• Title/Summary/Keyword: Luminescent materials

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Nonlinear, Optical and Luminescent Properties of xK2O-(33.3-x)BaO-16.7TiO2-50SiO2(mole%) Glasses (xK2O-(33.3-x)BaO-16.7TiO2-50SiO2(mole%) 유리의 비선형 광학 및 형광 특성)

  • Lee, Hoi-Kwan;Yoo, Eun-Sung;Chae, Su-Jin;Kang, Won-Ho
    • Journal of the Korean Ceramic Society
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    • v.43 no.9 s.292
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    • pp.569-574
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    • 2006
  • Transparent glass-ceramics containing fresnoite crystals have been prepared by controlled heat treatment in $K_2O-BaO-TiO_2-SiO_2$ and their nonlinear optical and luminescent properties were investigated using Maker fringe method and Spectrofluorometer. The second harmonic generation was observed in all samples and the values decreased with increasing $K_2O$ content. The luminescence of blue light at ${\sim}482nm$ could be observed and it was shown that the luminescent property was controlled by the $K_2O$ content.

Synthesis of Sr3Al2O6 Phosphors by Solid State Reaction and Its Luminescent Properties (고상법에 의한 Sr3Al2O6 형광체의 분말합성 및 발광특성)

  • Kim, Sue-Jin;Won, Hyung-Il;Won, Chang-Whan;Nersisyan, Hayk
    • Journal of the Korean Ceramic Society
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    • v.48 no.3
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    • pp.241-245
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    • 2011
  • A red strontium aluminate phosphor ($Sr_3Al_2O_6:Eu^{3+},Eu^{2+}$) is synthesized using a solid state reaction method in air and reducing atmosphere. The investigation of firing temperature indicates that a single phase of $Sr_3Al_2O_6$ is formed when the firing temperature is higher than $1300^{\circ}C$. The effect of firing temperature and doping concentration on luminescent properties are investigated. $Sr_3Al_2O_6$ phosphor exhibits the typical red luminescent properties of $Eu^{3+}$ and $Eu^{2+}$.

Preparation and Luminescent Characteristics of Phosphate-Based Phosphors (포페이트계열 형광체의 합성 및 광특성 평가)

  • Noh, Seh-Chul;Kim, You-Hyuk
    • Korean Journal of Materials Research
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    • v.12 no.1
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    • pp.21-26
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    • 2002
  • In order to search new phosphors for plasma display panel(PDP), phosphate hosts which has a host excitation band at around 150nm were prepared and their luminescent properties were investigated. In the preparation of $YPO_4: Eu\; and\; (Y,Gd)PO_4: Eu$ phosphors, the effect of oxide and oxalate starting materials on prepared phosphors were compared in terms of relative emission intensities and particle characteristics. The results showed that oxalate starting materials gave better performance in emission intensities and smaller size and more round shape phosphors which would be more applicable for high resolution display. Additionally, Gd, V, Nb and Ta ions were doped to $YPO_4:Eu$ and the luminescent properties of the resulant solid solutions were investigated to find efficient sensitizer. Among these ions, Gd, V and Nb ions increased the emission intensities of parent phosphor to around 10%. While Nb ion gave the best result in emission intensities, CIE color coordinate were improved by doping V ion into $YPO_4:Eu$ phosphor to give x=0.6523, y=0.3406 compared to commercial sample.

Effects of heat treatment and substrates on luminescent characteristics of $ZnGa_O_4:Mn$ thin film phosphor (열처리조건과 기판이 $ZnGa_O_4:Mn$ 박막 형광체의 발광특성에 미치는 영향)

  • Chung, Sung-Mook;Kim, Young-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05a
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    • pp.181-184
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    • 2004
  • The green emitting phosphor, $ZnGa_2O_4:Mn$ thin film with spinel structure were deposited by rf magnetron sputtering. Thin film phosphors were heat-treated in nitrogen, vacuum and air atmosphere, respectively. The effects of the substrates, heat-treatment conditions and the sputtering parameters were investigated. The growing behavior and luminescent properties of thin films depend on the crystallinity of the substrates. The Ga/Zn atomic ratios and luminescent characteristics were dependent on the annealing conditions.

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Luminescent characteristics of a blue-emitting $CaAl_2Si_2O_8:Eu^{2+}$ phosphor and the effect of boron ion substitution

  • Kwon, Byoung-Hwa;Vaidyanathan, Sivakumar;Li, Hui;Jang, Ho-Seoung;Yoo, Hyoung-Sun;Jeon, Duk-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.578-580
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    • 2008
  • Blue-emitting $CaAl_2Si_2O_8:Eu^{2+}(CAS:Eu^{2+})$ phosphor, prepared by solid-state reaction, is described in this paper. We researched the effect of boron ion substitution in the host materials. The phase and luminescent properties were investigated using the powder X-ray diffraction(XRD) and photoluminescence(PL) spectra.

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Synthesis and Luminescent Property Investigation of the $Mg_4GeO_2:Mn$ for LEDs

  • Lee, Seung-Jae;Park, Joung-Kyu;Kim, Kyung-Nam;Bae, Pan-Kee;Kim, Chang-Hae;Chang, Hyun-Ju;Kim, Yong-Rok
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1526-1528
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    • 2007
  • In this report, Manganese doped magnesium germanate ($Mg_4GeO_2:Mn$) phosphor has been synthesized by the solid state method. Also, this phosphor was prepared by simple process under an air atmosphere for oxidation of Mn. The prepared phosphor shows a main luminescent peak at 661nm. Therefore, this phosphor is possible to be applicable to white LED lamp by GaN or InGaN chips.

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Study of Synthesis and Property of Eu-PEG Phase Change Luminescent Materials (Eu-PEG로 구성된 상변환 발광재료의 합성 및 물성에 대한 연구)

  • Gu, Xiao-Hua;Xi, Peng;Shen, Xin-Yuan;Cheng, Bo-Wen
    • Polymer(Korea)
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    • v.32 no.4
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    • pp.305-312
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    • 2008
  • A novel TPC-PEG-TPC with active end-groups was obtained from the end-groups of polyethylene glycol (PEG) modified by terephthaloyl chloride (TPC). These active end-groups can link up with a rare earth ion, which is a luminescent center of a rare earth fluorescent complex. Complexes of Eu-PEG with novel ligands (TPC-PEG-PTC) were synthesized by the coordination of the active reactant (as the first ligand) and phenanthroline (as the second ligand) with $Eu^{3+}$.IR, $^1H$-NMR, element analysis, DSC, WAXD, fluorescent spectroscopy, TGA, and SEM were used to characterize the structure and properties of these complexes. The results showed that this type of complex is a heat storage material with the phase change character of polyethylene glycol (PEG) and the luminescent properties of europium. There was no thermal decomposition of the complex of Eu-PEG until $300^{\circ}C$. SEM showed that the complex of Eu-PEG can be dispersed in PE.

Combinatorial Synthesis and Screening of the $Eu^{2+}$-activated Phosphors for LED in the System CaO-$Al_2O_3-SiO_2$

  • Park, Seung-Hyok;Yoon, Ho-Shin;Kim, Chang-Hae;Jang, Ho-Gyeom
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.647-649
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    • 2004
  • We have synthesized phosphor in the system CaO-$Al_2O_3-SiO_2$ by combinatorial polymerized-complex method. The application of combinatorial synthesis and characterization of luminescent materials has been enlarged to identification and optimization in interesting new phosphor. In this study, we investigated luminescent properties of above-mentioned materials by excitation and emission spectra. In $Eu^{2+}$ activated $Ca_1Al_2Si_2O_8$ phosphor emit the blue light.

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Synthesis and Luminescent Property Investigation of the $Lu_3Al_5O_{12}$:Ce for the White LEDs

  • Lee, Seung-Jae;Park, Joung-Kyu;Bae, Pan-Kee;Kim, Chang-Hae;Chang, Hyun-Ju;Kim, Yong-Rok
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.591-593
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    • 2008
  • In this report, cerium doped lutetium aluminate ($Lu_3Al_5O_{12}$:Ce) phosphor has been synthesized by the solid state method under reduction atmosphere with mixture gas. The prepared phosphor shows a main luminescent peak at 555nm. Consequently, this phosphor is possible to be applicable to white LED lamp by InGaN chips.

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Synthesis and Photoluminescent Property of Diheteryl-substituted Triphenylamine Compound (Diheteryl-substituted triphenylamine 화합물의 합성과 형광 특성)

  • Kim, Byung-Soon;Kim, Sung-Hoon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.19 no.6
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    • pp.35-38
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    • 2007
  • FTriphenylamine dye compound having diheteryl moiety was synthesized and its photoluminescent property was investigated. Organic luminescent materials have received great attentions due to potential application subjects onto full color image displays. In this context, the dye (III) for light emitting materials was synthesized using 2-(4-amino-2-hydroxyphenyl)benzoxazole (I) and 4,4'-diformyltriphenylamine (II). It is well known that the amino groups of compound (I) react with carbonyl groups, especially an aldehyde, to afford azomethine linkages. The dye shows bulish-green fluorescence property, which is anticipated for the light-emitting material for display devices. In this context, our aim is to synthesize diheteryl-substituted triphenylamine fluorescent dye as an emitting material. The spectroscopic characteristics and the fluorescent properties of this dye molecule were examined and determined.