• Fire Science and Engineering
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• v.22 no.3
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• pp.228-233
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• 2008

Detonation limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower detonation limits (LDL) and the upper detonation limits (UDL) of the flammable substances predicted with the appropriate use of the heat of combustion and the stoichiometric coefficient. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the detonation limits of for other flammable substances.

• Journal of the Korean Society of Safety
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• v.13 no.2
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• pp.116-121
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• 1998

Various flammable vapors as energy source and raw material have been stored, transported in the industries, and accidental leakage of these vapors occurs occasionally. Without an appropriate protection system, flammable vapors can be ignited and serious damage results from them. To reduce the risk caused by explosion, we should know the explosion limit and explosion characteristics. In this study, the maximum explosion pressure, the maximum explosion pressure rise, the effect of temperature and mixing with other vapor were measured in a cylindrical vessel. Experimental results showed that maximum explosion pressure of flammable vapor was about 3.1~$4.2 kg/cm^2$ and it was reached 3.4 times faster than that at explosion limit. The lower explosion limit was coincided well with Le Chateilier's equation, however, upper explosion limit was not.

• Journal of the Korean Society of Safety
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• v.15 no.3
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• pp.71-77
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• 2000

The aim of this study is to investigate the temperature dependence of the lower explosive limit(LEL) at elevated temperature. The temperature dependence of the lower explosive limit is one of the significant indices of flammability and combustibility. By using the literature data, the new equations for predicting the temperature dependence of the lower explosive limits for paraffinic hydrocarbons are proposed. The values calculated by the proposed equations were a good agreement with the literature data. It is hoped eventually that this proposed equations will support the use of the prediction for the lower explosive limit and the flash points of the flammable mixtures.

• Journal of Advanced Marine Engineering and Technology
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• v.32 no.3
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• pp.455-460
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• 2008

The flammable gas monitoring system is to be provided in cargo pump rooms of tankers in accordance with the requirements of SOLAS regulations, and flammable gas detectors are to be arranged in a proper position. In this paper, simulation tests and CFD analysis are carried out under the actual ventilation conditions of pump rooms in the ship in service. Based on the results, a new guidelines for an arrangement of flammable gas detectors are suggested.

• Journal of the Korean Institute of Gas
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• v.10 no.1 s.30
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• pp.19-25
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• 2006

Explosion limit is one of the major physical properties used to determine the fire and explosion hazards of the flammable substances. Explosion limits are used to classify flammable materials according to their relative flammability. Such a classification is important for the safe handling, storage, transportation of flammable substances. In this study, the lower explosion limits(LEL) of the flammable mixtures predicted with the appropriate use of the vapor composition and the heat of combustion of the individual components which constitute mixture. The values calculated by the proposed equations were a good agreement with literature data within a few percent. From a given results, It is to be hoped that this methodology will contribute to the estimation of the explosive properties of flammable mixtures with improved accuracy and the broader application for other flammable substances.

• Fire Science and Engineering
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• v.15 no.3
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• pp.14-20
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• 2001

The flash points are one of the most important fundamental properties used to determine the potential for fire and explosion hazards of flammable substances. A classification of the flash points is important for the safe handling of flammable liquids which constitute the solvent mixtures. Basic to all flash points behavior are vapor pressure and explosive limits(lower explosive limit and upper explosive limit). The flash points of flammable solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Dalton, Le Chatelier and activity coefficient models. In this study, the reference values of lower flash points were compared with the calculated values by using Raoult's law and MRSM(modified response surface methodology) model. The lower flash points were in agreement with the predicted by Raoult's law and MRSM model. By means of this methodology, it is possible to evaluate reliability of experimental data of the flash points of the flammable mixtures.

• Journal of the Korean Institute of Gas
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• v.15 no.4
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• pp.44-50
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• 2011

Explosion limit is one of the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, the lower explosion limit(LEL) and upper explosion limit(UEL) of ethers were predicted by using the heat of combustion and stoichiometric coefficients. The values calculated by the proposed equations agreed with literature data within a few percent. From the given results, using the proposed methodology, it is possible to predict the explosion limits of the other flammable ethers.

• 한국연소학회:학술대회논문집
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• 2015.12a
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• pp.123-125
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• 2015

A study has been conducted to investigate the effect of swirl angle in low swirl combustor. In this study, the employed swirl angles were $28^{\circ}$, $32^{\circ}$ and $37^{\circ}$. Direct flame photos show that the width of the flame is expanded and the length of the flame is shortened when swirl angle is increased. Also, as the swirl angle was increased, the flame stability region could be widened due to the expansion of lower flammable limit. Between 3 and 7kW, CO emissions was below 10 ppm and NOx emissions was also below 27 ppm at $O_2$ 15% basis over the lean burning range of 0.6 < ${\Phi}$ < 0.9. From this investigation of stability expansion effect and emission performance, it was identified that the swirl angle $37^{\circ}$ is most suitable swirling condition in the low swirl model combustor.

• Corrosion Science and Technology
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• v.3 no.6
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• pp.257-261
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• 2004

Leaking of fuel gas in a building creates flammable atmosphere and gives rise to explosion. Observations from accidents suggest that some explosions are caused by quantity of gas significantly less than the lower explosion limit amount required to fill the whole confined space, which might be attributed to inhomogeneous mixing of the leaked gas. The minimum amount of leaked gas for explosion is highly dependent on the degree of mixing in the building. This paper proposes a method for estimating minimum amount of flammable gas for explosion assuming Gaussian distribution of flammable gas.

• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.91-97
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• 2005

The research on the explosive limits is one of fundamental fields of combustion process, and information on the explosive limits of mixture of fuel and oxidant, with or without additives, is very important for the prevention in industrial fire and explosion accidents. Explosive limits of all compounds and solvent mixtures can be calculated with the appropriate use of the fundamental laws of Raoult, Batten, Le Chatelier and MRSM(modified response surface methodology) model. In this study, the reference values of lower explosive limits(LEL) of the ethanol+toluene+ethylacetate system were compared with the calculated values by using the solution thermodynamics and the MRSM model, respectively. The values calculated by the proposed equations were a good agreement with literature data within a few percent. By means of this methodology, it is possible to evaluate reliability of experimental data of the lower explosive limits of the flammable mixtures. Also, from given results, it is possible to predict explosive limits of the other flammable liquid mixtures used in the chemical process by the use of the proposed equations.