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Effect of Annealing on the Pitting Corrosion Resistance of Anodized Aluminum-Magnesium Alloy Processed by Equal Channel Angular Pressing

  • Son, In-Joon;Nakano, Hiroaki;Oue, Satoshi;Kobayashi, Shigeo;Fukushima, Hisaaki;Horita, Zenji
    • Corrosion Science and Technology
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    • v.6 no.6
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    • pp.275-281
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    • 2007
  • The effect of annealing on the pitting corrosion resistance of anodized Al-Mg alloy (AA5052) processed by equal-channel angular pressing (ECAP) was investigated by electrochemical techniques in a solution containing 0.2 mol/L of $AlCl_3$ and also by surface analysis. The Al-Mg alloy was annealed at a fixed temperature between 473 and 573 K for 120 min in air after ECAP. Anodizing was conducted for 40 min at $100-400A/m^2$ at 293 K in a solution containing 1.53 mol/L of $H_2SO_4$ and 0.0185 mol/L of $Al_2(SO_4)_3$. The internal stress generated in anodic oxide films during anodization was measured with a strain gauge to clarify the effect of ECAP on the pitting corrosion resistance of anodized Al-Mg alloy. The time required to initiate the pitting corrosion of anodized Al-Mg alloy was shorter in samples subjected to ECAP, indicating that ECAP decreased the pitting corrosion resistance. However, the pitting corrosion resistance was greatly improved by annealing after ECAP. The time required to initiate pitting corrosion increased with increasing annealing temperature. The strain gauge attached to Al-Mg alloy revealed that the internal stress present in the anodic oxide films was compressive stress, and that the stress was larger with ECAP than without. The compressive internal stress gradually decreased with increasing annealing temperature. Scanning electron microscopy showed that cracks occurred in the anodic oxide film on Al-Mg alloy during initial corrosion and that the cracks were larger with ECAP than without. The ECAP process of severe plastic deformation produces large internal stresses in the Al-Mg alloy; the stresses remain in the anodic oxide films, increasingthe likelihood of cracks. It is assumed that the pitting corrosion is promoted by these cracks as a result of the higher internal stress resulting from ECAP. The improvement in the pitting corrosion resistance of anodized AlMg alloy as a result of annealing appears to be attributable to a decrease in the internal stresses in anodic oxide films

A study on the optical properties of $LiNbO_3$ single crystal grown by Floating zone method (Floating zone 법에 의한 $LiNbO_3$ 단결정의 광학적 특성에 관한 연구)

  • Ko, J.M.;Cho, H.;Kim, S.H.;Choi, J.K.;Auh, K.H.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.5 no.4
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    • pp.318-331
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    • 1995
  • The c - axis oriented single crystal of $LiNbO_3$ and $LiNbO_3$ : 5mol%MgO was success-fully grown by Floating zone method using halogen lamp as a heat source. The effects of the sintering condition of the feed rod and the atmosphere gas during the crystal growth on the be havior of the feed rod/melt interface were studied for growing crystal with the high quality, and then, the optimum growth conditions were determined by studying the experimental param eters, such as gas flow rate, pulling rate, rotation speeds of the feed rod and the seed. The grown crystals were analyzed using the chemical etching to observe the tch pattern and the ICP (Inductively Coupled Plasma) to determine the composition uniformity and the impurity content of Fe. The effects of additive (5 mol % MgO) on the transmittance and refractive index was, also, analyzed. In order to compare the nonlinear optical oharacteristics of $LiNbO_3$ with those of the other optical materials, the nonlinear optical refractive index ($n_2$) was calcu l lated using the measured refractive index.

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Tension Force Monitoring of Tension Type Ground Anchor Using Optical FBG Sensors (광섬유 센서를 이용한 인장형 그라운드 앵커의 장력측정)

  • Sung, Hyun-Jong;Kim, Young-Sang;Kim, Jae-Min;Park, Gui-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.27 no.6
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    • pp.17-26
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    • 2011
  • Ground anchor method is one of the most popular reinforcing technology in Korea. For the sound monitoring of slope reinforced by permanent anchor for a long period, monitoring the tension force of ground anchor is very important. However, special technology except conventional load cell has not been developed for this purpose. In this paper, a new method is described to replace the conventional strain gauge and V.W. type load cell which has been commonly used as a prestress force monitoring tool for a short-term and long-term. Four 11.5 m long strain detectable tension type anchors were made using FBG sensor embedded tendon since FBG sensor is smaller than strain gauge type load cell and does not have noise from electromagnetic wave. Each two set strain detectable tension type anchors were installed into the different ground conditions, i.e., soft rock and weathered granite soil. Prestress force of ground anchor was monitored during the loading-unloading step from in-situ pullout test using proposed FBG sensor embedded in the tendon and the conventional load cell Test results show that the prestress force monitored from FBG sensor may well be used practically, for it almost matches with that measured from expensive load cell.

Electrical properties of multilayer actuator and linear ultrasonic motor using low temperature PZW-PMN-PZT ceramics (저온소결 PZW-PMN-PZT 세라믹을 이용한 적층액츄에이터 및 선형초음파 모터의 전긱적 특성)

  • Lee, Il-Ha;Yoo, Ju-Hyun;Hong, Jae-Il;Jeong, Yeong-Ho;Yoon, Hyun-Sang
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.206-206
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    • 2008
  • 압전소자를 이용한 초음파 모터는 전자기적 원리로 동작하는 기존의 모터에 비해 구조가 간단하고 소형, 경량화가 가능하며 저속에서 큰 토크가 가능하고 ${\mu}m$단위 까지 정밀제어가 가능하다는 장점 등으로 인해 그 응용분야가 점차 확대되고 있다. 초음파 모터의 원리는 수평과 수직방향에서 변위가 타원형 운동을 형성하는 것이다. 따라서 선택한 타원운동의 방식에 의해서 모터의 형상이 달라진다. 초음파 모터는 액츄에이터를 사용하여 만들기 때문에 액츄에이터의 특성은 모터의 타원변위나 토크에 영향을 미친다. 단판형 액츄에이터에 비하여 적층 액츄에이터는 입력 임피던스를 낮추어 낮은 구동전압에서 구동이 가능하며 큰 변위와 토크를 발생하기 때문에 진동자의 수명 향상과 구동전압을 낮추기에 적합하다. 적층 액츄에이터는 변위량이나 응력 등을 개선하기 위해서 전기기계 결합계수(kp) 및 압전 d상수가 큰 재료가 요구되며, 고전압에서 장시간 구동 시 마찰에 의한 열손실을 감소시키기 위해 높은 기계적 품질계수(Qm)를 가져야한다. 적층 시 내부전극으로 사용하는 Pd, Pt가 함유된 전극은 가격이 비싸 제조비용을 상승시킨다. 상대적으로 값싼 Ag전극을 사용하면 비용절감을 할 수 있지만 융점이 낮아서 저온소결이 불가피하다. 따라서, 특성이 우수한 적층 액츄에이터를 제조하기 위해서 저손실, 저온소결 할 수 있는 액츄에이터 재료가 필요한 실정이다. L1-B4 혈 선혈 초음파 모터는 L1모드와 B4모드의 공진 주파수가 일치하여야 큰 변위를 얻을 수 있는데 이전의 논문에서 Atila를 이용한 시뮬레이션 결과를 분석한 봐 있다. 적층 액츄에이터의 층수를 5,7,9,11,13,15층으로 하여 L1-B4모드에서의 공진주파수를 비교한 결과 13 층일 때 두 모드가 비슷한 공진주파수를 보였고, 티원변위궤적도 다른 층수에 비해 크게 나타났다. 본 연구에서는 시뮬레이션 결과 가장 좋은 특성을 보인 13층 액츄에이터로 선형 초음파 모터를 제작하였다. 또한, 액츄에이터는 압전 및 유전특성이 우수한 저온소결 PZW-PMN-PZT세라믹을 이용하여 제작하였고, 내부전극으로 Ag전극을 사용하였다. 제작된 13 층 선형초음파모터를 가지고 프리로드 및 전압에 따른 속도를 조사하였고, 시뮬레이션 결과와 비교해 보았다.

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Performance of Underwater Communication in Low Salinity Layer at the Western Sea of Jeju (제주도 서부 해역의 저염수층을 고려한 수중통신 성능)

  • Bok, Tae-Hoon;Kim, Ju-Ho;Lee, Chong-Hyun;Bae, Jin-Ho;Paeng, Dong-Guk;Pang, Ig-Chan;Lee, Jong-Kil
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.48 no.1
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    • pp.16-24
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    • 2011
  • The sound speed of seawater can be calculated by the empirical formula as a function of temperature, salinity and pressure. It is little affected by salinity because the average salinity is 34 psu and varies within a few psu seasonally and spatially in the ocean. Recently, low-salinity water of 24 psu flows into the western sea area of Jeju Island due to the flood of the Yangtze River in China during summer, affecting sound speed profile. In this paper, it was analyzed how environmental changes affected to the underwater communication - the sound speed of low-salinity water was calculated, and the communication channel was estimated by the simulated acoustic rays while the transmitting and receiving depth and the range were varied with and without the low-salinity layer. And The BER (Bit error rate) was calculated by BPSK(Binary phase shift key) modulation and the effects of the low-salinity water on the BER was investigated. The sound speed profile was changed to have positive slope by the low-salinity layer at the sub-surface up to 20 m of depth, forming acoustic wave propagation channel at the sub-surface resulting in the decrease of most of the BER Consequently, this paper suggests that it is important to consider changes of the ocean environment for correctly analyzing the underwater communication and the detection capability.

An epidemiological survey of Cryptosporidium parvum infection in randomly selected inhabitants of Seoul and Chollanam-do (서울 및 전남 지역 주민의 작은와포자충 감염에 대한 역학조사)

  • 채종일;이상협
    • Parasites, Hosts and Diseases
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    • v.34 no.2
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    • pp.113-120
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    • 1996
  • An epidemiological survey was performed to know the status of Cwptespori,mum sp. infection among the people in Seoul and Chollanam-do in 1992. One village of Chollanam-do (Hwasun-gun) which showed the highest oocyst positive rate was re-surveyed in 1995 for human infection and for cattle also. The subjected areas consisted of 8 urban villages (: dongs) of Seoul and 4 urban (: dongs) and 7 rural (: myonsl villages of Chollanam-do. A total of 3,146 fecal samples was collected randomly, and smears were made from formalin-ether sediments. They were examined for Cwptosporinium oocysts by modified acid fast staining. The overall oocyst positive rate was 79% (248/3,146), but the rate was remarkably different between Seoul and Chollanam-do, 0.5% (4/853) and 10.6% (244/2,293), respectively The average size of oocysts was 4.8 ± 0.5 by 4.2 ± 0.5 ㎛, compatible with C. pcnlum. In Chollanam-do, rural villages showed significantly higher rate (14.0%) than urban villages (3.7%). Especially the people in Iyang-myon, Hwasun- gun, a typical rural village, revealed a very high rate of 40.0% (74/185). Adults aged 51-70 years revealed the highest positive rate among all age groups. At the re-survey of the same village of Hwasun-fun in 1995, 44 (35.2%) of 125 villagers and 14 (93.3%) of IS cattle examined were positive for C. pnnpum oocysts. The results suggest that C. pnnpum is highly prevalent in rural areas of Chollanam-do, and an important source or mode of infection seems to be contaminated water or contact with the feces of infected cattle.

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Effect of widening excavation in divergence section of a double-deck tunnel on its stability (복층터널 분기구 확폭구간 굴착에 따른 안정성 영향)

  • La, You-Sung;Kim, Yunhee;Lee, Kangil;Kim, Yongseong;Kim, Bumjoo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.22 no.4
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    • pp.435-450
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    • 2020
  • The divergence section of a double-deck tunnel can be divided into a 'widening pre-divergence section', a large cross-section with a cap shape and a 'post-divergence section' where the separation between the main and the branch tunnel is made. Since the cross-section of the widening pre-divergence section is considerably larger than that of the post-divergence section, the influence of excavation due to the different sizes and shapes in the cross-section should be considered in the examination of the tunnel stability. In this study, the effect of the preceding excavation, that is the excavation of the widening pre-divergence section, on excavation stability of the post-divergence section was examined by varying the excavation methods and bench lengths through 3D finite element analysis. The results showed that although the effects of the excavation methods and the bench lengths are not significant on the variation of principal stresses, the preceding excavation causes a relatively large variation on the stresses which may have an impact on the stability of the post-divergence section from the comparison of Stress-Strength Ratio (SSR) between the cases with and without the consideration of the preceding excavation effect by 2D finite element analysis.

The Second Annealing Effect on Giant Magnetoresistance Properties of PtMn Based Spin Valve (이차 열처리가 PtMn계 스핀밸브의 거대자기저항 특성에 미치는 영향)

  • 김광윤;김민정;김희중
    • Journal of the Korean Magnetics Society
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    • v.11 no.2
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    • pp.72-77
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    • 2001
  • Top spin valve films with PtMn antiferromagnetic layers were deposited using a multi-target dc magnetron sputtering in (100)Si substrates overcoated with 500 $\AA$ of Al$_2$O$_3$. Firstly, the post-deposition annealing was performed at 270$\^{C}$ in a unidirectional magnetic field of 3 kOe to induce the crystallographic transformation of the PtMn layer from a fcc (111) to a fct (111) structure. Secondly, the spin valve films were annealed without magnetic fields and magnetic properties were measured. In Si/A1$_2$O$_3$ (500$\AA$)/Ta(50$\AA$)NiFe(40$\AA$)/CoFe(17$\AA$)/Cu(28$\AA$)/CoFe (30$\AA$)PtMn(200$\AA$)Ta(50$\AA$) top spin valve samples, the MR ratio decreased slowly with increasing annealing temperature up to 325$\^{C}$. But above 325$\^{C}$, the MR ratio decreased rapidly to 1%, due to a collapse of the exchange coupling between a antiferromagnetic layer and a pinned layer with increasing annealing temperature. Also above 325$\^{C}$, the exchange biased field rapidly decreased and the interlayer coupling field rapidly increased with increasing annealing temperature. A change in the interlayer coupling field was resulted from the increase in interface roughness due to Mn-interdiffusion through the grain boundaries. We confirmed the temperature in changing magnetic properties agreed well with the blocking temperature of PtMn based spin valve structure.

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A Simulation Study for Evaluation of Alternative Plans and Making the Upper-limit for Improvement in Productivity of Flow-shop with Considering a Work-wait Time (흐름생산 공정에서의 작업 대기시간을 고려한 공정 개선 상한선 도출 : H사의 공정 개선 계획안 시뮬레이션 사례를 중심으로)

  • Song, Young-Joo;Woo, Jong-Hun;Lee, Don-Kun;Shin, Jong-Gye
    • Journal of the Korea Society for Simulation
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    • v.17 no.2
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    • pp.63-74
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    • 2008
  • The design of best efficient production process is common requirements of the production strategy department and the process planning department to maximize the revenue and accomplish target production volumes in the production periods. And they use several general methods for that-line-balancing, removing of the bottle-neck process, facility ramp-up, increasing of the worker's utilization, etc. But, those methods have depended on analytic, static and arithmetic calculations, yet. So, irregular work-waiting time causing the delay time isn't include in extracting production capacity, especially in the line production process. The work-waiting time is changed irregularly along the variation of each machine and very important for calculate real product lead-time and forecasting target production volumes. At this thesis, i'm going to mention the importance of the delay time of conveyor system which can be extracted by discrete-event simulation. And suggest it as a new main variable that must be considered at designing new production system. Then experimented and tested that's effects in the H-company case, conveyor based line production process.

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MCC 입자의 표면화학적 특성에 따른 부유부상 효과

  • 이학래;이진희;허용성;한신호;조중연
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2000.11a
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    • pp.41-41
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    • 2000
  • 부유부상 공정은 현재 신문고지와 사무용 고지의 탈묵을 통한 신문용지 및 화장지 제조 에 널리 사용되고 있는 고지재활용을 위한 핵심공정이다. 하지만 이들 공정은 갈수록 열악 해지는 국내 고지원료의 품질변화에 따라서 잉크 및 토너의 분리효율이 저하되고 있어 생산 되는 탈묵 펄프의 품질저하, 리젝트 발생량의 증대, 폐수 처리공정의 부하 증가 등 다양한 문제점을 발생시키고 있어 이에 대한 대책의 수립이 시급히 요청되고 있다. 현재와 같이 다양한 형태의 잉크 및 인쇄방식으로 인쇄된 많은 종류의 재활용지가 원료 로 투입되고 있는 경우 탈묵공정의 효율 향상을 위해서는 부유부상 공정에 대한 좀 더 체계 적이고 논리적인 접근이 필요하다. 이러한 문제점을 극복하기 위해 먼저 고지 재활용 공정 의 핵심 단위공정인 부유부상 공정에 관련된 복잡한 문제점을 단순화하여 고상 및 액상의 표면화학적 특성을 평가하고, 이에 따른 부유부상 공정의 효율을 분석하였다. 본 연구에서는 부유부상 공정을 기초과학적 측면에서 구명하기 위해 마이크로 크리스탈린 셀룰로오스(Microcrystalline cellulose: MCC)를 모델 물질로 사용하였고, 친수성 의 표면 특 성을 나타내는 MCC의 표면 특성을 바꾸기 위하여 AKD(alkyl ketene dimer)로 처리비율을 달리하여 사이징 처리하였다. 부유부상 실험에 사용된 MCC는 친수성을 띠는 것과 소수성 을 부여한 것을 구별하고 그 비율을 백색도를 통해 측정하기 위하여 자체적으로 친수성을 가지는 MCC는 세척 견뢰도가 높은 검은색 염료로 염색하였다. 준비된 친수성과 소수성 M MCC의 혼합비율 별로 패드를 작성하여 백색도를 측정함으로써 검량선을 작성하였다. 또한 부유부상 시간에 따른 제거효율을 알아보기 위하여 부유부상 시간별로 각각의 리젝트율과 수율올 측정하고, 리젝트 시료로부터 패드를 제조하여 백색도를 측정하였다. 실험 결과 소수성 MCC의 소수화 정도에 따라서 리젝트율이 증가하였으며, 이를 통해 표 면에 소수성을 띠는 입자는 소수성이 강할수록 부유부상공정에서 제거율이 증가한다는 것을 확인하였다. 부유부상 처리한 MCC로 패드를 제조한 뒤 백색도를 비교한 결과에서도 이를 확인하였다. 한편 리젝트로 함께 제거된 MCC 내에 존재하는 친수성 MCC의 양은 극히 미 세하였다. 또한 부유부상를 실시하는 초기에 상당량의 리젝트가 발생함을 확인하였는데, 이 는 전체 부유부상을 통해 제거되는 양의 45-68%였다. 한편 부유부상이 진행됨에 따라서 리젝트 양의 증가폭이 둔화되는 경향을 나타내었다. 이러한 경향은 MCC의 소수성이 강할 수록 더욱 뚜렷하게 나타났다. 이를 통해 계 내로부터 소수성인 물질이 급속하게 제거됨을 알 수 있었으며 필요 이상의 부유부상 처리는 잉크제거 효율을 높일 수는 있으나 소모되는 시간에 비하여 비효과적임을 알 수 있었다.

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