• Title/Summary/Keyword: Lyocell

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Evaluation of Heat Resistance of Lyocell-based Carbon/Phenolic for Aerospace (항공우주용 리오셀계 탄소/페놀릭 복합재료의 내열 성능 평가)

  • Seo, Sang-Kyu;Kim, Yun-Chul;Bae, Ji-Yeul;Hahm, Hee-Chul;Hwang, Tae-Kyung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.5
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    • pp.355-363
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    • 2021
  • Heat resistance performance evaluation and thermal analysis were performed to confirm the applicability of the lyocell-based carbon/phenolic composite material for heat-resistant parts for aerospace. Heat resistance performance evaluation of carbon/phenolic was conducted by Thermal Protection Evaluation Motor (TPEM). In this paper, boundary layer integration code considering the boundary layer analysis of combustion gas and MSC-Marc 2018 considering ablation and thermal pyrolysis were used for the thermal analysis. The ablation and thermal insulation performance were analyzed by the pressure curve of test motor and the cut carbon/phenolic specimens. The thermal response of the lyocell-based carbon/phenolic material was similar to that of the rayon-based carbon/phenolic material. Based on the results through the combustion test, the applicability of heat-resistant parts for aerospace to which domestic lyocell-based carbon fibers were applied was confirmed.

The Structural Change and Hand of Cellulosic Fiber treated with N-methylmorpholine-N-oxide (N-Methylmorpholine-N-Oxide 처리에 의한 셀룰로오스 직물의 구조변화와 태분석)

  • 조규민;강건우;임용진;김미경;김태경;이혜정
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.43-50
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    • 2003
  • N-methylmorpholine-N-oxide(NMMO) is recently hewn as a solvent dissolving cellulose to produce a new regenerated cellulosic fiber, lyocell. In this study, four kinds of cellulosic fibers (lyocell, regular cotton, treated cotton with 50% and 75% NMMO aqueous solution) was examined and compared in terms of mechanical properties and dyeability. The swelling of cotton treated with NMMO aqueous solution is higher than that of cotton treated with water. In dyeing rate, the cotton treated with NMMO was faster than regular cotton. NMMO treatment decreased the crystallinity of cotton fabrics and improved their softness and smoothness.

Effect of Processing and Reactive Dyeing on Swelling and Pore Structure of Lyocell Fibers

  • Sasaki, Hiroaki;Donkai, Nobuo;Kasahara, Katusji
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.33-34
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    • 2003
  • Lyocell yarns were treated with NaOH, liquid ammonia, high pressure steam and polycarboxylic acids, and dyed with five reactive dyes. The water content of the samples was also measured by the centrifugal and chromatographic techniques. The total pore volume w as substantially increased by NaOH treatment, while decreased by high pressure steaming. The pore size distributions for the dyed samples were affected by the dyes used.

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The Effects of Scouring on Mechanical Properties and Appearance of Iyocell -NaOH Scouring vs. Enzymatic Scouring - (정련 방법에 의한 리오셀 섬유의 역학적 변화와 3D CAD SYSTEM에 의한 외관분석 -NaOH와 효소처리 중심으로-)

  • Park, Ji-Yang;Kim, Ju-Hea;Jeon, Dong-Won;Park, Young-Hwan
    • Journal of the Korean Society of Clothing and Textiles
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    • v.30 no.9_10 s.157
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    • pp.1485-1493
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    • 2006
  • This study was to investigate the effect of different scouring methods on mechanical properties and appearance of lyocell. Two different scouring methods were adopted for the study; one was the traditional scouring with alkali and the other was enzymatic scouring. Enzymatic scouring was carried with four different enzymes; C1 : Cellusoft L, C2 : Cellusoft UL, D1 : Denimax 992L, D2 : Denimax Acid XCL. The mechanical properties of scoured lyocell were measured using KES-FB. The appearance of scoured samples was analyzed by 3D CAD SYSTEM of i-Designer. While the untreated fabric showed the best linearity because it is stiff, alkali treated samples showed the worst dimensional stability and distorted easily. Enzyme treated samples, especially C1 treated samples showed the best dimensional stability. In addition, enzyme treated samples showed low bending rigidity compared to the alkali treated samples. It means that the enzyme treated samples are more flexible than alkali treated samples. However, the smoothness of the sample's surface treated by either of methods did not show much difference. From the study, it was suggested that the enzymatic scouring for lyocell could help to gain natural silhouette.

Study of the Crystal Structure of a Lyocell Precursor for Carbon Fibers (탄소섬유용 리오셀 전구체의 결정구조에 관한 연구)

  • Park, Gil-Young;Kim, Woo-Sung;Lee, Su-Oh;Hwang, Tae-Kyung;Kim, Yun-Chul;Seo, Sang-Kyu;Chung, Yong-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.23 no.5
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    • pp.36-42
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    • 2019
  • In this study, the pre-treatment of lyocell fabrics was performed using phosphoric acid (PA) as a phosphorus flame retardant and melamine resin (MR) as a cross-linking agent to fabricate carbon fabrics using lyocell fibers. The physical and chemical changes were investigated by thermogravimetric analysis (TGA), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD) and weight analysis. We confirmed that the weight yield of the carbon fabrics compared to the untreated fabrics increased by 14.7%, and width and length yield of the fabrics increased by 15% and 15.5%, respectively. This may be due to the effect of promoting the dehydration reaction of cellulose, forming char on the fiber surface, which induces a crosslinking reaction in the cellulose molecule and stabilizes the structure upon pyrolysis.

The Effect of Fusible Interlining on the Appearance related Properties & Mechanical Characteristics for the Lyocell Fabric(Part I) (리오셀직물의 심지접착에 따른 외관적 성능 및 역학적 특성(제1보))

  • 김인영;송화순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.25 no.7
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    • pp.1193-1202
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    • 2001
  • The goal of this research is to investigate the effect of fusible interlinings on the mechanical characteristics and appearance related values for the Lyocell fabrics. In this study, to establish optimum fusing conditions, peel strength of the fused fabrics depending on the fusing temperature, pressure and time was measured. Appearance related properties and mechanical characteristics of the fused fabrics ere determined. The reulst are as follows: In the fusing condition of $120^{\circ}C,\;3kgf/textrm{cm}^2$, 15sec, peel strength was excellent. Peel strength was excellent in the case of tencel/cotton fabric, with increasing cover factor of woven interlining, with twill and nonwoven interlining. Flex stiffness was increased in the case of tencel/cotton fabric, with increasing weight of woven interlining, with twill and nonwoven interlining. Drapability was excellent in the case of 100% tencel fabric, with decreasing weight of woven interlining, with plain and woven interlining. Crease recovery was excellent in the case of 100% tencel fabric, with increasing weight of woven interlining, with twill and woven interlining. Shear and bend properties were increased in the case of tencel/cotton fabric, with increasing weight of woven interlining, with plain and nonwoven interlining.

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Preparation and Characterization of Multiwalled Carbon Nanotubes/Lyocell Composite Fibers (다중벽 탄소나노튜브/리오셀 복합섬유의 제조 및 특성조사)

  • Lu, Jiang;Zhang, Huihui;Shao, Huili;Hu, Xuechao
    • Polymer(Korea)
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    • v.31 no.5
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    • pp.436-441
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    • 2007
  • In this work, the multiwalled carbon nanotubes(MWNTs) were functionalized with sodium dodecylbenzene sulfonate(SDBS) and then MWNTs/Lyocell composite fibers were prepared. The properties of MWNTs, the functionlization on the surface of MWNTs and their dispersion in the cellulose matrix were characterized by TEM, SEM, WAXD and FT-IR. The results showed that SDBS has been coated successfully onto the surface of the MWNTs by functionlization. This can improve effectively the dispersion uniformity of MWNTs in NMMO aqueous solution and is helpful to prepare a spinnable spinning dope. Moreover, the resultant MWNTs/Lyocell composite fibers still have cellulose II crystal structure, and their tensile strength and initial modulus increased with the increasing draw ratio and reached the optimal value with adding 1 wt% MWNTs. The thermal stability of the composite fiber was also improved by the addition of the MWNTs.