• Title/Summary/Keyword: Low-temperature paste

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A Study on the Characteristics of Low Temperature Calcined Phosphor Paste (저온소성 형광체 페이스트의 특성 연구)

  • Lee, Dong-Wook;Lee, Mi-Young;Ahn, Suk-Chul;Nam, Su-Yong
    • Clean Technology
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    • v.14 no.1
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    • pp.14-20
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    • 2008
  • In this study we have manufactured and characterized the low temperature calcined phosphor paste that can be used as a flat light source for LCD BLU. For the phosphor paste, the low temperature calcined acryl resin was used as the binder. From the result of thermal decomposition measurement, residual carbonaceous materials was found to be less than 0.1 wt% at $400^{\circ}C$. A flat light source device that was made by screen printing using the manufactured paste showed a near 100% luminous efficiency compared to the luminance of the phosphor.

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Investigated properties of Low temperature curing Ag Paste for Silicon Hetero-junction Solar Cell

  • Oh, Donghyun;Jeon, Minhan;Kang, Jiwoon;Shim, Gyeongbae;Park, Cheolmin;Lee, Youngseok;Kim, Hyunhoo;Yi, Junsin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.160-160
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    • 2016
  • In this study, we applied the low temperature curing Ag paste to replace PVD System. The electrode formation of low temperature curing Ag paste for silicon Hetero-junction solar cells is important for improving device characteristics such as adhesion, contact resistance, fill factor and conversion efficiency. The low temperature curing Ag paste is composed various additives such as solvent, various organic materials, polymer, and binder. it depends on the curing temperature conditions. The adhesion of the low temperature curing Ag paste was decided by scratch test. The specific contact resistance was measured using the transmission line method. All of the Ag electrodes were experimented at various curing temperatures within the temperature range of $160^{\circ}C-240^{\circ}C$, at $20^{\circ}C$ intervals. The curing time was also changed by varying the conditions of 10-50min. In the optimum curing temperature $200^{\circ}C$ and for 20 min, the measured contact resistance is $19.61m{\Omega}cm^2$. Over temperature $240^{\circ}C$, confirmed bad contact characteristic. We obtained photovoltaic parameter of the industrial size such as Fill Factor (FF), current density (Jsc), open-circuit voltage (Voc) and convert efficiency of up to 76.2%, 38.1 mA/cm2, 646 mV and 18.3%, respectively.

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A Study on the Characteristics of Low Temperature Calcined Paste for LCD Flat Light Source (LCD 면광원용 저온 소성 Paste 특성 연구)

  • Lee, Dong-Wook;Lee, Mi-Young;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.26 no.1
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    • pp.97-111
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    • 2008
  • BLU is a important part of the most representative LCD at flat panel display. In order to supplement the optical special quality which LCD cannot light itself, BLU is an essential property to supply with same brightness on the screen. In this study we have manufactured and characterized the low temperature calcined paste that can be used as a flat light source for LCD BLU. For the phosphor paste and intermediate paste, the low temperature calcined acryl resin was used as the binder. From the result of thermal decomposition measurement, residual carbonaceous materials was found to be less than 0.2wt% at $400^{\circ}C$.

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The application of Nano-paste for high efficiency back contact Solar cell (고효율 후면 전극형 태양전지를 위한 나노 Paste의 적용에 대한 연구)

  • Nam, Donghun;Lee, Kyuil;Park, Yonghwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.53.2-53.2
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    • 2010
  • In this study, we focused on our specialized electrode process for Si back-contact crystalline solar cell. It is different from other well-known back-contact cell process for thermal aspect and specialized process. In general, aluminum makes ohmic contact to the Si wafer and acts as a back surface reflector. And, silver is used for low series resistance metal grid lines. Aluminum was sputtered onto back side of wafer. Next, silver is directly patterned on the wafer by screen printing. The sputtered aluminum was removed by wet etching process after rear silver electrode was formed. In this process, the silver paste must have good printability, electrical property and adhesion strength, before and after the aluminum etching process. Silver paste also needs low temperature firing characteristics to reduce the thermal budget. So it was seriously collected by the products of several company of regarding low temperature firing (below $250^{\circ}C$) and aluminum etching endurance. First of all, silver pastes for etching selectivity were selected to evaluate as low temperature firing condition, electrical properties and adhesive strength. Using the nano- and micron-sized silver paste, so called hybrid type, made low temperature firing. So we could minimize the thermal budget in metallization process. Also the adhesion property greatly depended on the composition of paste, especially added resin and inorganic additives. In this paper, we will show that the metallization process of back-contact solar cell was realized as optimized nano-paste characteristics.

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Fabrication of Photoimageable Silver Paste for Low-Temperature Cofiring Using Acrylic Binder Polymers and Photosensitive Materials

  • Park, Seong-Dae;Yoo, Myong-Jae;Kang, Nam-Kee;Park, Jong-Chul;Lim, Jin-Kyu;Kim, Dong-Kook
    • Macromolecular Research
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    • v.12 no.4
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    • pp.391-398
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    • 2004
  • Thick-film photolithography is a new technology that combines lithography processes, such as exposure and development, with the conventional thick-film process applied to screen-printing. In this study, we developed a low-temperature cofireable silver paste applicable for thick-film processing to form fine lines using photolitho-graphic technologies. The optimum paste composition for forming fine lines was investigated. The effect of processing parameters, such as the exposing dose, had on the fine-line resolution was also investigated. As the result, we found that the type of polymer and monomer, the silver powder loading, and the amount of photoinitiator were the main factors affecting the resolution of the fine lines. The developed photoimageable silver paste was printed on a low-temperature cofireable green sheet, dried, exposed, developed in an aqueous process, laminated, and then fired. Our results demonstrate that thick-film fine lines having widths < 20 $\mu\textrm{m}$ can be obtained after cofiring.

Low-Temperature Chemical Sintered TiO2 Photoanodes Based on a Binary Liquid Mixture for Flexible Dye-Sensitized Solar Cells

  • Md. Mahbubur, Rahman;Hyeong Cheol, Kang;Kicheon, Yoo;Jae-Joon, Lee
    • Journal of Electrochemical Science and Technology
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    • v.13 no.4
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    • pp.453-461
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    • 2022
  • A chemically sintered and binder-free paste of TiO2 nanoparticles (NPs) was prepared using a binary-liquid mixture of 1-octanol and CCl4. The 1:1 (v/v) complex of CCl4 and 1-octanol easily interacted chemically with the TiO2 NPs and induced the formation of a highly viscous paste. The as-prepared binary-liquid paste (PBL)-based TiO2 film exhibited the complete removal of the binary-liquid and residuals with the subsequent low-temperature sintering (~150℃) and UV-O3 treatment. This facilitated the fabrication of TiO2 photoanodes for flexible dye-sensitized solar cells (f-DSSCs). For comparison purposes, pure 1-octanol-based TiO2 paste (PO) with moderate viscosity was prepared. The PBL-based TiO2 film exhibited strong adhesion and high mechanical stability with the conducting oxide coated glass and plastic substrates compared to the PO-based film. The corresponding low-temperature sintered PBL-based f-DSSC showed a power conversion efficiency (PCE) of 3.5%, while it was 2.0% for PO-based f-DSSC. The PBL-based low- and high-temperature (500℃) sintered glass-based rigid DSSCs exhibited the PCE of 6.0 and 6.3%, respectively, while this value was 7.1% for a 500℃ sintered rigid DSSC based on a commercial (or conventional) paste.

A Study on the Characteristics of Low Temperature Firing Phosphor Paste for Flat Light Source (면광원용 저온 소성형 형광체 Paste 특성 연구)

  • Lee, Dong-Wook;Nam, Su-Yong
    • Proceedings of the Korean Printing Society Conference
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    • 2007.11a
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    • pp.75-81
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    • 2007
  • As manufacturing the low temperature firing paste applicable flat light source for LCD BLU, this study examined the specific quality. For the phosphor pastes, the low temperature firing acryl resin is used as the binder resin. As the result of thermal decomposition characteristics, residual hydroxylcarbon rested under 0.1wt% on 400$^{\circ}C$. With the manufactured paste in this study, the flat light source device is manufactured through the screen printing and it brought the almost 100% of special quality radiation about the phosphor brightness.

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Preparation of Lead-free Silver Paste with Nanoparticles for Electrode (나노입자를 첨가한 전극용 무연 silver 페이스트의 제조)

  • Park, Sung Hyun;Park, Keun Ju;Jang, Woo Yang;Lee, Jong Kook
    • Journal of the Korean Society for Heat Treatment
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    • v.19 no.4
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    • pp.219-224
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    • 2006
  • Silver paste with low sintered temperature has been developed in order to apply electronic parts, such as bus electrode, address electrode in PDP (Plasma Display Panel) with large screen area. In this study, nano-sized silver particles with 10-30 nm were synthesized from silver nitrate ($AgNO_3$) solution by chemical reduction method and silver paste with low sintered temperature was prepared by mixing silver nanoparticles, conventional silver powder with the particle size 1.6 um and Pb-free frit. Conductive thick film from silver paste was fabricated by screen printing on alumina substrate. After firing at $540^{\circ}C$, the cross section and surface morphology of the thick films were analyzed by FE-SEM. Also, the sheet resistivity of the fired thick films was measured using the four-point technique.

Efficiency Characteristics of DSSC Using TiO2 Paste for Low Temperature Annealing with TTIP (TTIP가 첨가된 저온소성용 TiO2 Paste를 이용한 DSSC의 효율 특성)

  • Kwon, Sung Yeol;Sim, Chang Soo;Yang, Wook
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.1
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    • pp.53-57
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    • 2019
  • Recently, the application field of solar panels is increasing. Accordingly, the demand for flexible devices is also steadily increasing. It is therefore necessary to develop $TiO_2$ paste for low-temperature annealing for flexible DSSC fabrication. In this study, the $TiO_2$ paste for low-temperature annealing with varying molar ratio of titanium isopropoxide (TTIP) was prepared, and DSSC was fabricated and its characteristics were compared. As a result, there was no deformation of the particles on the surface in the SEM data. However, the highest open circuit voltage, short circuit current, and fill factor were measured in the DSSC unit cell prepared by adding 0.5 mol of TTIP to the $TiO_2$ paste, and the highest efficiency was 4.148%.

Flexible Dye-sensitized Solar Cell Using Titanium Gel at Low Temperature (저온 티타늄 겔을 이용한 플렉시블 염료감응형 태양전지)

  • Ji, Seung Hwan;Park, Hyunsu;Kim, Doyeon;Han, Do Hyung;Yun, Hye Won;Kim, Woo-Byoung
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.183-188
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    • 2019
  • Flexible dye-sensitized solar cells using binder free $TiO_2$ paste for low temperature sintering are developed. In this paste a small amount of titanium gel is added to a paste of $TiO_2$ nanoparticle. Analysis of titanium gel paste prepared at $150^{\circ}C$ shows that it has a pure anatase phase in XRD and mesoporous structure in SEM. The formation of the titanium gel 1-2 nm coated layer is confirmed by comparing the TEM image analysis of the titanium gel paste and the pristine paste. This coating layer improves the excited electron transfer and electrical contact between particles. The J-V curves of the organic binder DSSCs fabricated at $150^{\circ}C$ shows a current density of $0.12mA/cm^2$ and an open-circuit voltage of 0.47 V, while the titanium gel DSSCs improves electrical characteristics to $5.04mA/cm^2$ and 0.74 V. As a result, the photoelectric conversion efficiency of the organic binder DSSC prepared at low temperature is as low as 0.02 %, but the titanium gel paste DSSCs has a measured effciency of 2.76 %.