• Journal of Korean Society of Environmental Engineers
• /
• v.32 no.4
• /
• pp.349-356
• /
• 2010

Ion chromatography (IC) coupled with conductivity detector (CD) is a common system for the determination of perchlorate in water samples. Although the IC method with CD has been widely used for the determination of trace level perchlorate ion in water, sensitivity decreases dramatically as the complexity of the matrices increases. Here we proposed the application of ion chromatography coupled with mass spectrometry (IC-MS/MS) to significantly improve selectivity of perchlorate. The mean recovery of the method was 104.4 ${\pm}$ 5.7% and the relative standard deviation (RSD%) was 1.9 ${\pm}$ 1.3%. The alculated method detection limit (MDL) was 0.0207 ${\pm}$ 0.0099 ${\mu}g/L$. The concentrations of perchlorate were minimum <0.1 ${\mu}g/L$ and maximum 18.3 ${\mu}g/L$ in source water (Namhan, Bukhan and Han River). Hongreung showed higher concentrations ($1^{st}$-14.3 ${\mu}g/L$, $2^{st}$-18.3 ${\mu}g/L$) than the other places. And the concentrations of perchlorate were 0.18~0.34 ${\mu}g/L$ in the samples taken from the six water treatment plants and six intake stations in Seoul.

• Analytical Science and Technology
• /
• v.29 no.4
• /
• pp.179-185
• /
• 2016

An effective analytical method has been developed for the determination of β-blockers(atenolol, metoprolol and propranolol) and 6 β-lactams(amoxicillin, penicillin G, cefaclor, cefadroxil, cephalexin and cephradine) in water samples using two different cartridges. The samples were extracted by solid-phase extraction (SPE) with the usage of polymeric hydrophile-lipophile balance(HLB cartridges) and strong cation-exchange mixed-mode polymeric sorbent (MCX cartridges). A XDB-C₁₈ column(1.8 μm; 3.0 mm × 100 mm) was used for the sufficient chromatographic resolution. The calibration curves showed good linearity with high correlation coefficients (>0.995). The method detection limits (MDL) and the limits of quantification(LOQ) were from 1.1 to 3.9 ng/L and from 5 to 13 ng/L, respectively. The method was applied for the determination of the target compounds in tributaries and raw water of the Han River and these were found at N.D. to 0.209 μg/L.

• Analytical Science and Technology
• /
• v.24 no.1
• /
• pp.10-14
• /
• 2011

This study was performed to compare international analytical methods of bromide and applied to determine bromide in bottled mineral water and raw ground water in Korea. Bromide in water was eluted by 10~50 mM potassium hydroxide (KOH) and determined by ion chromatography-suppressed conductivity detector (IC-CD). Sample was purified with Ba- and H-on-guard cartridge and $0.2\;{\mu}m$ membrane filter. The method detection limit (MDL) and the limit of quantitation (LOQ) of bromide were 0.2 and $0.5\;{\mu}g/L$, respectively. The calibration curve showed good lineality above 0.9993 in the ranges of the $0.5\sim80\;{\mu}g/L$. A correlation coefficient of bromide in ground water and sum of bromide and bromate in bottled mineral water is 0.808.

• Journal of The Geomorphological Association of Korea
• /
• v.19 no.2
• /
• pp.31-49
• /
• 2012

Satae cheon, a tributary of the Suip cheon in Yanggu, Gangwon province, is an international river extended to North Korea. Most of drainage basin area of the river was the fierce battle field during the Korean War(1950-1953) and hard to access as it located between the MDL(Military Demarcation Line) and the CCZ(Civilian Control Zone: about 10km south from MDL). By the restriction of access to the sites, most of natural landscape have been well conserved except limited use for military activities. Even the landfoms in that area were not studied, except the government's heritage reports. Satae Cheon's channel follows the Imdang fault line(N-S) to Satae-ri and flow to west to the Dutayeon area. The river meanders along geological structure or weak line at the Dutayeon area. The meandering channel was shorten by the meander cut which linked the thalweg line of meander loop ant the meander neck. As a result of this cut, the river cliff formed by the Satae cheon became the part of newly formed channel bed and the S-forms are formed. After the channel route stabilized, channel incised the rock with large potholes and undulating walls were formed. The channel width changes from 1m to 10m with restriction of the undulating walls, so this part can be regarded as inner channel or inner gorge. From the point of planar forms it also can be slot-type canyon.

• Korean Journal of Heritage: History & Science
• /
• v.52 no.1
• /
• pp.242-257
• /
• 2019

The Demilitarized Zone (DMZ) stretches two kilometers north and south from the Military Demarcation Line (MDL) of South and North Korea. This area was established as a weapons-free buffer zone when an armistice agreement was signed in 1953. However, there have been several very high-tension military standoffss over the past 65 years. On the South Korean side, civilian access to the Civilian Control Line (CCL) and beyond to the north has been restricted, and natural heritage has been well maintained. Natural heritage is defined as living things, their habitat and non-living things of the ecosystem which deserve to be protected. Research shows that a variety of flora and fauna, their habitat, marshes and geographical structures are found across the DMZ region. Although the DMZ region has not been such a good place for habitat conservation, we can say that this area may be the best location for restoration in terms of its variety of ecosystems and considerable land size. Restoration of course depends on future plans and management policies. This area, including the DMZ and the well-protected north of the CCL, will be the best habitat for endangered species of wild fauna and flora if we classify the various habitat types and create a habitat map. In doing this project, we need to include the estuary of the Han River and the lagoon (brackish water lake) of the East Sea coast. In addition, we must establish long-term plans for conservation and sustainable use and do international scientific research across the DMZ region in collaboration with scientists of South and North Korea and international experts. Mutual cooperation between the two Koreas for investigation and conservation efforts is paramount.

• Environmental Engineering Research
• /
• v.12 no.5
• /
• pp.203-210
• /
• 2007

Since the emissions composition from the household products have potentially been associated with health risks for building occupants, the chemical composition emitted from the products should be surveyed. The current study identified the emission composition for 42 liquid household products, using a purge-and-trap method. This evaluation was done by classifying the household products into five product classes (deodorizers, household cleaners, color removers, pesticides, and polishes). Nineteen compounds were chosen on the basis of selection criteria. The quality control program for purge-and-trap and analytical systems included tests of laboratory blank Tenax traps and blank water samples, and the determination of calibration equation, measurement precision, method detection limit (MDL), and recovery. The number of chemicals varied according to the product categories, ranging from 4 for the product category of bleaches to 12 for the product categories of air fresheners and nail color removers. For all product categories, the emission composition and concentrations varied broadly according to product. It is noteworthy that most household products emit limonene: 19 of 25 cleaning products; 5 of 6 deodorizers; 1 of 3 pesticides; 3 of 3 color removers; and 4 of 5 polishes. It was suggested that the use of household products sold in Korea could elevate the formation of secondary toxic pollutants in indoor environments, by the reaction of limonene with ozone, which entered indoor environments or might be generated by indoor sources such as electronic air cleaning devices and copying machines.

• Journal of the Korean Chemical Society
• /
• v.45 no.1
• /
• pp.40-44
• /
• 2001

Benomyl, one of the known endocrine disrupting chemicals, was analyzed to understand the its fate in water. Benomyl analysis process in water sample include the following sequential steps. Hydrolysis of benomyl into carbendazim, solvent extraction, concentration, and the concentration of final carbendazim solution was determined by LC/MS (TOF). Recoveries of the spiked samples were good with the range of 80.6 to 118.6% and the MDL was 1,600 times lower than that of LC/UVD method. The use of LC/MS (TOF) successfully eliminated the positive error incurred by interferencing materials in the matrix.

• Journal of the Korean Statistical Society
• /
• v.30 no.2
• /
• pp.179-192
• /
• 2001

When a statistical model has a hierarchical structure such as multilayer perceptrons in neural networks or Gaussian mixture density representation, the model includes distribution with unidentifiable parameters when the structure becomes redundant. Since the exact structure is unknown, we need to carry out statistical estimation or learning of parameters in such a model. From the geometrical point of view, distributions specified by unidentifiable parameters become a singular point in the parameter space. The problem has been remarked in many statistical models, and strange behaviors of the likelihood ratio statistics, when the null hypothesis is at a singular point, have been analyzed so far. The present paper studies asymptotic behaviors of the maximum likelihood estimator and the Bayesian predictive estimator, by using a simple cone model, and show that they are completely different from regular statistical models where the Cramer-Rao paradigm holds. At singularities, the Fisher information metric degenerates, implying that the cramer-Rao paradigm does no more hold, and that he classical model selection theory such as AIC and MDL cannot be applied. This paper is a first step to establish a new theory for analyzing the accuracy of estimation or learning at around singularities.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.38B no.1
• /
• pp.10-17
• /
• 2013

This thesis proposes an automatic embedded core generator system that supports branch prediction. The proposed system includes a dynamic branch prediction module that enhances execution speed of target applications by inserting history/direction flags into BTAC(Branch Target Address Cache). Entries of BHT(Branch History Table) and BTAC are determined based on branch informations extracted by simulation. To verify the effectiveness of the proposed branch prediction module, ARM9TDMI core including a dynamic branch predictor was described in SMDL and generated. Experimental results show that as the number of entry rises, area increase up to 60% while application execution cycle and BTAC miss rate drop by an average of 1.7% and 9.6%, respectively.

• Proceedings of the Korean Society for Bioinformatics Conference
• /
• 2003.10a
• /
• pp.164-169
• /
• 2003

In this paper, we propose the integrated Bayesian network framework to reconstruct genetic regulatory networks from genome expression data. The proposed model overcomes the dimensionality problem of multivariate analysis by building coherent sub-networks from confined gene clusters and combining these networks via intermediary points. Gene Shaving algorithm is used to cluster genes that share a common function or co-regulation. Retrieved clusters incorporate prior biological knowledge such as Gene Ontology, pathway, and protein protein interaction information for extracting other related genes. With these extended gene list, system builds genetic sub-networks using Bayesian network with MDL score and Sparse Candidate algorithm. Identifying functional modules of genes is done by not only microarray data itself but also well-proved biological knowledge. This integrated approach can improve there liability of a network in that false relations due to the lack of data can be reduced. Another advantage is the decreased computational complexity by constrained gene sets. To evaluate the proposed system, S. Cerevisiae cell cycle data [1] is applied. The result analysis presents new hypotheses about novel genetic interactions as well as typical relationships known by previous researches [2].