• Title/Summary/Keyword: M-H plot

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Oxide Nanolayers Grown on New Ternary Ti Based Alloy Surface by Galvanic Anodizing-Characteristics and Anticorrosive Properties

  • Calderon Moreno, J.M.;Drob, P.;Vasilescu, C.;Drob, S.I.;Popa, M.;Vasilescu, E.
    • Corrosion Science and Technology
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    • v.16 no.5
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    • pp.257-264
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    • 2017
  • Film of new Ti-15Zr-5Nb alloy formed during galvanic anodizing in orthophosphoric acid solution was characterized by optical microscope, scanning electron microscope (SEM), energy dispersive spectroscopy (EDS), and Raman micro-spectroscopy. Its anticorrosive properties were determined by electrochemical techniques. The film had a layer with nanotube-like porosity with diameters in 500-1000 nm range. The nano layer contained significant amounts of P and O as well as alloying element. Additionally, Raman micro-spectroscopy identified oxygen as oxygen ion in $TiO_2$ anatase and phosphorous as $P_2O_7{^{4-}}$ ion in phosphotitanate compound. All potentiodynamic polarization curves in artificial Carter-Brugirard saliva with pH values (pH= 3.96, 7.84, and 9.11) depending on the addition of 0.05M NaF revealed nobler behavior of anodized alloy and higher polarization resistance indicating the film is thicker and more compact nanolayer. Lower corrosion rates of the anodized alloy reduced toxicity due to less released ions into saliva. Bigger curvature radii in Nyquist plot and higher phase angle in Bode plot for the anodized alloy ascertain a thicker, more protective, insulating nanolayer existing on the anodized alloy. Additionally, ESI results indicate anodized film consists of an inner, compact, barrier, layer and an outer, less protective, porous layer.

Experimental Study on Side Impact Characteristics for Automotives Door Module (자동차용 도어 모듈의 측면 충돌특성에 관한 실험적 연구)

  • Jeon, S.J.;Kim, M.H.;Lee, G.B.;Lee, M.Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.10a
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    • pp.318-318
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    • 2009
  • The door stiffness is one of the important factors side impact. Generally, the researches have been conducted on the assembled door module. This study is to analysis the side impact characteristics for automotives door module. The impact characteristics have been determined by door module side impact test machine. To determine the initial, intermediate and peak crush resistances use the plot of load versus displacement and obtain the integral of the applied load with respect to the crush distances specified below for each door tested. The initial crush resistance is the average force required to deform the door through the initial 6 inches of crush. The intermediate crush resistance is the average force required to deform the door through the initial 12 inches of crush. The peak crush resistance will be directly obtained from the plot of load versus displacement since it is the largest force required to deform the door through the entire 18 inches crush distance. The data are used to determine if a specific vehicle or item of automotives equipment meets the minimum performance requirements of the subject Federal Motor Vehicle Safety Standard(FMVSS). FMVSS Static 214, Side impact protection, specifies performance requirements for protection of occupants in side impact crashes.

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Optimization of the Sulfur-oxidzing Bacteria, Thiobacillus novellus SRM (황 산화 세균인 Thiobacillus novellus SRM 성장 최적화)

  • 권규혁;차월석;고한철;이광연;박돈희;차진명
    • KSBB Journal
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    • v.18 no.6
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    • pp.443-447
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    • 2003
  • The microorganism was isolated from the night soil treatment plant for the removal of sulfur compounds. The growth conditions of the sulfur-oxidizing bacteria were investigated and the isolate characterized as Thiobacillus noveilus SRM. The optimal pH of Thiobacillus novellus SRM on cell growth was pH 7.0 and the optimal temperature was 30$^{\circ}C$ and the optimal air flow rate was 1 vvm, respectively. As a results of cell growth from the Monod plot, the specific growth rate was 0.032 hr$\^$-l/, $V_{max}$ was 1.43 hr$\^$-l/ and $K_{m}$ was 0.32, respectively. The thiosulfate oxidation by Thiobacillus novellus SRM was made of sulfate ion. The sulfate ion reduced pH and decreased cell growth.

Studies on the Salt Movement of Upland Soil in Reclaimed Tidal Land (간척지(干拓地) 밭토양(土壤)의 염류이동(鹽類移動)에 관(關)한 연구)

  • Lee, Jong-Sik;Kim, Jong-Gu;Yoo, Chul-Hyun;Kang, Jong-Gook;Kim, Ho-Jung
    • Korean Journal of Soil Science and Fertilizer
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    • v.24 no.1
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    • pp.28-34
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    • 1991
  • This study was carried out to investigate the salt movement in upland soils in reclaimed region (Kye-Hwa Do). The results obtained were summarized as follows : 1. The cation content in ground water increased during time course. but in the case of land-surface water the content was variable, and $K^+$ was lower than that of $Na^+$ and $M^{+2}$. At the L. S. P(Low salinity plot) under rainproof condition, the salinity was directly proportional to soil water content, but at the H. S. P (High salinity plot) the tendency was no reversed. 3. In condition of rainproof, the amount of available phosphorous was higher at the H. S. P than at the L. S. P. 4. Positive correlation was obtained between the soil water content and available phosphorous content at the rainfall plot, but there was no significance at the surface soil of the rainproof plot. 5. SAR (Sodium adsorption ratio) and anion ($Cl^-$, $SO_4{^{2-}}$) contents in soil were repressed in the order of black vinyl>white vinyl>rice straw>control.

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The Influence of Ventilation and Shade on the Mean Radiant Temperature of Summer Outdoor (통풍과 차양이 하절기 옥외공간의 평균복사온도에 미치는 영향)

  • Lee, Chun-Seok;Ryu, Nam-Hyung
    • Journal of the Korean Institute of Landscape Architecture
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    • v.40 no.5
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    • pp.100-108
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    • 2012
  • The purpose of the study was to evaluate the influence of shading and ventilation on Mean Radiant Temperature(MRT) of the outdoor space at a summer outdoor. The Wind Speed(WS), Air Temperature(AT) and Globe Temperature(GT) were recorded every minute from $1^{st}$ of May to the $30^{th}$ of September 2011 at a height of 1.2m above in four experimental plots with different shading and ventilating conditions, with a measuring system consisting of a vane type anemometer(Barini Design's BDTH), Resistance Temperature Detector(RTD, Pt-100), standard black globe(${\O}$ 150mm) and data acquisition systems(National Instrument's Labview and Compfile Techs' Moacon). To implement four different ventilating and shading conditions, three hexahedral steel frames, and one natural plot were established in the open grass field. Two of the steel frames had a dimension of $3m(W){\times}3m(L){\times}1.5m(H)$ and every vertical side covered with transparent polyethylene film to prevent lateral ventilation(Ventilation Blocking Plot: VP), and an additional shading curtain was applied on the top side of a frame(Shading and Ventilation Blocking Plot: SVP). The third was $1.5m(W){\times}1.5m(L){\times}1.5m(H)$, only the top side of which was covered by the shading curtain without the lateral film(Shading Plot: SP). The last plot was natural condition without any kind of shading and wind blocking material(Natural Open Plot: NP). Based on the 13,262 records of 44 sunny days, the time serial difference of AT and GT for 24 hour were analyzed and compared, and statistical analysis was done based on the 7,172 records of daytime period from 7 A.M. to 8 P.M., while the relation between the MRT and solar radiation and wind speed was analyzed based on the records of the hottest period from 11 A.M. to 4 P.M.. The major findings were as follows: 1. The peak AT was $40.8^{\circ}C$ at VP and $35.6^{\circ}C$ at SP showing the difference about $5^{\circ}C$, but the difference of average AT was very small within${\pm}1^{\circ}C$. 2. The difference of the peak GT was $12^{\circ}C$ showing $52.5^{\circ}C$ at VP and $40.6^{\circ}C$ at SP, while the gap of average GT between the two plots was $6^{\circ}C$. Comparing all four plots including NP and SVP, it can be said that the shading decrease $6^{\circ}C$ GT while the wind blocking increase $3^{\circ}C$ GT. 3. According to the calculated MRT, the shading has a cooling effect in reducing a maximum of $13^{\circ}C$ and average $9^{\circ}C$ MRT, while the wind blocking has heating effect of increasing average $3^{\circ}C$ MRT. In other words, the MRT of the shaded area with natural ventilation could be cooler than the wind blocking the sunny site to about $16^{\circ}C$ MRT maximum. 4. The regression and correlation tests showed that the shading is more important than the ventilation in reducing the MRT, while both of them do an important role in improving the outdoor thermal comfort. In summary, the results of this study showed that the shade is the first and the ventilation is the second important factor in terms of improving outdoor thermal comfort in summer daylight hours. Therefore, it can be apparently said that the more shade by the forest, shading trees etc., the more effective in conditioning the microclimate of an outdoor space reducing the useless or even harmful heat energy for human activities. Furthermore, the delicately designed wind corridor or outdoor ventilation system can improve even the thermal environment of urban area.

Substituted Phenyl 2-Thiophenecarboxylates and Benzoates:Synthesis, NMR Spectra, and Aromaticity Index

  • Lee, Chang Gyu;Yu, Ji Suk;Park, Jong Seok
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.49-55
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    • 2000
  • A series of m-, and p-substituted phenyl 2-thiophenecarboxylates and benzoates was prepared by the reaction of the corresponding acyl chlorides and phenols. Their $^1H$ and $^{13}C$ NMR chemical shifts were analyzed using single substituent parameter (S SP) and dual substituent parameter (DSP) methods. The relative aromaticity index of thiophene was estimated to be 0.92 from the plot of the chemical shift of the carbonyl carbons of the thienoyl esters against chemical shift of the carbonyl carbons of the benzoyl esters.

Site Characteristics and Carbon Dynamics of the Gwangneung Deciduous Natural Forest in Korea

  • Lim, Jong-Hwan;Shin, Joon-Hwan;Kim, Choonsig;Oh, Jeong-Soo
    • The Korean Journal of Quaternary Research
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    • v.17 no.2
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    • pp.163-163
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    • 2003
  • The study area, Kwangneung Experiment Forest (KEF) is located on the west-central portion of Korean peninsula and belongs to a cool-temperate broadleaved forest zone. At the old-growth deciduous forest near Soribong-peak (533.1m) in KEF, we have established a permanent plot and a flux tower, and the site was registered as a KLTER site and also a KoFlux site. In this study, we aimed to present basic ecological characteristics and synthetic data of carbon budgets and flows, and some monitoring data which are essential for providing important parameters and validation data for the forest dynamics models or biogeochemical dynamics models to predict or interpolate spatially the changes in forest ecosystem structure and function. We made a stemmap of trees in 1 ha plot and analyzed forest stand structure and physical and chemical soil characteristics, and estimated carbon budgets by forest components (tree biomass, soils, litter and so on). Dominant tree species were Quercus serrata and Carpinus laxiflora, and accompanied by Q. aliena, Carpinus cordata, and so on. As a result of a field survey of the plot, density of the trees larger than 2cm in DBH was 1,473 trees per ha, total biomass 261.2 tons/ha, and basal area 28.0 m2/ha. Parent rock type is granite gneiss. Soil type is brown forest soil (alfisols in USDA system), and the depth is from 38 to 66cm. Soil texture is loam or sandy loam, and its pH was from 4.2 to 5.0 in the surface layer, and from 4.8 to 5.2 in the subsurface layer. Seasonal changes in LAI were measured by hemispherical photography at the l.2m height, and the maximum was 3.65. And the spatial distributions of volumetric soil moisture contents and LAIs of the plot were measured. Litterfall was collected in circular littertraps (collecting area: 0.25m2) and mass loss rates and nutrient release patterns in decomposing litter were estimated using the litterbag technique employing 30cm30cm nylon bags with l.5mm mesh size. Total annual litterfall was 5,627 kg/ha/year and leaf litter accounted for 61% of the litterfall. The leaf litter quantity was highest in Quercus serrata, followed by Carpinus laxiflora and C. cordata, etc. Mass loss from decomposing leaf litter was more rapid in C. laxiflora and C. cordata than in Q. serrata litter. About 77% of C. laxiflora and 84% of C. cordata litter disappeared, while about 48% in Q. serrata litter lost over two years. The carbon pool in living tree biomass including below ground biomass was 136 tons C/ha, and 5.6 tons C/ha is stored in the litter layer, and about 92.0 tons C/ha in the soil to the 30cm in depth. Totally more than about 233.6 tons C/ha was stored in DK site. And then we have drawn a schematic diagram of carbon budgets and flows in each compartment of the KEF site.

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Effect of By-product Gypsum on Soil Erosion at Burned Forest Land (부산물 석고를 이용한 산불피해 지역 토양유실 방지)

  • Kim, Kye-Hoon;Jung, Chang-Wook
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.3 no.4
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    • pp.52-59
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    • 2000
  • This study was carried out to find out effect of by-product gypsum on reducing soil erosion at the sloping burned area at Sampo-ri, Gosung-gun in Kangwon-province during the period between June 28 and Sept. 30, 2000. Four experimental plots ($1.2m{\times}10m$) were prepared at the study area with slopes $15^{\circ}{\sim}18^{\circ}$ where forest fire took place twice during last 4 years. Phosphogypsum (PG) was applied to the soils of the 4 plots at the rates of 0 (control), 5, 7.5, and 10 ton/ha, respectively. Amount of rainfall, runoff, and soil loss were measured 7 times during the study. In the beginning, the amounts of runoff and soil loss from the PG treated plots were not different from those from the control plot due to steepness of the plots. However, the difference between the amount of runoff and soil loss from the PG treated plots and those from the control became apparent over time. The effect of PG treatment lasted until at least 870 mm of rainfall. Compared to the cumulative runoff from the control plot, the cumulative runoff from the plots treated with 5, 7.5, and 10 ton/ha PG decreased 7%, 31 %, and 35%, respectively. The cumulative soil loss from the plots treated with 5, 7.5, and 10 ton/ha PG decreased 44%, 53%, and 77% compared to that from the control plot. Strong acidity of PG (pH 2.0~2.5) did not affect the acidity of the soil and runoff.

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Fly Ash Application for Reduction of Acid Mine Drainage (AMD) as Runoff and Leachate Released from Mine Waste Disposal Sites

  • Oh, Se Jin;Moon, Sung Woo;Oh, Seung Min;Kim, Sung Chul;Ok, Yong Sik;Lee, Bup Yeol;Lee, Sang Hwan;Yang, Jae E.
    • Korean Journal of Soil Science and Fertilizer
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    • v.47 no.6
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    • pp.533-539
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    • 2014
  • Mine wastes such as acid mine drainage (AMD) can cause the detrimental effects on surrounding environment, thereby eventually threatening human health. Main objective of this study was to evaluate the neutralizing effect of fly ash (FA) as a stabilizing material AMD. Field plot was constructed in a coal waste depot which has caused aluminium-whitening adjacent to the stream. Different mixing ratios of FA were applied on a top of the soil, and then the physicochemical properties of runoff and soil were monitored. Constructed plots were as following: control (mine waste only (W)), mine waste + 20% ($w\;w^{-1}$)of FA (WC20M), mine waste + 40% ($w\;w^{-1}$)of FA (WC40M), and WC40M dressed with a fresh soil at the top (WC40MD). Result showed that initial pH of runoff in control was 5.09 while that in WC40M (7.81) was significantly increased. For a plot treated with WC40M, the concentration of Al in runoff was decreased to $0.22mg\;L^{-1}$ compared to the W as the control ($4.85mg\;L^{-1}$). Moreover, the concentration of Fe was also decreased to less than half at the WC40M compared to the control. Application of FA can be useful for neutralizing AMD and possibly minimizing adverse effect of AMD in mining area.

The Study of Servo-Parameter Tuning Technique for 6-Axes Articulated Robot Manipulator in Consideration of Dynamic Characteristics (동적 특성을 고려한 6축 로봇의 서보 파라미터 튜닝에 관한 연구)

  • Chung, W.J.;Kim, H.G.;Lee, C.M.;Hong, D.S.;Park, S.G.;Seo, Y.G.;Lee, G.S.
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.16 no.5
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    • pp.1-6
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    • 2007
  • This paper presents a new experimental Servo-Parameter tuning technique for a 6-axes articulated robot manipulator, especially considering robot's dynamics. First of all, investigation for proportional gain of velocity control loop by using a Dynamic Signal Analyzer(DSA) is performed. Using the FUNCTION characteristic of DSA based on the Bode plot, the Bode plot of open loop transfer function can be obtained. In turn, the integral gain of a servo controller can be found out by using the integration time constant extracted from the Bode plot of open loop transfer function. In the meanwhile, the positional gain of the servo controller can be obtained by using the Bode plot of the closed loop transfer function. Using the experimental gain tuning technique proposed in this paper, the testing linear motion of DR6-II robot has been shown to be more accurate rather than the motion with a conventional(empirical) gain tuning technique in Doosan Mecatec Co., Ltd., by improving the dynamic response of the robot as well as synchronizing each joint velocity according to the positional command of an end-effector.