• 제목/요약/키워드: Low density polyethylene(LDPE)

검색결과 227건 처리시간 0.021초

메타로센 촉매를 이용한 저밀도 폴리에틸렌의 전기적 특성 (Electrical Properties Low-Density Polyethylene by use of Metallocene Catalyst)

  • 조돈찬;;;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.123-127
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    • 2000
  • In order to investigate the influence of manufacturing process on the electrical properties, we used two kinds of low density polyethylene prepared using metallocene catalyst (mL), linear low density polyethylene prepared using Ziegler catalyst (LL) and low density polyethylene by high pressure process (LD). mL has the narrowest composition and molecular weight distributions. We measured the dc and impulse breakdown strengths and current densities at 3$0^{\circ}C$, 6$0^{\circ}C$ and 9$0^{\circ}C$. mL had a higher breakdown strength and a lower high-field current than LD and LL. These results were discussed from the point of manufacturing processes.

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Effect of Corona Discharge Treatment on the Dyeability of Low-density Polyethylene Film

  • Park, Soo-Jin
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.35-36
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    • 2003
  • The purpose of this work is to investigate the surface modification of LDPE film via corona discharge treatment and subsequent graft polymerization, and their effect on the resulting dyeability is studied in terms of the surface functional groups, surface energetics, and acid-base interaction between the modified LDPE and the dyes used.

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Cabbage 와 Broccoli 의 저장중 품질유지에 미치는 포장환경의 영향 (Effects of Package Environment on Keeping Quality during Storage in Cabbage and Broccoli)

  • 심기환;;최진상
    • 한국식품저장유통학회지
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    • 제7권1호
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    • pp.33-37
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    • 2000
  • Effects on keeping quality according to the different package environment in cabbage and brccoli were studied. Opened 2 mil LDPE (low density polyethylene) sealed 4 mil LDPE and BA(barrier polyethylene) were used as package films. Weight loss was markedly in opened 2 mil LDPE in cabbage and broccoli as 6 and 28%, respectively. Carbon dioxide was higher in seal-packaging cabbage and broccoli with BA held at 4 $^{\circ}C$ was above 15 and 31% within 15 days, respectively, while oxygen content was depleted to 2% or less after 10 days. The main difference between volatile sulfur-containing compounds produced from cabbage and broccoli were the relative quantities and rates of production of hydrogen sulfide, carbonyl sulfide, methanethiol and dimethyl disulfide in opened 2 mil LDPE , sealed 4 mil LDPE and barrier bags during storage.

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제작방법에 따른 전력케이블용 폴리에틸렌 박막의 전기전도특성 (The Electrical Conduction Properties of Polyethylene Thin Film for Power Cable with Manufacturing Methods)

  • 조경순;이용우;이수원;홍진웅
    • E2M - 전기 전자와 첨단 소재
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    • 제10권5호
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    • pp.453-460
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    • 1997
  • In order to investigate the electrical conduction properties of polyethylene thin film for power cable with manufacturing methods, the thickness of specimen was the 30, 100[${\mu}{\textrm}{m}$] of LDPE and 200[${\mu}{\textrm}{m}$] of XLPE were manufactured. The experimental condition for conduction properties was measured until the breakdown occurs at temperature ranges from 30 to 110[$^{\circ}C$] and the electric field from 1$\times$10$^3$to 5$\times$10$^{6}$ [V/cm]. As for increase of temperature, the current density of LDPE was increased with constant ratio in low field, but changes with exponential function in high electric field. The tunnel current of pre-breakdown region is shifted toward low field as much as thermal excitation energy. At low electric field, the XLPE showed dominant electrical conduction properties by thermal excitation, and transformation of the electron was resisted by the crystal at high electric field.

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사출 블렌드 저밀도 폴리에틸렌의 절연파괴 특성 (Electrical Breakdown Properties of Extrusion Blended Low Density Polyethylene)

  • 조돈찬;김형주;신현택;이충호;이수원;홍진웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.593-596
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    • 2001
  • In the previous work, the effect of blending with two kinds of low density polyethylene (LDPE) on physical and electrical properties have been investigated. From the results, blending with two kinds of LDPE was effective method on changing the morphology of LDPE and improving the high-field characteristics in high temperature region. Especially, it suggested that the F$\_$BImp/ was associated with the changes of the crystal size. In this work, the relationship between the morphology and the high-field characteristics of blended LDPE was discussed. In addition, the physical and electrical properties of blended LDPE with extrusion treatment were investigated. The two groups of specimen were prepared; Group 1 was prepared by passing 1 time through the extruder included in the film-blowing process, and Group 2 was prepared by passing 2 times through the extruder. From the relation between the crystal size which was perpendicular to the (020) plane and the F$\_$BImp/ of blended LDPE, it was confirmed that the F$\_$BImp/ was associated with the changes of crystal size due to the blending. Moreover, the F$\_$BImp/ of blended LDPE in Group 2 was higher than that of blended LDPE in Group 1. The crystal size of the (020) plane became smaller according to the extrusion treatment. These results suggest that the uniform distribution and dispersion of crystalline occurred due to the extrusion treatment and the morphological change due to the extrusion treatment influenced on the electrical properties of blended LDPE.

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Plug Flow Reactor 모델을 이용한 폐플라스틱의 열분해 특성 해석 (Analysis on the Pyrolysis Characteristics of Waste Plastics Using Plug Flow Reactor Model)

  • 최상규;최연석;정연우;한소영;응웬 반 꾸잉
    • 신재생에너지
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    • 제18권4호
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    • pp.12-21
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    • 2022
  • The pyrolysis characteristics of high-density polyethylene (HDPE), low-density polyethylene (LDPE), and polypropylene (PP) were analyzed numerically using a 1D plug flow reactor (PFR) model. A lumped kinetic model was selected to simplify the pyrolysis products as wax, oil, and gas. The simulation was performed in the 400-600℃ range, and the plastic pyrolysis and product generation characteristics with respect to time were compared at various temperatures. It was found that plastic pyrolysis accelerates rapidly as the temperature rises. The amounts of the pyrolysis products wax and oil increase and then decrease with time, whereas the amount of gas produced increases continuously. In LDPE pyrolysis, the pyrolysis time was longer than that observed for other plastics at a specified temperature, and the amount of wax generated was the greatest. The maximum mass fraction of oil was obtained in the order of HDPE, PP, and LDPE at a specified temperature, and it decreased with temperature. Although the 1D model adopted in this study has a limitation in that it does not include material transport and heat transfer phenomena, the qualitative results presented herein could provide base data regarding various types of plastic pyrolysis to predict the product characteristics. These results can in turn be used when designing pyrolysis reactors.

Utilization of PTE and LDPE Plastic Waste and Building Material Waste as Bricks

  • Intan, Syarifah Keumala;Santosa, Sandra
    • 한국재료학회지
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    • 제29권10호
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    • pp.603-608
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    • 2019
  • Plastic waste is becoming a problem in various countries because of the difficulty of natural decomposition. One type is PET plastic(Polyethylene Terephthalate), which is often used as a bottle for soft drink packaging, and LDPE(Low Density Polyethylene), which is also widely used as a food or beverage packaging material. The use of these two types of plastic continuously, without good recycling, will have a negative impact on the environment. Building material waste is also becoming a serious environmental problem. This study aims to provide a solution to the problem of the above plastic waste and building material waste by making them into a mixture to be used as bricks. Research is carried out by mixing both materials, namely plastic heated at a temperature of $180-220^{\circ}C$ and building material waste that had been crushed and sized to 30-40 mesh with homogeneous stirring. The ratios of PET and LDPE plastic to building material waste are 9 : 1, 8 : 2, 7 : 3, 6 : 4 and 5 : 5. After heating and printing, density, water absorption and compressive strength tests are carried out. Addition of PET and LDPE plastic can increase compressive strength, and reduce water absorption, porosity and density. A maximum compressive strength of 10.5 MPa is obtained at the ratio of 6 : 4.

브렌드 저밀도 폴리에틸렌의 전기적 특성 및 브렌드 효과 (Electrical Properties and Blend Effect of Blended Low-Density Polyethylene)

  • 조돈찬;삼용웅;수곡조길;홍진웅
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1999년도 하계학술대회 논문집 D
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    • pp.1617-1620
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    • 1999
  • In this work, the effect of blend on physical and electrical properties investigated. The two kinds of low-density polyethylene (LDPE) whose densities are evaluated at $0.9179[g/cm^3]$ and $0.9192[g/cm^3]$, respectively, were used and blended according to the different blend ratio. The LDPE with the blend ratio of 50[wt%] represented the lowest impulse breakdown strength, $F_{BImp}$ at $30[^{\circ}C]$, but the highest $F_{BImp}$ at $90[^{\circ}C]$. DC breakdown strength, $F_{BDC}$. decreased with the increase of blend ratio at $30[^{\circ}C$, but increased at $60[^{\circ}C]$. The current density decreased with a blend ratio up to 75 [wt%] at $90[^{\circ}C]$. By analyzing the diffraction patterns of XRD, we found that the LDPE with the blend ratio of 50 [wt%] represented the largest crystal size of (020) plane. We investigated the relationship between the effect of blend and electrical properties and these results are discussed.

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Compositional Quenching 공정에 의한 LDPE/LLDPE 블렌드의 물성에 관한 연구 (A Study on the Properties of LDPE/LLDPE blends Prepared by Compositional Quenching Process)

  • 조수민;이영철;황석호;이상원;김수경
    • 공업화학
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    • 제7권3호
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    • pp.504-510
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    • 1996
  • 새로운 상용성 조절 기법인 compositional quenching 공정을 이용하여 LDPE(Low-density polyethylene)/LLDPE(Linear low-density polyethylene) 블렌드를 제조하고, 기존의 mechanical blending과 solution blending 방법으로 제조한 블렌드와 물성 등을 비교 고찰하였다. DSC thermogram에서는 $T_m$ peak와 $T_c$ peak가 세 가지 블렌드 방법에 따라 변하였다. Compositional quenching 공정에 의한 블렌드의 열적 성질은 solution blending에 의한 블렌드와 거의 유사하였으나 mechanical blending에 의한 블렌드와는 서로 다른 경향을 보였다. 이러한 결과는 matrix 내에 분산된 domain 크기에 의한 것으로 생각된다. 인장실험에서는 compositional quenching 공정과 solution blending에 의한 블렌드의 파괴신율이 mechanical blending방법에 의한 것에 비해 상대적으로 컸으며, Young's modulus는 mechanical blending에 의한 결과가 상대적으로 컸다. 또한 compositional quenching 공정과 solution blending에 의한 블렌드의 인장강도가 mechanical blending에 의한 것보다 큰 경향을 보였다.

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자몽종자추출물 처리와 포장방법에 따른 반건시 곶감의 품질 변화 (Effects of Grapefruit Seed Extract Pretreatment and Packaging Materials on Quality of Dried Persimmons)

  • 박형우;차환수;김상희;박혜란;이선아;김윤호
    • 한국식품저장유통학회지
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    • 제13권2호
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    • pp.168-173
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    • 2006
  • 자몽종자추출물처리와 포장재에 따라 반건시 곶감의 품질 변화를 알아보고자 하였다. 자몽종자추출물에 반건시 곶감을 침지한 후 대조구(무포장), LDPE(low density polyethylene) 필름 포장구와 적층 필름 포장구 (Nylon/LDPE)로 각각 포장하여 $15^{\circ}C$에서 $60{\sim}100$일간 저장한 결과 다른 포장구보다 적층 필름 포장구(Nylon/LDPE)가 중량변화에서는 86%, 곰팡이 발생율은 60%, 갈변도는 50% 이상 낮게 나타났다. 자몽종자추출물(GFSE) 처리와 대조구의 분석실험에서 유의적 차이는 보이지 않았으나 자몽종자추출물 처리시에 반건시 곶감의 표면색도에서는 색변화 억제에 효과를 보였다.