• 제목/요약/키워드: Luminous efficient

검색결과 72건 처리시간 0.019초

7층 적층구조 배면발광 청색 OLED의 발광 특성 연구 (A Study on the Bottom-Emitting Characteristics of Blue OLED with 7-Layer Laminated Structure)

  • 최규철;김덕열;장상목
    • 청정기술
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    • 제29권4호
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    • pp.244-248
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    • 2023
  • 최근 많은 정보를 신속하게 전달하기위한 방법으로 디스플레이의 역할은 아주 중요하며 다양한 색을 자연색에 가깝게 재현하기 위한 연구가 진행 중이다. 특히 정확하고 풍부한 색을 표현하기 위한 방법으로 발광 구조에 대한 연구가 진행되고 있다. 기술의 고도화, 디바이스의 소형화로 인해 작지만 높은 시인성과 에너지 소모에서 높은 효율을 가진 디스플레이의 필요성이 지속적으로 증가되고 있는 실정이다. OLED의 효율을 향상시키기 위해서는 운반자 주입의 향상, 전자와 정공이 수적인 균형을 이루며 효율적으로 재결합 할 수 있는 소자의 구조, 발광 효율이 큰 물질의 개발 등 OLED의 효율을 향상시키고자 하는 노력은 다방면에서 진행되고 있다. 본 연구에서는 7층 적층구조 배면발광 청색 OLED 소자의 전기적 특성 및 광학적 특성을 분석하였다. 소자는 제작이 용이하며, 고효율 및 고휘도화가 가능한 Blue 발광물질인 4,4'-Bis(carbazol-9-yl)biphenyl : Ir(difppy)2(pic)를 사용하였다. OLED 소자 제작은 SUNICEL PLUS 200 시스템을 이용하여 5×10-8 Torr 이하의 고진공 상태에서 In-Situ 방식으로 증착하였다. Electron or Hole Injection Layer(EIL or HIL) Electron or Hole Transport Layer(ETL or HTL) 등이 추가된 5층 구조에 Electron or Hole Blocking Layer(EBL or HBL)을 추가한 7층 구조로 실험을 진행하였다. 제작한 소자의 전기적, 광학적 특성을 분석한 결과 EBL 층과 HBL층을 삽입하여 색의 확산을 방지한 소자는 색 순도가 우수하게 나타났다. 본 연구결과를 이용하여 청색 OLED 디스플레이 소자의 연구 개발 기초 및 실용화에 크게 기여할 것으로 기대된다.

Excimer-Based White Phosphorescent OLEDs with High Efficiency

  • Yang, Xiaohui;Wang, Zixing;Madakuni, Sijesh;Li, Jian;Jabbour, Ghassan E.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1520-1521
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    • 2008
  • There are several ways to demonstrate white organic light emitting diodes (OLEDs) for displays and solid state lighting applications. Among these approaches are the stacked three primary or two complementary colors light-emitting layers, multiple-doped emissive layer, and excimer and exciplex emission [1-10]. We report on white phosphorescent excimer devices by using two light emitting materials based on platinum complexes. These devices showed a peak EQE of 15.7%, with an EQE of 14.5% (17 lm/W) at $500\;cd/m^2$, and a noticeable improvement in both the CIE coordinates (0.381, 0.401) and CRI (81). Devices with the structure ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 12% FPt (10 nm) /26 mCPy: 2% Pt-4 (15 nm)/BCP (40 nm)/CsF/Al [device 1], ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4 (15 nm)/26 mCPy: 12% FPt (10 nm)/BCP (40 nm)/CsF/Al [device 2], and ITO/PEDOT:PSS/TCTA (30 nm)/26 mCPy: 2% Pt-4: 12% FPt (25 nm)/BCP (40 nm)/CsF/Al [device 3] were fabricated. In these cases, the emissive layer was either the double-layer of 26 mCPy:12% FPt and 15 nm 26 mCPy: 2% Pt-4, or the single layer of 26mCPy with simultaneous doping of Pt-4 and FPt. Device characterization indicates that the CIE coordinates/CRI of device 2 were (0.341, 0.394)/75, (0.295, 0.365)/70 at 5 V and 7 V, respectively. Significant change in EL spectra with the drive voltage was observed for device 2 indicating a shift in the carrier recombination zone, while relatively stable EL spectra was observed for device 1. This indicates a better charge trapping in Pt-4 doped layers [10]. On the other hand, device 3 having a single light-emitting layer (doped simultaneously) emitted a board spectrum combining emission from the Pt-4 monomer and FPt excimer. Moreover, excellent color stability independent of the drive voltage was observed in this case. The CIE coordinates/CRI at 4 V ($40\;cd/m^2$) and 7 V ($7100\;cd/m^2$) were (0.441, 0.421)/83 and (0.440, 0.427)/81, respectively. A balance in the EL spectra can be further obtained by lowering the doping ratio of FPt. In this regard, devices with FPt concentration of 8% (denoted as device 4) were fabricated and characterized. A shift in the CIE coordinates of device 4 from (0.441, 0.421) to (0.382, 0.401) was observed due to an increase in the emission intensity ratio of Pt-4 monomer to FPt excimer. It is worth noting that the CRI values remained above 80 for such device structure. Moreover, a noticeable stability in the EL spectra with respect to changing bias voltage was measured indicating a uniform region for exciton formation. A summary of device characteristics for all cases discussed above is shown in table 1. The forward light output in each case is approximately $500\;cd/m^2$. Other parameters listed are driving voltage (Bias), current density (J), external quantum efficiency (EQE), power efficiency (P.E.), luminous efficiency (cd/A), and CIE coordinates. To conclude, a highly efficient white phosphorescent excimer-based OLEDs made with two light-emitting platinum complexes and having a simple structure showed improved EL characteristics and color properties. The EQE of these devices at $500\;cd/m^2$ is 14.5% with a corresponding power efficiency of 17 lm/W, CIE coordinates of (0.382, 0.401), and CRI of 81.

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