• Title/Summary/Keyword: Luminescence properties

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Thermally assisted IRSL and VSL measurements of display glass from mobile phones for retrospective dosimetry

  • Discher, Michael;Kim, Hyoungtaek;Lee, Jungil
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.429-436
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    • 2022
  • Investigations of retrospective dosimetry have shown that components of mobile phones are suitable as emergency dosimeters in case of radiological incidents. For physical dosimetry, components can be read out using optically stimulated luminescence (OSL), thermoluminescence (TL) and phototransferred thermoluminescence (PTTL) methods to determine the absorbed dose. This paper deals with a feasibility study of display glass from modern mobile phones that are measured by thermally assisted (Ta) optically stimulated luminescence. Violet (VSL, 405 nm) and infrared (IRSL, 850 nm) LEDs were used for optical stimulation and two protocols (Ta-VSL and Ta-IRSL) were tested. The aim was to systematically investigate the luminescence properties, compare the results to blue stimulated Ta-BSL protocol (458 nm) and to develop a robust measurement protocol for the usage as an emergency dosimeter after an incident with ionizing radiation. First, the native signals were measured to calculate the zero dose signal. Next, the reproducibility and dose response of the luminescence signals were analyzed. Finally, the signal stability was tested after the storage of irradiated samples at room temperature. In general, the developed Ta-IRSL and Ta-VSL protocols indicate usability, however, further research is needed to test the potential of a new protocol for physical retrospective dosimetry.

On the study of two luminescence band structfue from ambient air aged porous silicon (대기중에서 aged된 다공성 실리콘의 2가지 발광 band에 관한 연구)

  • Sung-Sik Chang;Akira Sakai
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.4
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    • pp.564-570
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    • 1996
  • We have observed the red and blue luminescence from porous silicon (PS) without any rapid thermal oxidation. Aged porous silicon specimens prepared in dilute HF concentration, especially for the short duration of etching, display the increase of the blue band. The measured luminescence decay time at room temperature exhibits a decay time of about 100 ps and shows appreciably faster decay time than that of 20 K. No photoluminescence (PL) peak maximum shift is observed for the blue PL band at 77 K. However, the red PL band shows the blue shift and displays yellow luminescence at 77 K. The origin of red luminescence has some properties related to Si crystallites, whereas blue luminescence seems to be associated other than Si crystallites.

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A Characterization on Organic Electro-luminescence (유기 전기 luminescence 다이오드 특성)

  • Lee, Han-Seong
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.165-169
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    • 2007
  • Organic EL has been expected to adopt to a new styles of technology that make flat display after Tang & Vanslyke made food electric luminescence device in late 1980s. Their studies based on multi layer structure that consists of emitting layer and carrier transporting layer using proper organic material. In this study we made multi layer device using $Eu(TTA)_3(phen)$ as a luminescence material by PVD and investigate luminous properties of each device. But oxidization of organic layer by ITO, energy walls in both pole interface, contaminations of ITO surface, importance of protecting membrane, diffusive dimming of light to cathode organic layer, these causes of degradations are common facts of a macromolecule and micromolecule. We think these degradation caused by the impact of heat and electro-chemical factor, bulk effect and interface phenomenon, and raise a question.

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Study on the Luminescence Properties according to ZnS multi-phase (ZnS multi-phase에 따른 발광특성 연구)

  • 김광복;김용일;천희곤;조동율;구경완
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.1
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    • pp.48-53
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    • 2001
  • The crystal structure of ZnS fabricated by gas-liquid phase reaction was refined by the Rietveld program using X-ray diffraction data. The R-weighted pattern (R$\sub$wp/) of ZnS powder was 10.85%. The fraction of HCP phase was closely related with extra amount of H$_2$S gas. The lattice parameters and crystalline size were changed by the relative ratio of multi-phase. The luminescence property of ZnS:Cu, Al green phosphors prepared by conventional methods was good in the range of 91∼94% and 150∼190${\AA}$, respectively. According to the maximum entropy electron density(MEED) methods, any defects in (001) plane of cubic phase were not found. We suggest that both the Rietveld and maximum entropy density methods may be useful tools for studying luminescence mechanism of other phosphors materials.

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Optical Properties of a ZnO-MgZnO Quantum-Well

  • Ahn, Do-Yeol;Park, Seoung-Hwan
    • JSTS:Journal of Semiconductor Technology and Science
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    • v.6 no.3
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    • pp.125-130
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    • 2006
  • The optical gain and the luminescence of a ZnO quantum well with MgZnO barriers is studied theoretically. We calculated the non-Markovian optical gain and the luminescence for the strained-layer wurtzite quantum well taking into account of the excitonic effects. It is predicted that both optical gain and luminescence are enhanced for the ZnO quantum well when compared with those of InGaN-AlGaN quantum well structure due to the significant reduction of the piezoelectric effects in the ZnO-MgZnO systems.

Preparation and Luminescent Properties of (Sr1Ca)TiO3:Pr1Al Phosphors ((Sr1Ca)TiO3:Pr1Al 형광체의 제조와 발광특성)

  • Park Chang-Sub;Lee Jeng-Un;Yu Il
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.19 no.5
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    • pp.422-426
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    • 2006
  • [ $Sr_xCa_{(1-x)}TiO_3$ ] red phosphors doped with Pr(0.13 mol%) and Al(0.23 mol%) were synthesized by solid state reaction method. Change of crystal structure occurred in $Sr_xCa_{(1-x)}TiO_3:Pr,Al$ phosphors with increasing value of x. Green and red luminescence were observed from $SrTiO_3:Pr,Al$ phosphors at low temperature. However, only red luminescence in the case of $CaTiO_3:Pr,Al$ phosphors was measured at low temperature. The main cause of green luminescence was explained by the bandgap reduction.

Luminescence Enhancement by Ba in SrTiO3:Pr, Al Red Phosphor for Field Emission Displays

  • Won, Chang-Whan;Lee, Jong-Eun;Won, Hyung-Il;Kim, Kwang-Bok;Song, Yoon-Ho;Kang, Seung-Youl;Koo, Kyoung-Wan
    • Journal of the Korean Ceramic Society
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    • v.43 no.11 s.294
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    • pp.743-745
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    • 2006
  • The luminescence properties of $Sr_{1-x}Ba_xTiO_3:Pr$, Al red phosphor for Field Emission Displays (FEDs) have been investigated in powders prepared though solid-state reactions. $Sr_{1-x}Ba_xTiO_3:Pr$, Al red phosphors indicate a higher luminescent intensity, and have been found to have potential for field emission displays. The addition of Ba increased the luminescence intensity at 617 nm by up to 30%. Ba ions are effective in producing the energy transfers from host-to-activator in 4f-5d transitions.

The Origin of Change in Luminescent Properties of ZnMgS:Mn Thin Film Phosphor with Varying Annealing Temperature

  • Lee, Dong-Chin;Kang, Jong-Hyuk;Jeon, Duk-Young;Yun, Sun-Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1576-1579
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    • 2005
  • With varying rapid thermal annealing (RTA) temperature, luminescence properties of $Zn_{0.75}Mg_{0.25}S:Mn$ thin film deposited by RF-magnetron sputtering technique were investigated. In this study, $Zn_{0.75}Mg_{0.25}S:Mn$ thin film phosphor showed more red emission than those of the previous studies when annealed around 600 or $650^{\circ}C$. Although all samples were deposited from identical source composition, a main peak wavelength of photoluminescence spectra of $Zn_{0.75}Mg_{0.25}S:Mn$ shifted toward shorter wavelengths depending upon increase of RTA temperature. The same dependence of wavelength on RTA temperature was also observed in cathodoluminescence as well as electroluminescence measurements. It was revealed that the change of the luminescence properties were originated from structural changes in $Zn_{0.75}Mg_{0.25}S:Mn$ thin film phosphor from cubic to hexagonal phases analyze using conventional X-ray pole figure mapping. The phase transition would be the origin of luminescence property changes with respect to RTA temperature.

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Excitation and Emission Properties of Adsorbed U(VI) on Amorphous Silica Surface

  • Jung, Euo Chang;Kim, Tae-Hyeong;Kim, Hee-Kyung;Cho, Hye-Ryun;Cha, Wansik
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.497-508
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    • 2020
  • In the geochemical field, the chemical speciation of hexavalent uranium (U(VI)) has been widely investigated by performing measurements to determine its luminescence properties, namely the excitation, emission, and lifetime. Of these properties, the excitation has been relatively overlooked in most time-resolved laser fluorescence spectroscopy (TRLFS) studies. In this study, TRLFS and continuous-wave excitation-emission matrix spectroscopy are adopted to characterize the excitation properties of U(VI) surface species that interact with amorphous silica. The luminescence spectra of U(VI) measured from a silica suspension and silica sediment showed very similar spectral shapes with similar lifetime values. In contrast, the excitation spectra of U(VI) measured from these samples were significantly different. The results show that distinctive excitation maxima appeared at approximately 220 and 280 nm for the silica suspension and silica sediment, respectively.

Morphological Change and Luminescence Properties of ZnO Crystals Synthesized by Thermal Evaporation of a Mixture of Zn and Cu Powder (Zn과 Cu 혼합 분말의 열 증발에 의하여 생성된 ZnO 결정의 형상 변화 및 발광 특성)

  • Lee, Geun-Hyoung
    • Korean Journal of Materials Research
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    • v.28 no.10
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    • pp.578-582
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    • 2018
  • ZnO crystals with different morphologies are synthesized through thermal evaporation of the mixture of Zn and Cu powder in air at atmospheric pressure. ZnO crystals with wire shape are synthesized when the process is performed at $1,000^{\circ}C$, while tetrapod-shaped ZnO crystals begin to form at $1,100^{\circ}C$. The wire-shaped ZnO crystals form even at $1,000^{\circ}C$, indicating that Cu acts as a reducing agent. As the temperature increases to $1,200^{\circ}C$, a large quantity of tetrapod-shaped ZnO crystals form and their size also increases. In addition to the tetrapods, rod-shaped ZnO crystals are observed. The atomic ratio of Zn and O in the ZnO crystals is approximately 1:1 with an increasing process temperature from $1,000^{\circ}C$ to $1,200^{\circ}C$. For the ZnO crystals synthesized at $1,000^{\circ}C$, no luminescence spectrum is observed. A weak visible luminescence is detected for the ZnO crystals prepared at $1,100^{\circ}C$. Ultraviolet and visible luminescence peaks with strong intensities are observed in the luminescence spectrum of the ZnO crystals formed at $1,200^{\circ}C$.