• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.524-525
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• 2005

The principal problems in development of dielectric paste materials for PDP(plasma display panel)are PbO free paste and low melting temperature. We prepared PbO free paste from glasses in the system $ZnO-B_2O_3-Bi_2O_3-SiO_2$, DTA, and XRD were used to characterize $ZnO-B_2O_3-Bi_2O_3-SiO$ glasses. In this present study, PbO free paste had thermal expansion of $74\times10^{-7}/^{\circ}C$, DTA transformation point of $470^{\circ}C$, and firing condition of $540^{\circ}C$, 20min.

• 대한금속재료학회지
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• 제46권8호
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• pp.516-523
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• 2008

The effect of glass-frit size on microstructural evolution and electrical resistance of conductive silver paste was investigated. Silver paste was prepared by mixing 70 wt% commercial silver powder with $1.6{\mu}m$, 3 wt% Bi based glass-frit and 27 wt% organic vehicle. Two different sizes of glass-frit were obtained by ball-milling of commercial glass-frit ($3{\mu}m$) for 3 and 5 days, which had an average particle size of 1.0 and $0.5{\mu}m$. The smaller glass-frit was melt at low sintered temperature and rapidly spread between the silver particles, which is induced the dense networking among silver particles and strong adhesiveness to $Al_2O_3$ substrate. The silver film with smaller glass-frit sintered at $500^{\circ}C$ showed the small pore size and low porosity resulting in low electrical resistivity of $4{\mu}{\Omega}cm$.

• Journal of Pharmaceutical Investigation
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• 제6권1호
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• pp.26-32
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• 1976

Dicalcium phosphate dihydrate (DCPD) is the most widely-used dentifrice abrasive in non-therapeutic tooth-paste requiring, low abrasive level, high stability and excellent compatibility with other formulation ingredients. One of the difficulties encountered in the use of this material in tooth-paste is that unless storage of the product is maintained at a relative low temperature there is a distinct tendency to lose water of crystallization. Another difficulty which has been encountered is that there is a tendency for the product to become lumpy. Various means have been proposed for increasing the stability and overcoming the lumping tendency, most of which means comprise the addition of stabilizing agent. But there is not any report about the relationships between the mechanism of dehydration, physical properties, structure and manufacturing condition. In this experiment, DCPD were manufactured by methods of Moss' patent, its two varied and J.P.VIII, these were studied by means of stability test, IR spectra, and DTA. According to the manufacturing conditions, DCPD has different physical properties and structures, i. e., monoclinic system of low drying temperature, triclinic system of high drying temperature. Dehydration of DCPD may be supposed one step debydration at about $100^{\circ}$ and it finaly converts to ${\gamma}-pyrophosphate$ at about $465^{\circ}$ and if the drying temperature is high it becomes DCP anhydrous. DCPD made by Moss' patent is thought of the best polishing agent of tooth-paste.

• 한국분말재료학회지
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• 제19권5호
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• pp.343-347
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• 2012

In this study, an oxygen plasma treatment was used as a low temperature debinding method to form a conductive copper feature on a flexible substrate using a direct printing process. To demonstrate this concept, conductive copper patterns were formed on polyimide films using a copper nanoparticle-based paste with polymeric binders and dispersing agents and a screen printing method. Thermal and oxygen plasma treatments were utilized to remove the polymeric vehicle before a sintering of copper nanoparticles. The effect of the debinding methods on the phase, microstructure and electrical conductivity of the screen-printed patterns was systematically investigated by FE-SEM, TGA, XRD and four-point probe analysis. The patterns formed using oxygen plasma debinding showed the well-developed microstructure and the superior electrical conductivity compared with those of using thermal debinding.

• 콘크리트학회논문집
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• 제17권5호
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• pp.853-856
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• 2005

A low water/cement ratio leads to autogenous shrinkage of cement paste at an early age. This autogenous shrinkage is related to the change of relative humidity in the pore structure that is formed during the hydration process. The relationship between autogenous shrinkage and relative humidity change are relatively well defined today, but the effects of temperature on autogenous shrinkage, relative humidity, and pore structures have been studied less systematically. This study focused on correlating alterations of these properties of cement paste hydrated at constant temperatures of 20, 40, and $60^{\circ}C$. The test results clearly indicate that increasing curing temperature resulted in increased porosity, particularly for pores between 5 to 50 nm as measured by MIP, and increased autogenous shrinkages, as a consequence of a reduction of relative humidity at early ages.

• 한국식품과학회지
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• 제22권2호
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• pp.111-115
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• 1990

원료 성분조성이 다른 시판용 정맥 및 소맥된장의 두 종류 시료를 대상으로 하여 여러 농도의 물 현탁액 (50-200v/w%)을 조제하고 각 현탁액의 리올로지적 거동을 검토하였다. 각 시료 된장 현탁액은 모두 thixotropic 거동을 보였으며, 가수량이 125% 이하인 고농도 현탁액의 경우 전단상승곡선과 하강곡선이 교차하는 Figure-eight 현상을 나타내었다. 시료 모두 가열에 따라 겉보기 점도가 뚜렷한 증가 경향을 보였으며 단백질의 등전점 부근에서 겉보기 점도가 가장 높은점, 가수량 200%의 묽은 현탁액의 경우 $60^{\circ}C$이상으로 가열했을 때 Figure-eight 현상을 보이는 점 등을 종합하여 볼 때 점성거동은 단백질 존재상태와 밀접한 관련을 갖는 것으로 추정되었다.

• 한국식품과학회지
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• 제22권4호
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• pp.434-438
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• 1990

동결방지제를 첨가하여 붉은생고추 페이스트 및 딸기 펄프의 저온저장 실험을 한 결과, 붉은생고추 페이스트는 줄기만을 제거한 후 NaCl 15%, citric acid 0.5%를 첨가하면 $-9.6^{\circ}C$에서 미동결 상태로 저장할 수 있었고, 딸기펄프는 dextrose 25%, fructose 17%, sorbitol 8%, ascorbic acid 0.2%를 첨가했을 때 $-15^{\circ}C$까지도 미동결 상태로 저장할 수 있었다. 또한 동결방지제를 이용한 시료는 무처리한 시료에 비해 저장소요시간이 약 1/2 정도 걸리며, 소요에너지도 약 $70{\sim}80%$의 절감효과를 얻을 수 있었다. 따라서, 동결방지제를 이용하면 저온저장시 빙결정 생성에 따른 조직손상을 억제할 수 있을 뿐만 아니라 에너지 절감효과도 얻을 수 있는 것으로 사료되며, 이와 같은 결과를 일시에 다량 수확되는 과채류에 적용할시 농산물의 저장법 개선에 상당한 효과가 있을 것이다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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• pp.385-390
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• 2002

Autogenous shrinkage of concrete has been defined as decrease in volume due to hydration cement, not due to other causes such as evaporation, temperature change and external load and so on. For ordinary concretes, autogenous shrinkage is so little compared to the other deformations that it has been dignored. It has recently been proved, however, that autogenous shrinkage considerably increase with decrease in water to cement ratio. And it has been reported that cracking can be caused by autogenous shrinkage, when high- strength concretes were used. In this study, we propose an analytical system to represent autogenous shrinkage in cement paste in order to control crack due to autogenous shrinkage. The system is composed with the hydration model and pore structure model. Contrary to the usual assumption of uniform properties in the hydration progress, the hydration model to refine Tomosawa's represents the situation that inner and outer products are made in cement paste. The pore structure model is based upon the physical phenomenon of ion diffusion in cement paste and chemical phenomenon of hydration in cement particle. The proposed model can predict the pore volume ratio and the pore structure in cement paste under variable environmental conditions satisfactorily The autogenous shrinkage prdiction system with regard to pore structure development and hydration at early ages for different mix-proportions shows a reasonable agreement with the experimental data.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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• pp.1096-1099
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• 2004

The principal problems in development of dielectric paste materials for PDP(plasma display panel)are PbO free paste and low melting temperature. We prepared PbO free paste from glasses in the system BaO-ZnO-$B_2O_3$-$V_2O_5$. DTA, and XRD were used to characterize BaO-ZnO-$B_2O_3$-$V_2O_5$ glasses. In this present study, PbO free paste had thermal expansion of $74\times10^{-7}/^{\circ}C$, DTA softening point of $460^{\circ}C$, and firing condition of $520^{\circ}C$, 20min

• 한국태양에너지학회 논문집
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• 제38권1호
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• pp.45-55
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• 2018

Environmentally benign lead-free solder coated ribbon (e. g. SnCu, SnZn, SnBi${\cdots}$) has been intensively studied to interconnect cells without lead mixed ribbon (e. g. SnPb) in the crystalline silicon(c-Si) photovoltaic modules. However, high melting point (> $200^{\circ}C$) of non-lead based solder provokes increased thermo-mechanical stress during its soldering process, which causes early degradation of PV module with it. Hence, we proposed low-temperature conductive paste (CP) based tabbing method for lead-free ribbon. Modules, interconnected by the lead-free solder (SnCu) employing CP approach, exhibits similar output without increased resistivity losses at initial condition, in comparison with traditional high temperature soldering method. Moreover, 400 cycles (2,000 hour) of thermal cycle test reveals that the module integrated by CP approach withstands thermo-mechanical stress. Furthermore, this approach guarantees strong mechanical adhesion (peel strength of ~ 2 N) between cell and lead-free ribbons. Therefore, the CP based tabbing process for lead free ribbons enables to interconnect cells in c-Si PV module, without deteriorating its performance.