• 한국산업융합학회 논문집
• /
• 제25권2_2호
• /
• pp.199-208
• /
• 2022

The steel wire or steel bar processing process applied to the manufacture of various bolts and power transmission shafts was improved by applying in-line phosphate film treatment technology. By applying a polymer lubricant for a non-reactive metal forming process and a non-reactive non-phosphorus lubricating coating agent, the film formation for each process time was comparatively analyzed and reviewed. Compared to the nine processes applied previously, the in-line phosphate film treatment technology applied with only two processes has been effectively improved in terms of reduction of treatment time, reduction of facility installation area, prevention of water pollution due to wastewater, and non-use of ozone-depleting substances. In addition, it was found that it can have an important effect on productivity improvement and price competitiveness from the simplification of quality control and process control as well as improvement of the working environment.

• Tribology and Lubricants
• /
• 제39권2호
• /
• pp.43-48
• /
• 2023

In this study, we investigate the tribological behavior of AISI 304 stainless steel pairs under deionized water and hexagonal boron nitride (h-BN) water dispersion lubrication. The specimen friction and wear properties are evaluated using a reciprocating ball-on-flat tribometer. The coefficient of friction remains nearly constant throughout the test under both lubricant conditions. The wear depth of the specimens under h-BN lubrication is smaller than that under deionized water lubrication, indicating the inhibition behavior of h-BN nanolubricants on direct metal-metal contacts. Optical micrographs and stylus profilometer measurements are performed to evaluate the severity of damage caused by the sliding motion and to determine the wear morphology of the specimens, respectively. The results show that h-BN nanolubricants does not have a significant effect on the friction behavior but demonstrates reduced wear owing to their trapping effect between the sliding interfaces. Moreover, scanning electron microscopy and energy-dispersive X-ray spectroscopy images of the specimens were acquired to confirm the trapping effect of h-BN between the sliding interfaces. The results also suggest that the trapped lubricants can distribute the contact pressure, reducing the wear damage caused by the metal-metal contact at the interface. In conclusion, h-BN nanolubricants have potential as an anti-wear additive for lubrication applications. Further investigation is needed to provide direct evidence of the trapping effect of h-BN nanoparticles between the sliding interfaces. These findings could lead to the development of more efficient and effective lubricants for various industrial applications.

• 한국유체기계학회 논문집
• /
• 제17권6호
• /
• pp.29-37
• /
• 2014

Non-Newtonian fluid mechanics takes charge of an important role in the oil industries. Especially in the oil well drilling process, the drilling fluid such as mud keeps the drill bit cool and clean during drilling, with suspending drill cuttings and lubricating a drill bit. The purpose of this study is to examine the effect of fluid mud rheological properties to predict different characteristics of non-Newtonian fluid in the mud mixing tank on offshore drilling platforms. In this paper, ANSYS fluent package was used for the simulation to solve the hydrodynamic force and to evaluate mud mixing time. Prediction of the power consumption and the pumping effectiveness has been presented with different operating fluid models as Newtonian and non-Newtonian fluid. The comparison between Newtonain mud model and non-Newtonian mud model is confirmed by the CFD simulation method of drilling mud mixing tank. The results present useful information for the design of the drilling mud mixing tanks and provide some guidance on the use of CFD tool for such non-Newtonian fluid flow.

• 공업화학
• /
• 제4권1호
• /
• pp.54-63
• /
• 1993

Dodecanoic acid와 tetraethylenepentamine을 반응시켜서 1, 2-disubstituted imidazoline을 얻었고, 이것을 양이온화시켜 유화형 1, 2-disubstituted imidazolinium salt를 합성하였다. 또한 docosanoic acid와 hydroxyethylethylenediamine을 반응시켜 중간생성물인 2-docosamido-2'-docosanoyloxydiethylamine을 얻었고, 다시 우레아와 반응시켜서 지방산 카르바미드를 얻었다. 이것을 역시 양이온화시켜 유화형 지방산카르바미드염을 합성하였다. 합성된 각종 염들을 블렌딩시켜 유연제를 제조한 후, 아크릴섬유에 유연처리를 하여 유연성, 평활성 및 대전방지성을 측정한 결과, 유연성과 평활성이 양호하였고 약간의 대전방지성도 보유하였다. 또한 강연도시험과 pH변화에 따른 촉감의 내세탁성 시험결과를 통하여 제조된 유연제가 내구성 유연제임을 입증하였으며, SEM으로 유연처리된 아크릴섬유의 표면구조를 관찰하였다.

• Tribology and Lubricants
• /
• 제39권6호
• /
• pp.235-243
• /
• 2023

This paper presents the fabrication process of water-lubricated plastic bearings. Plastic bearings require good mechanical properties and tribological properties as well as elasticity and shock resistance, especially when lubricated in dirty water conditions. In this study, sleeve-type plastic bearings are produced by winding a prepreg sheet, which primary contains nitrile rubber (NBR)-modified epoxy, self-lubricating fillers, and various types of lattice-structured reinforcing fibers such as carbon, Aramid, and polyethylene terephthalate. A thermosetting epoxy is chemically modified with NBR to impart elasticity and low-friction characteristics in water conditions. Experimental investigations are conducted to examine the mechanical and tribological characteristics of the developed bearing materials, and the results are compared with the characteristics of a commercial plastic bearing (Thordon SXL), well known as a water-lubricated bearing. A Thordon bearing (mainly composed of polyurethane) exhibits an extremely low load-bearing capacity and is thus only suitable for medium loading (1~10MPa). The tribological characteristics of the test materials are evaluated through Falex block-on-ring (LFW-1) friction and wear tests. The results indicate that friction exhibited by the carbon-fiber-reinforced NBR-10wt.%-modified epoxy composite material, incorporated with the addition of 20wt.% UHMWPE and 6wt.% paraffin wax, is lower than that of the Thorden bearings, whereas its wear resistance surpass that of Thorden ones. Because of these features, the load carrying capacity of the fabricated composite (>10MPa) is higher than that of the Thorden bearings. These results confirm the applicability of water-lubricated plastic bearing materials developed in this study.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2000년도 춘계학술강연 및 발표대회 강연 및 발표논문 초록집
• /
• pp.9-10
• /
• 2000

An important business-field of world-wide steel-industry is the coating of thin metal-sheets with zinc, zinc-aluminum and aluminum based materials. These products mostly go into automotive industry. in particular for the car-body. into building and construction industry as well as household appliances. Due to mass-production, the processing is done in large continuously operating plants where the mostly cold-rolled metal-strip as the substrate is handled in coils up to 40 tons unwind before and rolled up again after passing the processing plant which includes cleaning, annealing, hot-dip galvanizing / aluminizing and chemical treatment. In the liquid Zn, Zn-AI, AI-Zn and AI-Si bathes a combined action of corrosion and wear under high temperature and high stress onto the transfer components (rolls) accounts for major economic losses. Most critical here are the bearing systems of these rolls operating in the liquid system. Rolls in liquid system can not be avoided as they are needed to transfer the steel-strip into and out of the crucible. Since several years, ceramic roller bearings are tested here [1.2], however, in particular due to uncontrollable Slag-impurities within the hot bath [3], slide bearings are still expected to be of a higher potential [4]. The today's state of the art is the application of slide bearings based on Stellite\ulcorneragainst Stellite which is in general a 50-60 wt% Co-matrix with incorporated Cr- and W-carbides and other composites. Indeed Stellite is used as the bearing-material as of it's chemical properties (does not go into solution), the physical properties in particular with poor lubricating properties are not satisfying at all. To increase the Sliding behavior in the bearing system, about 0.15-0.2 wt% of lead has been added into the hot-bath in the past. Due to environmental regulations. this had to be reduced dramatically_ This together with the heavily increasing production rates expressed by increased velocity of the substrate-steel-band up to 200 m/min and increased tractate power up to 10 tons in modern plants. leads to life times of the bearings of a few up to several days only. To improve this situation. the Mechanical Alloying (MA) TeChnique [5.6.7.8] is used to prOduce advanced Stellite-based bearing materials. A lubricating phase is introduced into Stellite-powder-material by MA, the composite-powder-particles are coated by High Energy Milling (HEM) in order to produce bearing-bushes of approximately 12 kg by Sintering, Liquid Phase Sintering (LPS) and Hot Isostatic Pressing (HIP). The chemical and physical behavior of samples as well as the bearing systems in the hot galvanizing / aluminizing plant are discussed. DependenCies like lubricant material and composite, LPS-binder and composite, particle shape and PM-route with respect to achievable density. (temperature--) shock-reSistibility and corrosive-wear behavior will be described. The materials are characterized by particle size analysis (laser diffraction), scanning electron microscopy and X-ray diffraction. corrosive-wear behavior is determined using a special cylinder-in-bush apparatus (CIBA) as well as field-test in real production condition. Part I of this work describes the initial testing phase where different sample materials are produced, characterized, consolidated and tested in the CIBA under a common AI-Zn-system. The results are discussed and the material-system for the large components to be produced for the field test in real production condition is decided. Outlook: Part II of this work will describe the field test in a hot-dip-galvanizing/aluminizing plant of the mechanically alloyed bearing bushes under aluminum-rich liquid metal. Alter testing, the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed. Part III of this project will describe a second initial testing phase where the won results of part 1+11 will be transferred to the AI-Si system. Part IV of this project will describe the field test in a hot-dip-aluminizing plant of the mechanically alloyed bearing bushes under aluminum liquid metal. After testing. the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed.

• 공업화학
• /
• 제25권5호
• /
• pp.548-551
• /
• 2014

기존 유기 세정제의 문제점인 인체 독성을 낮추기 위하여 생분해도 및 $LD_{50}$가 향상된 에테르 및 에스테르 작용기를 동시에 갖는 세정제 4종을 새롭게 합성하였다. 합성한 세정제를 한국기계전기전자시험연구원에서 국가산업표준 방법으로 분석하여 물리적인 성질과 생분해도 및 $LD_{50}$을 측정하고 세정성 평가를 수행하였다. 물성 측정 결과, 물리화학적 성질이 세정제로서 적합한 것으로 확인되었다. 세정력 평가를 위하여 $60{\times}40mm$ 크기의 스테인리스 강 기판에 절삭유, 방청유, 인발유, 윤활유를 각각 기판에 도포하여 합성한 세정제(1-4)에 침적하여 세정력을 평가하였다. 최대 5 min 간 침적하였을 때 절삭유는 96-100%, 방청유에서는 64-72%, 인발유는 59-88%, 윤활유는 72-84% 정도의 높은 세정력을 보였다. 또한 세정제(1-4)의 생분해도 99% 이상, $LD_{50}$ 2,000 mg/kg 이상의 값을 보임으로서 인체에 거의 해가 없는 친환경 세정제임을 확인하였다.

• Tribology and Lubricants
• /
• 제28권2호
• /
• pp.47-55
• /
• 2012

Generally, to product multi-grade oil like engine oil, a sort of mineral base oil is mixed with a fundamental additive package liquid and a polymer liquid as viscosity index improver in order to improve the lubricating property of base oil. That is, engine oil is the mixture of more than two fluids. Specially, a polymeric type liquid cannot be seen as the linear viscosity like Newtonian fluids. In this research, by using the governing equation describing non-Newtonian hydrodynamic lubrication related with the mixture of incompressible fluids based on the principle of continuum mechanics, it will be compared the bearing performance between the mixture of each liquid to be blended and multi-grade engine oil as a single fluid in a high speed hydrodynamic journal bearing. Further, it is to be found the way estimating the performance of the blended multi-grade engine lubricant in a journal bearing in advance before blending by using the physical properties of mineral base oil, fundamental additive liquid and polymer liquid of viscosity index improver. So, it can be reduced the number of trial and error to get the wanted lubricant by selecting the proper volume fraction of each liquid to satisfy the expected performance and estimating in advance the performance of various multi-grade oils before blending. Therefore, it can be shorten the developing time and saved the developing cost.

• 청정기술
• /
• 제19권2호
• /
• pp.184-188
• /
• 2013

기존 탄화수소계 세정제는 낮은 인화점으로 인하여 화재, 폭발과 같은 문제점을 가지고 있다. 인화점을 높이기 위해 불소가 포함된 난연성 세정제 7종을 개발하였다. 새롭게 합성한 세정제를 한국석유관리원에서 국가산업표준 방법으로 분석하여 물성을 측정하고 세정성 평가를 수행하였다. 물성 측정 결과, 인화점이 탄화수소계 세정제보다 높은 것을 확인하였다. 세정력 평가를 위하여 가로 60 mm, 세로 40 mm 크기의 스테인리스강 기판에 인발유, 아비에트산, 절삭유, 윤활유를 각각 도포하여 합성한 세정제(1~7)에 넣어 침적한 후 세정력을 평가하였다. 최대 5분간 침적하였을 때 인발유는 80~96%, 아비에트산은 82~97%, 윤활유는 86~93% 정도의 높은 세정력을 보였다. 그러나 절삭유에서는 60~87% 정도로 다른 오일보다 낮은 세정력을 보였다. 따라서 약간의 차이는 있지만 대체적으로 우수한 세정력을 보여 산업세정분야에 적용이 가능함을 나타내었다.

• Tribology and Lubricants
• /
• 제36권3호
• /
• pp.133-138
• /
• 2020

In this paper, we present an experimental investigation of the friction coefficient and wear area change of carbon/epoxy and E-glass/epoxy composites depending on the fiber direction (0°/90°). We compared the results of the case where the sliding direction is parallel to the fiber direction (0°) with that of the case where it is perpendicular to the fiber direction (90°). The ball-on-plate wear test equipment was used to cause wear in both directions. Two types of specimens were prepared with thicknesses of 3 mm-one made of carbon fiber reinforced plastic composite (CFRP) and the other of glass fiber reinforced plastic composite (GFRP). A normal force of 20 N was applied to the specimen and the sliding speed was 10 mm/s and the sliding distance was set to 20 m to perform the wear test. The CFRP demonstrates superior tribological characteristics compared to the GFRP. This outcome is attributed to graphitization of carbon, which serves as solid lubricating particles. In addition, both CFRP and GFRP are worn more in the 90° direction than in the 0° direction. This is due to the greater occurrence of fiber breakage and separation in the 90° direction than in the 0° direction. This study is expected to be utilized as basic data for understanding the friction and wear characteristics of CFRP and GFRP composites along the fiber direction and to apply the appropriate material.