• 제목/요약/키워드: Luminescence thin film

검색결과 76건 처리시간 0.035초

Multiform Oxide Optical Materials via the Versatile Pechini-type Sol-Gel Process

  • Lin, J.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1247-1250
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    • 2008
  • This presentation highlights work from the authors' laboratories on the various kinds of oxide optical materials, mainly luminescence and pigment materials with different forms (powder, core-shell structures, thin film and patterning) prepared by the Pechini-type sol-gel (PSG) process. The PSG process which uses the common metal salts (nitrates, acetates, chlorides etc) as precursors and citric acid (CA) as chelating ligands of metal ions and polyhydroxy alcohol (such as ethylene glycol or poly ethylene glycol) as cross-linking agent to form a polymeric resin on molecular level, allowing the preparation of many forms of luminescent materials.

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전유기 트랜지스터용 유기 절연재

  • 이무열;손현삼;표승문;이미혜
    • E2M - 전기 전자와 첨단 소재
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    • 제17권7호
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    • pp.21-29
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    • 2004
  • 절연성 기판 위에 단결정이 아닌 반도체 박막을 이용하여 만든 전계효과 (Field Effect FET) 소자로 일반적으로 정의되는 박막 트랜지스터 (Thin Film Transistor, TFT)는 1962 RCA lab.의 Weimer에 제안되어 지금까지 많은 발전을 거듭해 왔다. [1] TFT는 SRAM이나 ROM에도 응용되지만, 주된 사용 분야는 능동구동방식 평판 디스플레이(Active Matrix Flat Panel Display)의 화소 스위칭 소자이다. 액정 디스플레이(Liquid Crystal Display, LCD)나 유기 전계발광 디스플레이(Organic Electro-luminescence Display, OELD) 화소의 스위칭 소자로도 TFT가 널리 사용되고 있다. (중략)

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고휘도 백색방출 전계발광소자의 제작 및 특성 (Fabrication and Characteristics of High Brightness White Emission Electroluminescent Device)

  • 배승춘;김정환;박성근;권성렬;김우현;김기완
    • 센서학회지
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    • 제8권1호
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    • pp.10-15
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    • 1999
  • ZnS 형광체와 BST 강유전체 박막을 절연층으로 사용한 백색방출 전계발광소자를 제작하였다. BST 박막의 제조조건으로 target의 조성비가 $Ba_{0.5}Sr_{0.5}TiO_3$이며, 기판온도가 $400^{\circ}C$, 분위기압이 30 mTorr, A:$O_2$의 비가 9:1일때 유전율이 1 kHz의 주파수에서 209를 나타내었다. 형광층으로 ZnS:Mn, ZnS:Tb 및 ZnS:Ag를 사용하였으며, 활성제 각각의 첨가량은 0.8, 0.8 및 1 wt%로 하였다. 형광층 전체의 두께가 500 nm로 하고 하부 절연층을 200 nm, 상부절연층을 400 nm로 증착하였을 때, 박막 전계발광소자의 발광문턱전압은 약 95 V 였고, 최고휘도는 150 V에서 약 $3000\;cd/m^2$이었다. 발광스펙트럼를 관찰한 결과 청색영역(450 nm), 녹색영역(550 nm) 그리고 적색영역(600 nm)의 파장에서 각각의 피이크가 나타나는 것을 관찰하였다.

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ZnS/CdS 분말과 박막의 구조 및 광학적 특성 (Structural and Optical Characteristics of ZnS/CdS Powders and Thin Films)

  • 장기석
    • 한국군사과학기술학회지
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    • 제13권4호
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    • pp.659-664
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    • 2010
  • The ZnS/CdS thin films were made using 99.99% ZnS and CdS(Aldrich) powders in $7{\times}10^{-6}torr$. The ZnS layer was coated over the CdS layer on an AlOx membrane within a vacuum, at the average speed of $1{\AA}/sec$. After studying the ZnS/CdS and CdS thin films(both with the dimensions of 2.52nm), using fluorescence spectroscopy and comparing the respective results together, we found that although both of the resulting spectra peaked at 390nm, the ZnS/CdS thin films showed a narrower peak, and a higher intensity of photoluminescence than the CdS thin films. The particles of ZnS/CdS thin films also proved to be more homogeneous in size. In addition, the ZnS layer acted as a protective layer. Also, after studying the spectra of ZnS/CdS thin films taken 30 days after their preparation, we found no signs of aging. These results were verified through the scanning electron microscopy(SEM), EDX analysis, thin film X-ray diffraction, and luminescence spectroscopy.

열처리 온도 변화에 따른 라디오파 마그네트론 스퍼터링으로 성장된 MgMoO4:Eu3+ 형광체 박막의 특성 (Properties of MgMoO4:Eu3+ Phosphor Thin Films Grown by Radio-frequency Magnetron Sputtering Subjected to Thermal Annealing Temperature)

  • 조신호
    • Current Photovoltaic Research
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    • 제4권1호
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    • pp.25-29
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    • 2016
  • $Eu^{3+}$-activated $MgMoO_4$ phosphor thin films were grown at $400^{\circ}C$ on quartz substrates by radio-frequency magnetron sputter deposition from a 15 mol% Eu-doped $MgMoO_4$ target. After the deposition, the phosphor thin films were annealed at several temperatures for 30 min in air. The influence of thermal annealing temperature on the structural and optical properties of $MgMoO_4:Eu^{3+}$ phosphor thin films was investigated by using X-ray diffraction (XRD), photoluminescence (PL), and ultraviolet-visible spectrophotometry. The transmittance, optical band gap, and intensities of the luminescence and excitation spectra of the thin films were found to depend on the thermal annealing temperature. The XRD patterns indicated that all the thin films had a monoclinic structure with a main (220) diffraction peak. The highest average transmittance of 91.3% in the wavelength range of 320~1100 nm was obtained for the phosphor thin film annealed at $800^{\circ}C$. At this annealing temperature the optical band gap energy was estimated as 4.83 eV. The emission and excitation spectra exhibited that the $MgMoO_4:Eu^{3+}$ phosphor thin films could be effectively excited by near ultraviolet (281 nm) light, and emitted the dominant 614 nm red light. The results show that increasing RTA temperature can enhance $Eu^{3+}$ emission and excitation intensity.

증착 온도가 Eu3+ 이온이 도핑된 MgMoO4 형광체 박막의 특성에 미치는 영향 (Effect of Deposition Temperature on the Properties of Eu3+-doped MgMoO4 Phosphor Thin Films)

  • 강동균;조신호
    • 한국표면공학회지
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    • 제49권1호
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    • pp.81-86
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    • 2016
  • $Eu^{3+}$-doped $MgMoO_4$ phosphor thin films were deposited on quartz substrates by radio frequency magnetron sputtering with changing various growth temperatures. The effects of growth temperature on the structure, transmittance, optical band gap, and luminescence of the phosphor thin films were characterized. All the phosphor thin films, irrespective of growth temperature, showed a monoclinic structure with a main (220) diffraction peak. The thin film deposited at a growth temperature of $400^{\circ}C$ indicated an average transmittance of 90% in the wavelength range of 500 ~ 1100 nm and band gap energy of 4.81 eV. The excitation spectra of the phosphor thin films consisted of a broad charge transfer band peaked at 284 nm in the range of 230 ~ 330 nm and two weak peaks located at 368 and 461 nm, respectively. The emission spectra under ultraviolet excitation at 284 nm exhibited a sharp emission peak at 614 nm and several weak bands. All the phosphor thin films showed high asymmetry ratio values, indicating that $Eu^{3+}$ ions incorporated into the host lattice occupied at the non-inversion symmetry sites. The results suggest that the growth temperature plays an important role in growing high-quality phosphor thin films.

Effect of Deposition and Annealing Temperature on Structural, Electrical and Optical Properties of Ag Doped ZnO Thin Films

  • Jeong, Eun-Kyung;Kim, In-Soo;Kim, Dae-Hyun;Choi, Se-Young
    • 한국재료학회지
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    • 제18권2호
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    • pp.84-91
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    • 2008
  • The effects of the deposition and annealing temperature on the structural, electrical and optical properties of Ag doped ZnO (ZnO : Ag) thin films were investigated. All of the films were deposited with a 2wt% $Ag_2O-doped$ ZnO target using an e-beam evaporator. The substrate temperature varied from room temperature (RT) to $250^{\circ}C$. An undoped ZnO thin film was also fabricated at $150^{\circ}C$ as a reference. The as-grown films were annealed in temperatures ranging from 350 to $650^{\circ}C$ for 5 h in air. The Ag content in the film decreased as the deposition and the post-annealing temperature increased due to the evaporation of the Ag in the film. During the annealing process, grain growth occurred, as confirmed from XRD and SEM results. The as-grown film deposited at RT showed n-type conduction; however, the films deposited at higher temperatures showed p-type conduction. The films fabricated at $150^{\circ}C$ revealed the highest hole concentration of $3.98{\times}1019\;cm^{-3}$ and a resistivity of $0.347\;{\Omega}{\cdot}cm$. The RT PL spectra of the as-grown ZnO : Ag films exhibited very weak emission intensity compared to undoped ZnO; moreover, the emission intensities became stronger as the annealing temperature increased with two main emission bands of near band-edge UV and defect-related green luminescence exhibited. The film deposited at $150^{\circ}C$ and annealed at $350^{\circ}C$ exhibited the lowest value of $I_{vis}/I_{uv}$ of 0.05.

Study on the Electrical Stability of Al-doped ZnO Thin Films For OLED as an alternative electrode

  • Jung, Jong-Kook;Lee, Seong-Eui;Lim, Sil-Mook;Lee, Ho-Nyeon;Lee, Young-Gu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.1469-1472
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    • 2006
  • We investigated the electrical and optical properties of ZnO:Al thin films as a function of the thermal process conditions. The film was prepared by RF magnetron sputtering followed by annealing in a box furnace in air. An ZnO:Al (98:2) alloy with the purity of 99.99% (3 inch diameter) was used as the target material. The electrical properties of the transparent electrode, exhibited surface oxidation as a result of rapid oxygen absorption with increasing annealing temperature. The processed ZnO:Al films and commercial ITO(indium-tin-oxide) were applied to an OLED stack to investigate the current density and luminescence efficiency. The efficiency of the device using the ZnO:Al electrode was higher than that from the device using the ITO electrode.

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Li 첨가에 의한 $Gd_2$$O_3$$Eu^3+$/ 박막 형광체의 형광 특성 (Luminescence Characteristics Of $Gd_2$$O_3$$Eu^3+$/ thin film phosphors by Li-doping)

  • Bae, Jong-Seong;Moon, Byung-Kee;Seo, Hyo-Jin;Jeong, Jung-Hyun;Yi, Soung-soo
    • 한국광학회:학술대회논문집
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    • 한국광학회 2003년도 하계학술발표회
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    • pp.284-285
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    • 2003
  • Significant research interest in the growth and characterization of $Y_2$O$_3$:Eu$^{3+}$ thin films has been shown over the last few years because of the promise for applications of display devices. Although an Eu-doped oxysulfide (Eu: $Y_2$O$_2$S) which has an efficiency of 13% has been used for a traditional cathode ray tube (CRT) red phosphor, the sulfide system is known to degrade rapidly under the high current densities needed for field-emission display (FED) technology. (omitted)d)

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