• Title/Summary/Keyword: Low-density concentration

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Synethisis of fine BSCCO precursor powder by spray pyrolysis (분무 열분해에 의한 미세 BSCCO 전구체 분말의 합성)

  • 김성환;유재무;고재웅;김영국;박성창
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.99-102
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    • 2003
  • Many researches on synthesis process for BSCCO precursor powders have been developed for high J$_{c}$ BSCCO-2223/Ag tape. Spray pyrolysis method for fabrication of precursor powder has many advantages, such as high purity, fine particle size of BSCCO precursor powder. Fine, spherical powders were prepared by ultrasonic spray pyrolysis from the aqueous solution of metal nitrates. BSCCO precursor powders were synthesized with 0.1 M concentration and heat treatment conditions. Average particle size for spray pyrolysis powders was 1.5 ~ 3 ${\mu}{\textrm}{m}$. BSCCO -2223/Ag tape was prepared by PIT method and followed by various sintering conditions. The critical current density of BSCCO-2223/Ag tape sintered in low oxygen partial pressure was ~ 23 kAcm$^{-2}$.

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Effect of Electrolyte Composition on Corrosion Behavior of PEO Treated AZ91 Mg Alloy

  • Park, Kyeong Jin;Lee, Jae Ho
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.227-231
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    • 2009
  • Mg and Mg alloys have been used for lots of applications, including automobile industry, aerospace, mobile phone and computer parts owing to low density. However, Mg and Mg alloys have a restricted application because of poor corrosion properties. Thus, improved surface treatments are required to produce protective films that protect the substrate from corrosive environments. Environmental friendly Plasma Electrolytic Oxidation (PEO) has been widely investigated on magnesium alloys. PEO process combines electrochemical oxidation with plasma treatment in the aqueous solution. In this study, AZ91 Mg alloys were treated by PEO process in controlling the current with PC condition and treated time, concentration of NaF, NaOH, and $Na_2SiO_3$. The surface morphology and phase composition were analyzed using SEM, EDS and XRD. The potentiodynamic polarization tests were carried out for the analysis of corrosion properties of specimen. Additionally, salt spray tests were carried out to examine and compare the corrosion properties of the PEO treated Mg alloys.

Thermal Conductivities of Nanofluids (나노 유체(Nanofluids)의 열전도도)

  • Jang, Seok-Pil
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1388-1393
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    • 2004
  • Investigators have been perplexed with the thermal phenomena behind the recently discovered nanofluids, fluids with unprecedented stability of suspended nanoparticles although huge difference in the density of nanoparticles and fluid. For example, nanofluids have anomalously high thermal conductivities at very low fraction, strongly temperature-dependent and size-dependent conductivities, and three-fold higher critical heat flux than that of base fluids. Traditional conductivity theories such as the Maxwell or other macroscale approaches cannot explain why nanofluids have these intriguing features. So in this paper, we devise a theoretical model that accounts for the fundamental role of dynamic nanoparticles in nanofluids. The proposed model not only captures the concentration and temperature-dependent conductivity, but also predicts strongly size-dependent conductivity. Furthermore, we physically explain the new phenomena for nanofluids. In addition, based on a proposed model, the effects of various parameters such as the ratio of thermal conductivity of nanofluids to that of a base fluid, volume fraction, nanoparticle size, and temperature on the thermal conductivities of nanofluids are investigated.

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A study on radiation degradation of LDPE by using ESR (ESR을 이용한 저밀도 폴리에틸렌의 방사선 열화에 관한 연구)

  • Kim, Ki-Yup;Kim, Jin-Ah;Lee, Chung;Kim, Pyeong-Jong;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.473-476
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    • 2004
  • This study has investigated radiation degradation of low density polyethylene(LDPE). Samples were irradiated using a $Co^{60}\;\gamma-ray$ and ray up to 800 kGy at a dose rate of 5 kGy/hr in the presence of air atmosphere at room temperature. After irradiation, free radical measurement of LDPE has established by electron spin resonance(ESR). Then, each sample was stored for 2 weeks. ESR measurement showed that free radical concentration(FRC) was increased with radiation dose and changed from alkyl, allyl radical to peroxy radical with time.

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Application of monodisperse Fe3O4 submicrospheres in magnetorheological fluids

  • Anupama, A.V.;Kumaran, V.;Sahoo, B.
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.347-357
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    • 2018
  • Steady shear response of a magnetorheological fluid (MRF) system containing porous mono-disperse magnetite ($Fe_3O_4$) spheres synthesized by solvothermal method is demonstrated. In applied magnetic field the interaction between the spherical particles leads to form strong columnar structures enhancing the yield strength and viscosity of the MRFs. The yield strengths of the MRFs also scale up with the concentration of magnetic particles in the fluid. Considering magnetic dipolar interaction between the particles the magneto-mechanical response of the MRFs is explained. Unlike metallic iron particles, the low-density corrosion resistant soft-ferrimagnetic $Fe_3O_4$ spherical particles make our studied MRF system efficient and reliable for shock-mitigation/vibration-isolation applications.

Effect of Cell Density on Xylitol Fermentation by Candida parapsilosis (Candida parapsilosis에 의한 Xylitol 생산시 균체농도가 미치는 영향)

  • Kim, Sang-Yong;Yoon, Sang-Hyun;Kim, Jung-Min;Oh, Deok-Kun
    • Korean Journal of Food Science and Technology
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    • v.28 no.5
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    • pp.970-973
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    • 1996
  • Effect of cell density on the xylitol production from xylose by Candida parapsilosis KFCC 10875 was investigated. The concentrated cells were obtained by centrifugation of culture broth. The xylitol production rate was maximum at the cell concentration of 20 g/l and the specific xylitol production rate decreased when the cell concentration was increased due to oxygen limitation. Effect of the initial concentration of xylose on the xylitol production was also examined using the concentrated cells of 20 g/l. The xylitol production rate, specific xylitol production rate, and xylitol yield from xylose were maximum at 170 g/l xylose. Above 170 g/l xylose, the xylitol production rate was remarkably decreased. The concentrated cells could also be obtained by adjusting the dissolved oxygen (DO) during fermentation. The rapid accumulation of cells up to 20 g/l was achieved by maintaining an increased level of DO during the exponential growth phase and then, for the efficient xylitol production, the DO was changed to a low level in the range of 0.7-1.5%. A fed-batch fermentation of xylose by adjusting the DO level was carried out in a fermentor and the final xylitol concentration of 140 g/l from xylose of 200 g/l could be obtained for 56 h fermentation.

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Estimation of Mass Size Distribution of Atmospheric Aerosols Using Real-Time Aerosol Measuring Instruments (실시간 에어로졸 측정장비를 이용한 대기 중 입자상 물질의 무게 농도 분포의 추정)

  • Ji, Jun-Ho;Bae, Gwi-Nam
    • Particle and aerosol research
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    • v.9 no.2
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    • pp.39-50
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    • 2013
  • Real-time aerosol measuring instruments have been widely used for the measurement of atmospheric aerosol, diesel particulate matter, or material synthesis. A scanning mobility particle sizer (SMPS) measures the number size distribution of particles using electrical mobility detection technique. An aerodynamic particle sizer (APS) is used to determine the number concentration and the mean aerodynamic diameter of test particles. An electrical low-pressure impactor (ELPI) is a multi-stage impaction device to separate airborne particles into aerodynamic size classes using particle charging and electrical detection techniques. In this study, the performance of these instruments were evaluated to assess their ability to obtain mass concentrations from particle number concentration measurements made as a function of particle size. The effect of determination of particle density on the measurement of mass concentration was investigated for the three instruments.

Response of Achlya racemosa, A. proliferoides and Saprolegnia furcata to Sub-lethal Treatments of Amino Acids

  • Ali, Esam H.
    • Mycobiology
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    • v.31 no.2
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    • pp.86-94
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    • 2003
  • The effect of four sub-lethal concentrations(400, 800, 1,200 and 1,600 ${\mu}g/ml$) of three amino acids such as isoluecine, aspartic acid and phenylalanine on vegetative growth and sexual and asexual reproduction of Achlya racemosa, A. proliferoides and Saprolegnia furcata was investigated. The density of vegetative growth and diameters of vegetative colonies of species of the Oomycetes fungi decreased with rising the concentration of the applied amino acid. Vegetative hyphae of treated fungi almost appeared branched in case of S. furcata, thick in case of A. racemosa and distorted in case of A. proliferoides as compared with control. The different treatments with amino acids depressed both sporangial formation and discharge, which were dependent on the tested species of zoosporic fungi, the amino acid and its dosage. Phenylalanine was the most effective amino acid in inhibiting sporulation and S. furcata was the most sensitive fungal species. Aspartic acid and isoleucine stimulated germination of discharged spores through the formation of germlings. Gemmae formation by the three fungi was reduced at the low concentrations of amino acids and nearly missed at high concentrations. Sex organs(oogonia and antheridia) were affected partly; rudiment oogonia were observed at low concentrations(400 and 800 ${\mu}g/ml$) and disappeared at higher concentrations, whereas antheridial branch formation was stimulated as the fungi were treated with isoleucine and to some extent phenylalanine.

Effects of Film Formation Conditions on the Chemical Composition and the Semiconducting Properties of the Passive Film on Alloy 690

  • Jang, HeeJin;Kwon, HyukSang
    • Corrosion Science and Technology
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    • v.5 no.4
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    • pp.141-148
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    • 2006
  • The chemical composition and the semiconducting properties of the passive films formed on Alloy 690 in various film formation conditions were investigated by XPS, photocurrent measurement, and Mott-Schottky analysis. The XPS and photocurrent spectra showed that the passive films formed on Alloy 690 in pH 8.5 buffer solution at ambient temperature, in air at $400^{\circ}C$, and in PWR condition comprise $Cr_2O_3$, $Cr(OH)_3$, ${\gamma}-Fe_2O_3$, NiO, and $Ni(OH)_2$. The thermally grown oxide in air and the passive film formed at high potential (0.3 $V_{SCE}$) in pH 8.5 buffer solution were highly Cr-enriched, whereas the films formed in PWR condition and that formed at low potential (-0.3 $V_{SCE}$) in pH 8.5 buffer solution showed relatively high Ni content and low Cr content. The Mott-Schottky plots exhibited n-type semiconductivity, inferring that the semiconducting properties of the passive films formed on Alloy 690 in various film formation conditions are dominated by Cr-substituted ${\gamma}-Fe_2O_3$. The donor density, i.e., concentration of oxygen vacancy, was measured to be $1.2{\times}10^{21}{\sim}4.6{\times}10^{21}cm^{-3}$ and lowered with increase in the Cr content in the passive film.

CF4 Treatment Characteristics using an Elongated Arc Reactor (신장 아크 반응기를 이용한 CF4 처리특성)

  • Kim, Kwan-Tae;Lee, Dae-Hoon;Lee, Jae-Ok;Cha, Min-Suk;Song, Young-Hoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.26 no.1
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    • pp.85-93
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    • 2010
  • $CF_4$ removal characteristics were investigated using an elongated arc reactor. The advantage of the elongated arc reactor includes direct use of treated gas as plasma operating gas and the enhancement of the removal reaction by using a thermo-chemistry and a plasma induced chemistry at the same time. Geometrical configurations, such as the length of the reactor and the shape of a throat, were tested to get an optimized removal efficiency with low power consumption. As results, over 95% of $CF_4$ removal was obtained with 300 lpm of total flowrate for various $CF_4$ concentration (0.1~1%). Corresponding specific energy density (SED), which means required electrical energy to treat the unit volume of treated gas, is about 3.5 kJ/L, The present technique can be applied to real applications by satisfying three major concerns, those are the high flowrate of treated gas, high removal efficiency (> 95%), and low power consumption (< 10 kJ/L).