically Treated Activated Carbon Fibers in Aqueous Solution

  • Park, Soo-Jin;Kim, Young-Mi
    • Carbon letters
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    • v.4 no.1
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    • pp.21-23
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    • 2003
  • In this work, the effect of anodic oxidation treatment on Cr(VI) ion adsorption behaviors of activated carbon fibers (ACFs) was investigated. The aqueous solutions of 10 wt% $H_3PO_4$ and $NH_4OH$ were used for acidic and basic electrolytes, respectively. Surface characteristics and textural properties of ACFs were determined by XPS and $N_2$ adsorption at 77 K. The heavy metal adsorption of ACFs was conducted by ICP. As a result, the adsorption amount of the anodized ACFs was improved in order of B-ACFs > A-ACFs > pristine-ACFs. In case of the anodized treated ACFs, the specific surface area was decreased due to the pore blocking or pore destroying by acidic electrolyte. However, the anodic oxidation led to an increase of the Cr(VI) adsorption, which can be attributed to an increase of oxygen-containing functional groups, such as, carboxylic, lactonic, and phenolic groups. It was clearly found that the Cr(VI) adsorption was largely influenced by the surface functional groups, in spite of the reduced specific surface area of the ACFs.

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A Study on Condensation Heat Transfer to Some Evaporated Metal Surface (각종증착금속면의 응축열전달에 관한 연구)

  • Jho Shi Gie;Lee Ki Woo;Park Young Jae;Cko Myong Jae
    • The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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    • v.15 no.2
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    • pp.188-195
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    • 1986
  • Condensation heat transfer can be classified in dropwise condensation and filmwise condensation, and for the industrial purpose, the former is more useful than the latter because of the higher heat transfer rate. But it is difficult to maintain the dropwise condensation continuously since most of the metal surfaces become wetted after exposure to a condensing vapor over an extended period of time. To maintain dropwise condensation continuously , various surface coatings and promoters have been used recently, but these methods must be reconsidered about the durability of condensing surface. Therefore, in this study, evaporating method of various pure metals on the condensing surface has been performed to maintain dropwise condensation. The results have showed that the heat transfer rate of silver evaporating surface is higher than any other metal evaporating in dropwise area. Transition temperature and filmwise condensation curves are uniform regardless of kinds of evaporating metals.

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The Surface Property and Shear Bonding Strength according to Composition of Ni-Cr alloy for Porcelain Fused to Metal Crown (도재용착주조관용 Ni-Cr계 합금의 조성에 따른 표면특성 및 전단결합강도 관찰)

  • Kim, Kap-Jin;Chung, In-Sung;Choi, Sung-Min
    • Journal of Technologic Dentistry
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    • v.35 no.2
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    • pp.113-120
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    • 2013
  • Purpose: This study was to observe surface property and bonding strength according to composition of Ni-Cr alloy for porcelain fused to metal crown. The two kinds of Ni-Cr alloy with different composition ratio of parent metal were observed general properties and chemical properties of each alloy surface and measured the shear bonding strength between ceramic and each alloys. The aim of study was to suggest the material for design of parent metal's composition ratio to development of alloy for porcelain fused to metal crown. Methods: The two kinds of alloy as test specimen was Ni(71wt.%)-Cr(12wt.%) and Ni(63wt.%)-Cr(23wt.%) alloy. The oxide on surface was observed by SEM and EDX. And the shear test was performed by MTS. Results: The surface property and oxide characteristic analysis of oxide layer, weight percentage of Element O within $Ni_{71}Cr_{12}$ alloy measured 12.74wt.%, but $Ni_{63}Cr_{23}$ alloy was measured 15.91wt.%. And the maximum shear bonding strength was measured 106.14MPa between $Ni_{71}Cr_{12}$ alloy and vintage halo (VV group). Conclusion: The surface property and oxide characteristic of $Ni_{71}Cr_{12}$ alloy was similar to $Ni_{63}Cr_{23}$ alloy. And VV group has the strongest shear bonding strength.

A Consideration on the Application of Metal Surface Wave Communication Technology in the Ships (금속체 표면파 통신 기술의 선내 적용 방안에 관한 고찰)

  • Jin-Woo Kong;Bu-Young Kim;Woo-Seong Shim
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2023.11a
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    • pp.135-136
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    • 2023
  • This study is an empirical result for building an onboard communication network using metal surface wave communication and is a consideration of its application within the ship. Over the past three years, the applicability and the performance of metal surface wave communication has been confirmed by testing on five small and medium ships. In the tests, IEEE 802.11 protocol of Wi-Fi was used, and the signals were generated in the form of surface waves. Data was sent from AP to AP in the point-to-point form, and the transmission speed was measured at the same time. If necessary, additional repeaters were used to extend the transmission distance. As derived a transmission speed of 5 to 100 Mbps in wireless communication restricted areas of the 5 ships, it is believed that it is possible to reduce the weight of ships and costs by eliminating the communication cables by using surface wave communication as the back-bone network on ships.

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Composition Analysis and Thermodynamic Care for Replication of Ancient Metallic Type (고대 금속활자의 복제를 위한 성분분석과 열역학적 주의 점)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.45 no.3
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    • pp.136-141
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    • 2012
  • 'Jikjisimcheyocheal (Jikji afterwards)' is known as a first book printed by the metal type in the world. The metal type used for printing this book has not been found yet. To help for replicating the original metal type, it is required to investigate the composition analysis of the copied metal type. In this study, the composition analysis and thermodynamic care for replicating of ancient metal type was performed on the basis of an analytical reports concerned with the ancient metal type which made after Jikji printing. Metal types were made by remelting and casting of the mother alloy which came from a cast of a mixed metals in accordance with the composition revealed in the literatures. Change of composition during remelting of mother alloy and casting of metal was detected by the EDS analysis. The reasons for variation in composition were discussed by metallurgical and thermodynamic point of view, and a mixing ratio of metals to get the original composition of ancient metal type is suggested. Some attention should be paid on mixing, melting and casting of metals to get an objected composition for copy of ancient metal type.

Nickel Plating Techniques of Nylon-Inorganic Filler Alloy (Nylon-Inorganic Filler Alloy상의 니켈 도금 기술)

  • Roh, Yun-Chan
    • Applied Chemistry for Engineering
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    • v.10 no.1
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    • pp.67-72
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    • 1999
  • Optimal pretreatment processes for metal plating on engineering plastics, especially on Nylon-inorganic filler alloy was studied. For Nylon-inorganic filler alloy, adhesion strength between resin surface and metal could be improved by just etching process that eliminate amorphous layer. In the SEM picture and surface roughness measurement, etching treatment was found to make enabled the surface condition very rough and the adhesion strength good. It was also found that the surface condition of plated article and its adhesion strength partly depended upon molding condition of Nylon-inorganic filler alloy. EDS, peaks showed that what kinds of and how much of the metal elements remained on the resin surface after pretreatment processes. Cr did not affect on adsorption of Sn and Pd remarkably.

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Study on the Analysis of Wear Phenomena of Ion-Nitrided Steel (이온질화 처리강의 마모현상 분석에 관한 연구)

  • Cho, Kyu-Sik
    • Tribology and Lubricants
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    • v.13 no.1
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    • pp.42-52
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    • 1997
  • This paper deals with wear characteristics of ion-nitrided metal theoretically and experimentally in order to analysis of wear phenomena. Wear tests show that compound layer of ion-nitrided metal reduces wear rate when the applied wear load is mall. However, as th load becomes large, the existence of compound layer tends to increase wear rate. The residual stress at the surface of ion-nitrided metal is measured, and the internal stress distribution is calculated when the normal and tangential forces are applied to the surface of metal. Compressive residual stress is largeest at the compound layer, and decreases as the depth from the surface increases. Calculation shows that the maximum stress exists at a certain depth from the surface when normal and tangential force are applied, and that the larger the wear load is the deeper the location of maximum stress becomes. In the analysis, it is found that under small applied wear load the critical depth, where voids and cracks may be created and propagated, is located at the compound layer, as the adhesive wear, where hardness is an important factor, is created the existence of compound layer reduces the amount of wear. When the load becomes large the critical depth is located below the compound layer, and delamination, which may be explained by surface deformation, crack nucleation and propagation, is created, and the existence of compound layer increases wear rate.

A Study on Effect of Shot Peening on Fracture Toughness of Spring Steel (스프링강의 파괴인성에 미치는 쇼트피닝 효과에 관한 연구)

  • Ha, K.J.;Park, K.D.
    • Journal of Power System Engineering
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    • v.7 no.2
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    • pp.66-72
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    • 2003
  • Recently, the steel parts used at the aerospace and automobile industries are required to be used light weight parts. Therefore, used material, steel have to be a high stress, which is an indispensable condition in this field. At the consideration of parts design, high hardness of the lightweight parts have an benefit of saving fuel and material. A high stress of metal has a point of difference according to the shape of design, external cyclic load and condition of vibration. A crack generates on the surface of metal or under yield stress by defect of inner metal defect or surface defect and slowly, this crack grow stable growth. Finally, rapidity failure phenomena is happen. Fatigue failure_phenomena, which happen in metal, bring on danger in human life and property therefor, anti-fatigue failure technology take an important part of current industries Currently, the shot peening is used for removing the defect from the surface of steel and improving the fatigue strength on surface. Therefore, this paper investigated the effect on frcature toughness using shot peening which is improve the resistance of crack growth and crack expansion rate by fatigue that make a compressive residual stress on surface.

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A Study on Precision Measurement System for Metal Plate Surface Quality Using Moving Average Image Processing Techniques (이동평균 영상처리기법을 이용한 금속판재 표면품질 정밀 측정시스템 연구)

  • Kim, Tae-Soo;Chun, Joong-Chang
    • Journal of Korea Society of Industrial Information Systems
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    • v.17 no.2
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    • pp.73-80
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    • 2012
  • It has been highly required to develope an automatic metal surface inspection system, specifically using image processing techniques, which can replace the visual inspection method in the steel industry. In this paper, we propose a precisional surface measurement system using the moving average image processing technique. When the surface patterns which are generated in the rolling process of metal plates are recognized as defects, the proposed system can measure the actual number of defects. It has been proved that our system shows better results than the conventional FFT method.

In situ growth of Mg-Al hydrotalcite film on AZ31 Mg alloy

  • Song, Yingwei;Chen, Jun;Shan, Dayong;Han, En-Hou
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.11a
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    • pp.12-13
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    • 2012
  • An environmentally friendly method for in situ growth of Mg-Al hydrotalcite (HT) film on AZ31 magnesium alloy has been developed. The growth processes and corrosion resistance of the HT film were investigated. Then the HT film was surface modified by phytic acid solution to further improve the corrosion resistance. The film formation involves the dissolution of AZ31 substrate, adsorption of the ions from solution, nucleation of the precursor, followed by the dissolution of $Al^{3+}$, exchanging of $OH^-$ by $CO{_3}^{2-}$ and growth of the HT film. The HT film is very compact and acts as a barrier against $Cl^-$ attack in the early stage of corrosion, and then the surface of the film is dissolved gradually. This dense HT film can provide effective protection to the AZ31 alloy. The HT film with surface modification by phytic acid presents a self-healing feature and exhibits better corrosion resistance.

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