• 한국응용과학기술학회지
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• 제27권4호
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• pp.522-530
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• 2010

We developed functional synthetic lubricant for internal combustion engine oil, which would improve engine oil performance for internal combustion engine and extend engine life. We made base oil by synthesizing nonanoic acid, 1.1.1-trimethylol propane (which has good bio-degradability) and pentaerythrytol ester. We synthesized catalyst using p-toluene sulfonic acid 0.15 wt% and coloring-prevention agent hypo-phosphorus acid 0.18 wt% at 180-$190^{\circ}C$. Reaction temperature was increased at the rate of $10^{\circ}C$ for every 1 hour. When acid value reached below 3, reaction was completed. After cooling and deoxidization, we washed it by distilled water two times. After dehydration and filtering, we obtained trimethylol propane tripelargonate (TMTP) and pentaerythrytol tetrapelargonate (PETP) at yields of 96 % and 98 % respectively.

• 한국산학기술학회:학술대회논문집
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• 한국산학기술학회 2004년도 춘계학술대회
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• pp.311-314
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• 2004

바이오디젤 (지방산 메틸에스테르)을 기반으로 하여 생산된 합성윤활유 베이스에 대한 독성을 분석 평가하였다. OECD 207의 방법에 의거하여 인공토양(artifical soil)에서 300$\~$600 mg의 지렁이를 선별하였다. 0.01, 0.1, 1, 10, 100과 1,000 mg/kg의 각 농도별로 선별된 지렁이를 10마리씩 넣고 수분 $31\~37\%$, 온도 $20{\pm}2^{\circ}C$와 PH 6.0 $\pm$ 0.5를 조절하여 14일간 지렁이의 반수치사농도(lethal concentration when $50\%$ of the population were killed, $LC_{50}$)를 측정하였다. 합성윤활유의 측정 된 반수치사농도($LC_{50}$)는 1,555 mg/kg로 측정되었으며, 유의 확률이 < 0.02로서 유의수준 $5\%$에서 유의함을 알 수 있었다.

• Tribology and Lubricants
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• 제36권6호
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• pp.365-370
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• 2020

Recently, additive manufacturing (AM) technology has been applied to various industries such as automotive, aviation, medical, and electronics. Most prior studies are limited to the mechanical properties of printed materials, and few studies are being conducted on their tribological characteristics. However, the friction and wear characteristics of the material should be studied in order to utilize the components manufactured using AM technology as mechanical parts. In this study, the friction and wear characteristics of acrylonitrile-butadiene-styrene (ABS)-like resin printed with stereo lithography apparatus (SLA) 3D printing are evaluated according to the viscosity of silicon oil lubricant using a ball-on-disk experiment. Lubricants with a viscosity of 500, 1000, and 2000 cSt are prepared for the experiment. If silicon oil lubricants are used during the ball-on-disk test, the coefficient of friction (COF) and wear rates are significantly reduced, and the higher the viscosity of the lubricant, the lower will be the COF and wear rates. It is also verified that the temperature of the specimen owing to friction also decreases according to the viscosity of the lubricant. This is because of the silicon oil film thickness, and the higher the viscosity of the lubricant, the thicker will be the oil film. More studies on the tribological characteristics of 3D printing materials and suitable lubricants will be required to use 3D printed parts as mechanical elements.

• 설비공학논문집
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• 제19권10호
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• pp.718-725
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• 2007

In the general vapor-compression refrigeration system, refrigeration lubricant circulates in refrigeration system with refrigerant. Knowledge of the amount of circulating lubricant is very important to exactly calculate capacity of the refrigeration system. An experimental study was conducted to estimate the oil concentration of a flowing $CO_2/Oil$ mixtures. POE and PAG oil are considered as test lubricants in this study. Performance tests were conducted under simulated liquid conditions for $CO_2/POE$ oil mixture in oil concentration of 0 to 10 weight-percent and $CO_2/PAG$ oil mixture in oil concentration of 0 to 6 weight-percent in the temperature ranges of $-5^{\circ}C\;to\;15^{\circ}C$. The results obtained indicate specific gravity of $CO_2/Oil$ mixture is increased as oil concentration is increased and as temperature of mixture is decreased. Oil concentration correlation of $CO_2/POE$ oil mixture and $CO_2/PAG$ oil mixture is suggested, based on the measurement of specific gravity and temperature. This correlation enable to predict the oil concentration without extraction of the mixture and can be applied for $CO_2/POE$ mixtures and $CO_2/PAG$ mixtures.

• Tribology and Lubricants
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• 제3권2호
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• pp.68-71
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• 1987

This paper deals with some thermal Characteristics of journal bearing such as the behaviour of the maximum bearing temperature, the lubricant's carry-over in the inlet region and so on. Temperatures of the bearing and the lubricants being supplied and discharged were measured along with shaft speed and bearing load. The results showed that with the increase of the Shaft speed, the maximum temperature rose at any shaft speed at a defferent rate of change defending on the flow regime of the lubricant film. And the lower eccentricity ratio is the more lubricant's carry-over occur. Additionally it was partially proved that the oil discharge temperature and the maximum temperature changed in quite different each other.

• 공업화학
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• 제34권4호
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• pp.434-443
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• 2023

세계적으로 가장 많이 사용되고 있는 리튬 그리스의 대체 물질로서 calcium sulfonate 그리스를 합성하여 성능을 개선하였다. Calcium sulfonate 그리스의 저온성 문제를 해결하기 위하여 PAO (poly alpha olefin) 기반의 기유와 증주제를 도입하였다. 본 연구에서는 파라핀 오일과 PAO 기반의 기유와 증주제로 calcium sulfonate 그리스 3종을 합성하였으며, PAO 기반의 기유와 수산화 리튬, 12-hydroxy stearic acid, sebacic acid의 비누화 반응으로 리튬 그리스 1종을 합성하였다. 합성한 calcium sulfonate 그리스 3종과 리튬 그리스의 형태, 미세 구조 및 작용기는 SEM 및 FT-IR로 분석하였다. 저온 특성은 rheometer, low temperature torque로 측정하였고, 트라이볼로지 특성은 four ball lubricant tester, SRV로 측정하였다. 그 결과, PAO 기반의 기유와 증주제로 합성된 calcium sulfonate 그리스는 -40℃에서도 유동할 수 있었으며, 기존 calcium sulfonate 그리스의 저온 특성의 한계점을 극복하였다. 또한 합성한 calcium sulfonate 그리스는 PAO 기유로 합성된 리튬 그리스보다 우수한 내마모성, 내하중성, 마찰계수, 내열성, 점착성 및 내부식성을 보였으므로 상업적으로 기존의 리튬 그리스를 대체할 수 있을 것으로 기대된다.

• Tribology and Lubricants
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• 제13권4호
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• pp.47-52
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• 1997

Friction torques, electrical contact resistances and bearing temperatures were measured on high speed angular contact ball beatings for the spindle of machine tools. The test bearings ran with oil-air lubrication at the thrust loads from 320 N to 1920 N and at the rotational speed of up to 12000 rpm. Electrical contact resistances between balls and races were measured to evaluate the formation of the lubricant film in the contact area. The test results with sufficient lubrication showed that the variations of friction torques were sensitive to the thrust loads and the rotational speeds, and that the friction torques were higher than those with insufficient lubrication. With insufficient lubrication and high thrust loads, the collapse of the lubricant film was detected even at a high rotational speed. It was concluded that these high speed beatings to run in condition of fluid lubrication should require monitoring not only the temperature increase of the bearing but also the lubricant film formation in contact areas resulting from the change in the applied load and the lubricant amount.

• Tribology and Lubricants
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• 제12권4호
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• pp.28-34
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• 1996

The lubrication characteristics of high-speed ball bearings have been investigated empirically using 45mm bore split inner ring ball bearings employed in small industrial gas turbine engines with oil-jet lubrication method. For the close structural simulation, experiments carried out with bearing mounting supports of real engines, such as bearing housings and oil nozzle assemblies with squeeze film dampers. Thus the results of tests can be directly applied to the design and the development of gas turbine engines. Testing was done by varying operating speeds, axial load on bearings, and lubricant flow rates. During testing, the temperature of bearing at outer-ring face, the power consumption of the driving motor, and the rotating resistance of the bearing were measured. From this study, the representative factors for lubrication characteristics at high speed was found, and the most important one was not operating speed but axial load up to 1.95 million dmN speed and 2969 N axial load. Furthermore, the detailed variation of the rotational resistance of the bearing could be visualized by measuring the change of the radial load under the bearing supports. The rotational resistance consists of the frictional resistance and the bearing-cavity oil resistance.

• 한국정밀공학회지
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• 제19권7호
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• pp.20-27
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• 2002

An analysis model for an elliptical fluid film bearing is described. The principles of hydrodynamic lubrication are outlined together with an expanded version of the governing pressure field equation as related to elliptical journal bearing. Finite element method approximations are given for the pressure field equation and a temperature model, both related to the fluid film thickness. The thermal effects in the lubricant viscosity, lubricant film thickness, variation of the journal rotating speed and influence of turbulence are investigated in this paper A finite element model and an iterative computational process are described, whereby full simultaneously converged field solutions for fluid film thickness, temperature, viscosity, pressure, stiffness and damping coefficient are obtained.

• Journal of Industrial and Engineering Chemistry
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• 제68권
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• pp.99-108
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• 2018

An oil-tolerant and salt-resistant aqueous foam system was screened out as a possible lubricant to enable cold heavy oil transportation. The microstructures and viscoelasticity and effects of heavy oil, salt and temperature on the foam stability were investigated and new rheological and drainage models were established. The results indicate the foam with multilayered shells belongs to a special microcellular foam. The viscoelasticity could be neglected due to its low relaxation time. The drainage process can be divided into three stages. The foam with quality of 67.9% maintains great stability at high oil and salt concentrations and appropriate elevated temperature.