• Title/Summary/Keyword: Low temperature phase

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Growth of α-Ga2O3 Epitaxial Films on Al2O3 by Halide Vapor Pressure Epitaxy

  • Lee, Daejang;Cha, An-Na;Park, Junseong;Noh, Hogyun;Moon, Youngboo;Ha, Jun-Seok
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.4
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    • pp.113-118
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    • 2019
  • In this study, we investigated the growth of single-crystallinity α-Ga2O3 thin films on c-plane sapphire substrates using halide vapor pressure epitaxy. We also found the optimal growth conditions to suppress the phase transition of α-Ga2O3. Our results confirmed that the growth temperature and partial pressure of the reactive gas greatly influenced the crystallinity. The optimal growth temperature range was about 460~510℃, and the α-Ga2O3 thin films with the highest crystallinity were obtained at a III/VI ratio of 4. The thickness and surface morphology of the thin films was observed by scanning electron microscopy. The film thickness was 6.938 ㎛, and the full width at half maximum of the ω-2θ scan rocking curve was as small as 178 arcsec. The optical band gap energy obtained was 5.21 eV, and the films were almost completely transparent in the near-ultraviolet and visible regions. The etch pit density was found to be as low as about 6.0 × 104 cm-2.

The Particle Size Distribution of $\alpha-Fe_2O_3$from Mossbauer Spectra (${\Alpha}-Fe_2O_3$ 미세입자의 크기분포에 관한 Mossbauer 분광학적 연구)

  • 이민용;김시정;고영복;서정철;이충섭
    • Journal of the Korean Magnetics Society
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    • v.9 no.1
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    • pp.23-28
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    • 1999
  • ${\Alpha}-Fe_2O_3$ was accomplished by chemical method as low temperature as possible and the crystallographic and magnetic properties have been studied by Mossbauer spectroscopy and X-ray diffraction. The sample heated at 15$0^{\circ}C$ is found to have a Corundums symmetry with the hexagonal lattice constant a=8.26$\pm$0.05$\AA$, c=8.75$\pm$0.05$\AA$. The M$\"{o}$ssbauer spectra between the 4.2K and the room temperature show that the ${\Alpha}-Fe_2O_3$ crystallized with a single phase and fine sizes. The particle size distribution has the Gaussian distribution center at 98$\AA$ and the half width of 32$\AA$.TEX>.

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Steady-State/Transient Performance Simulation of the Propulsion System for the Canard Rotor Wing UAV during Flight Mode Transition

  • Kong, Changduk;Kang, Myoungcheol;Ki, Jayoung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2004.03a
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    • pp.513-520
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    • 2004
  • A steady-state/transient performance simulation model was newly developed for the propulsion system of the CRW (Canard Rotor Wing) type UAV (Unmanned Aerial Vehicle) during flight mode transition. The CRW type UAV has a new concept RPV (Remotely Piloted Vehicle) which can fly at two flight modes such as the take-off/landing and low speed forward flight mode using the rotary wing driven by engine bypass exhaust gas and the high speed forward flight mode using the stopped wing and main engine thrust. The propulsion system of the CRW type UAV consists of the main engine system and the duct system. The flight vehicle may generally select a proper type and specific engine with acceptable thrust level to meet the flight mission in the propulsion system design phase. In this study, a turbojet engine with one spool was selected by decision of the vehicle system designer, and the duct system is composed of main duct, rotor duct, master valve, rotor tip-jet nozzles, and variable area main nozzle. In order to establish the safe flight mode transition region of the propulsion system, steady-state and transient performance simulation should be needed. Using this simulation model, the optimal fuel flow schedules were obtained to keep the proper surge margin and the turbine inlet temperature limitation through steady-state and transient performance estimation. Furthermore, these analysis results will be used to the control optimization of the propulsion system, later. In the transient performance model, ICV (Inter-Component Volume) model was used. The performance analysis using the developed models was performed at various flight conditions and fuel flow schedules, and these results could set the safe flight mode transition region to satisfy the turbine inlet temperature overshoot limitation as well as the compressor surge margin. Because the engine performance simulation results without the duct system were well agreed with the engine manufacturer's data and the analysis results using a commercial program, it was confirmed that the validity of the proposed performance model was verified. However, the propulsion system performance model including the duct system will be compared with experimental measuring data, later.

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The stability comparison of purified bee venom and bee venom melittin in aqueous solution (수용액에서 정제봉독 (PBV)과 봉독멜리틴 (BVM)의 안정성 비교)

  • Park, Jung Keun;Shen, Chang Zhe;Kim, Choul Goo;Kim, Il Kwang
    • Analytical Science and Technology
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    • v.29 no.4
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    • pp.194-201
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    • 2016
  • The stability comparison tests on purified bee venom (PBV) and bee venom melittin (BVM) in different conditions of temperature, solvent, and concentration were studied. High purity BVM (98.2 %) was separated from PBV by prep-HPLC (column, C4) and used to stability tests in aqueous phase. The stability of the PBV has been increased in the saline solution, while BVM was reduced. In distilled water, the stability of PBV has been reduced, while BVM showed an increasing result. As a result, the appropriate conditions for maintaining the long term stability of BVM were found to be the low temperature (4 ℃), distilled water, and concentration (1.0 mg/mL).

Growth of Gallium Oxide Thin Film on c-, a-, m-, r-Plane Sapphire Substrates Using Mist Chemical Vapor Deposition System (미스트 화학기상증착법을 이용한 c면, a면, m면, r면 사파이어 기판 위의 산화갈륨 박막 성장 연구 )

  • Gi-Ryeo Seong;Seong-Ho Cho;Kyoung-Ho Kim;Yun-Ji Shin;Seong-Min Jeong;Tae-Gyu Kim;Si-Young Bae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.1
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    • pp.74-80
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    • 2023
  • Gallium oxide (Ga2O3) thin films were grown on c-, a-, m-, r-plane sapphire substrates using a mist chemical vapor deposition system. Various growth temperature range of 400~600℃ was applied for Ga2O3 thin film deposition. Then, several structural properties were characterized such as film thickness, crystal phase, lattice orientation, surface roughness, and optical bandgap. Under the certain growth temperature of 500℃, all grown Ga2O3 featured rhombohedral crystal structures and well-aligned preferred orientation to sapphire substrate. The films grown on c-and r-plane sapphire substrates, showed low surface roughness and large optical bandgap compared to those on a-and m-plane substrates. Therefore, various sapphire orientation can be potentially applicable for future Ga2O3-based electronics applications.

Water film covering characteristic on horizontal fuel rod under impinging cooling condition

  • Penghui Zhang;Bowei Wang;Ronghua Chen;G.H. Su;Wenxi Tian;Suizheng Qiu
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4329-4337
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    • 2022
  • Jet impinging device is designed for decay heat removal on horizontal fuel rods in a low temperature heating reactor. An experimental system with a fuel rod simulator is established and experiments are performed to evaluate water film covering capacity, within 0.0287-0.0444 kg/ms mass flow rate, 0-164.1 kW/m2 heating flux and 13.8-91.4℃ feeding water temperature. An effective method to obtain the film coverage rate by infrared equipment is proposed. Water film flowing patterns are recoded and the film coverage rates at different circumference angles are measured. It is found the film coverage rate decreases with heating flux during single-phase convection, while increases after onset of nucleate boiling. Besides, film coverage rate is found affected by Marangoni effect and film accelerating effect, and surface wetting is significantly facilitated by bubble behavior. Based on the observed phenomenon and physical mechanism, dry-out depth and initial dry-out rate are proposed to evaluate film covering potential on a heating surface. A model to predict film coverage rate is proposed based on the data. The findings would have reliable guide and important implications for further evaluation and design of decay heat removal system of new reactors, and could be helpful for passive containment cooling research.

Effect of La0.7Sr0.3MnO3 addition on superconducting properties and local structure of (Bi, Pb)-2223 superconductor

  • M. A. Anugrah;R. P. Putra;J. Y. Oh;B. Kang
    • Progress in Superconductivity and Cryogenics
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    • v.25 no.2
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    • pp.5-9
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    • 2023
  • The effect of La0.7Sr0.3MnO3 (LSMO) addition on the superconducting property of Bi1.6Pb0.4Sr2Ca2Cu3O10+δ ((Bi, Pb)-2223) polycrystalline samples was studied. LSMO (0.3 wt.% to 2.0 wt.%) added (Bi, Pb)-2223 samples were prepared by using a solid-state reaction method. The XRD analyses show that as the LSMO addition increases, the volume fraction of the Bi-2223 phase is gradually decreased. The critical temperature (Tc) exhibits a gradual decrease with a single transition as the LSMO amount increases up to 1.0 wt.%, but a further addition of LSMO induces an abrupt decrease of Tc with a dual transition. The analyses on the local structure of the CuO2 plane from the X-ray absorption fine structure (EXAFS) measurements showed that for the samples with low concentration of LSMO up to 1.0 wt.%, the Cu-O bond length and the CuO2 plane ordering do not degrade from the values of pure (Bi, Pb)-2223, while they get worsen with a further increase of LSMO addition. These results open up the possibility of LSMO as artificial pinning centers of the (Bi, Pb)-2223 system for power application.

Changes in Microstructure and Mechanical Properties due to Heat Treatment of Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca Alloy Sheet Manufactured via Normal Casting and Twin Roll Casting Process (일반주조 및 쌍롤주조 공정으로 제조된 Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca 합금 판재의 열처리에 따른 미세조직 및 기계적 특성 변화)

  • Dong Hwan Eom;No Jin Park
    • Journal of the Korean Society for Heat Treatment
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    • v.36 no.6
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    • pp.359-366
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    • 2023
  • Changes in microstructure and mechanical properties of Mg-1.0Al-1.0Zn-0.2Mn-0.5Ca (AZMX1100) alloy sheet manufactured by normal casting and twin roll casting process, were studied according to process and heat treatment. Non-uniform microstructure was observed in the initial sheet produced through both processes, and in particular, tilted dendrites and shifted central segregation were observed in the twin roll casting sheet. It was homogenized through hot rolling and heat treatment, and heat treated at 350℃ and 400℃ to compare the effect of heat treatment temperature. Both sheets were homogenized by the hot rolling process, and the grain size increased as the heat treatment temperature and time increased. It was confirmed that the grain size, deviation, and distribution of the second phase were finer and more homogenized in the TRC sheet. Accordingly, mechanical properties such as hardness, formability, and tensile strength also showed better values. However, unlike other previously reported AZMX alloy systems, it showed low formability (Erichsen value), which was judged by the influence of Al2Ca present in the microstructure.

A Study on the Characteristics of Waste Heat from the Industrial Complexes for Residential and Commercial Sectors (가정.상업부문 이용을 위한 산업체 폐열특성 연구)

  • 최영찬;박태준;홍재창;조선영
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.242-247
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    • 1999
  • The characteristics of waste heat effluents from 11 industrial complexes of 7 areas were analyzed to investigate the possibility of waste heat recovery of huge amount of waste heat producing from various industrial complexes. This study presents a part of the research work for the industrial waste heat for development of energy integrated network system in broad city area, which will utilize industrial waste heat for residential and commercial areas, where they are located at some distances from the complexes. The amount of waste heat from the investigated complexes was detected as 148,913 TOE/year. However, It was analyzed 83% of the waste heat was analyzed the temperature range from 0$^{\circ}C$ to 200$^{\circ}C$. Also, it was evaluated that 82% of waste heat was exhausted by flue gases. Especially, the characteristics of waste heat for the areas where most heat concentrated, such as Tae-gu industrial complex, Ul-san petrochemitry complex, Yio-chun petrochemistry complex, and Chun-ju industrial complex were investigated more precisely. Total amount of waste heat discharged from these four areas were analyzed 114,402 TOE/year, which was occupied as 77% of the total waste heat for the studied areas, and 87% of the waste heat from the industries was exhausted by flue gaseous phase and temperature range was from 0$^{\circ}C$ to 200$^{\circ}C$ 18.1 million TOE/year waste heat was released from the fossil fuel power plants, however 95% of waste heat was analyzed as cooling water from surface condensers at power plants. The temperature range was measured from 27$^{\circ}C$ to 34$^{\circ}C$, which are unable to utilize due to its low temperature. Otherwise, 5% (894,800 TOE/year) waste heat released from power plants were observed as flue gas, which temperature ranged from 90$^{\circ}C$ to 170$^{\circ}C$.

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Optimal Salinity and Temperature Conditions for the Growth of the Ultra-small Rotifer Synchaeta kitina (초소형 Rotifer Synchaeta kitina의 성장을 위한 최적 염분 및 수온 조건)

  • Park, Jin-Chul;Park, Heum-Gi
    • Journal of Aquaculture
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    • v.21 no.2
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    • pp.70-75
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    • 2008
  • We investigated the optimum salinity and temperature conditions for mass culture of ultra-small rotifer Synchaeta kitina. In the salinity experiment of ranging within 5 and 30 psu, the population growth of S. kitina increased continuously up to 20 psu, and then decreased over 20 psu. Their maximum density showed 390.1 inds./mL at 5 psu. A pre-reproductive phase was shortened in low salinity than high salinity. Also, the maximum offsprings and maximum lifespan and lifespan of the female were 13.4 inds. and 5.9 days, respctively at 5 psu. In the temperature experiments of ranging within 16 and $32^{\circ}C$, the population growth of S. kitina increased continuously up to $24^{\circ}C$, and then decreased over $24^{\circ}C$. The highest maximum density showed 492.8 inds./mL at $16^{\circ}C$. Their offsprings increased significantly with temperature decrease, and the maximum number of offsprings per female was 9.2 females. at $16^{\circ}C$. Their lifespan increased with temperatures decrease and the longest lifespan was to 5.5 days at $16^{\circ}C$. From these results, we conclude that the optimum culture conditions of S. kitina is 5 psu and $16^{\circ}C$.