• 제목/요약/키워드: Low cell gap

검색결과 136건 처리시간 0.03초

유기태양전지를 위한 작은 밴드갭 고분자의 합성과 광전특성 (Synthesis and Photovoltaic Properties of a Low Band Gap Polymer for Organic Solar Cell)

  • 우용호;이효상;박성남;최이준;김봉수
    • 폴리머
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    • 제39권1호
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    • pp.71-77
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    • 2015
  • 본 연구에서는 전자가 풍부한 구조단위(dithienosilole 및 benzodithiophene)와 전자가 부족한 구조단위(difluorobenzothiadiazole)를 주사슬에 교대로 갖는 작은 밴드갭 공중합체를 Stille 짝지움 반응을 이용하여 합성하였다. $^1H$ NMR을 통하여 각 단계별 화합물과 고분자의 구조를 확인하였다. GPC, TGA, UV-vis 분광분석기 및 cyclic voltammetry를 이용하여 합성한 고분자의 특성을 조사하였다. 합성한 공액고분자와 $PC_{70}BM$을 1:1.5, 1:2, 1:3, 1:3.5 및 1:4의 중량비로 혼합하여 ITO/PEDOT:PSS/polymer:$PC_{70}BM/Al$의 구조로 유기태양전지 소자를 제작하여 그 광전특성을 조사하였다. 고분자:$PC_{70}BM$의 혼합비율이 1:3에서 최고 1.0%의 광전변환효율이 달성되었다. TEM 실험을 통하여 1:3 혼합비율에서 유기태양전지에 가장 적합한 나노규모로 상분리가 일어났으며, 다른 혼합비율에서는 고분자와 $PC_{70}BM$의 뭉침현상에 기인하여 태양전지 특성이 낮아졌다.

Phenylene-Thiophene-Thieno[3,4-b]pyrazine 올리고머의 합성과 특성 (Synthesis and Characterization of Phenylene-Thiophene-Thieno[3,4-b]pyrazine Oligomer)

  • 황미림;이길성;서은옥;이수형;이연식
    • Korean Chemical Engineering Research
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    • 제49권1호
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    • pp.95-100
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    • 2011
  • 본 연구에서는 유기 태양전지용 작은 밴드 갭 물질(p-형 반도체)의 개발 과정에서, 2,5-dioctyloxyphenylene(OP), 3-hexylthiophene(HT) 및 2,3-dimethylthieno[3,4-b]pyrazine(TP)을 반복단위로 갖는 올리고머(oligo(OP-HT-TP))를 합성하였다. Oligo(OP-HT-TP)는 측정 온도 범위에서 무정형 상태로 존재하였으며, 범용 유기용매에 잘 용해되었다. 필름상태에서 최대 흡수 파장은 716 nm이었으며, 밴드 갭은 대략 1.20 eV로 측정되었다. Oligo(OP-HT-TP)의 HOMO와 LUMO의 에너지 준위는 각각 -5.27 eV와 -4.04 eV로 측정되었다. 그러나, 이 올리고머의 최대 흡수 파장에서 흡광도는 유기태양전지의 제작에 있어서 현재까지 가장 많이 사용되고 있는 poly(3-hexylthiophene) 흡광도의 1/5보다도 더 작은 것으로 측정되었다.

Individual Charge Equalization Converter with Parallel Primary Winding of Transformer for Series Connected Lithium-Ion Battery Strings in an HEV

  • Kim, Chol-Ho;Park, Hong-Sun;Kim, Chong-Eun;Moon, Gun-Woo;Lee, Joong-Hui
    • Journal of Power Electronics
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    • 제9권3호
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    • pp.472-480
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    • 2009
  • In this paper, a charge equalization converter with parallel-connected primary windings of transformers is proposed. The proposed work effectively balances the voltage among Lithium-Ion battery cells despite each battery cell has low voltage gap compared with its state of charge (SOC). The principle of the proposed work is that the equalizing energy from all battery strings moves to the lowest voltage battery through the isolated dc/dc converter controlled by the corresponding solid state relay switch. For this research a prototype of four Lithium-Ion battery cells is optimally designed and implemented, and experimental results show that the proposed method has excellent cell balancing performance.

트랜스포머 1차측 병렬 구조를 가진 직렬 연결 리튬이온 배터리 전하 균일 컨버터 (Charge Equalization Converter with Parallel Primary Winding for Series Connected Lithium-Ion Battery strings)

  • 김철호;박홍선;김정은;문건우;이중휘
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2007년도 하계학술대회 논문집
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    • pp.256-258
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    • 2007
  • A charge equalization converter with parallel-connected primary windings of transformers is proposed in digest. The proposed work effectively balance the voltage among Lithium-Ion battery cells despite each battery cell has low voltage gap compared with its SOC. The principle of the proposed work is that the equalizing energy from all battery strings moves to the lowest voltage battery through the isolated dc/dc converter controlled by the corresponding bi-directional switch. In this digest, a prototype of four Lithium-Ion battery cells is optimally designed and implemented, and experimental results show that the proposed method has excellent cell balancing performance.

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Fringe-Field 구동형 반사형 Hybrid Aligned Nematic 액정 디스플레이의 전기-광학 특성 (Electro-Optic Characteristics of the Fringe-Field driven Reflective Hybrid Aligned Nematic Liquid Crystal Display)

  • 정태봉;박지혁;손정석;이종문;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.972-975
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    • 2003
  • We have performed computer simulation to obtain electro-optic characteristics of reflective hybrid aligned nematic liquid crystal displays driven by fringe field. The results show that the optimal retardation value of the cell is $0.289{\mu}m$, which allows for the cell to have a practical cell gap of larger than $3{\mu}m$ when manufacturing. A reflectance of the dark state is only 0.114% for an incident light 550nm. At this condition, the light efficiency of white state reaches 92.7%. Further, we have studied a new reflective display with polarizer, optical compensation with half plate, LC plus reflector. The display with optimized cell parameters shows low wavelength dispersion and the contrast ratio greater than 5 over exists about $120^{\circ}$ in vertical direction and $160^{\circ}$ in horizontal direction.

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Flexible Display ; Low Temperature Processes for Plastic LCDs

  • Han, Jeong-In
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.185-189
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    • 2002
  • Flexible displays such as plastic based LCDs and organic light-emitting diodes for mobile communication devices have been researched and developed at KETI in KOREA since 1997. The Plastic film substrate has so poor thermal tolerance and non-rigidness that the fabrication of active devices and panel assembly have to perform at low temperature and pressure. In addition, high thermal expansion of the substrate is also a serious problem for reliable metallic film deposition. In this paper, we investigated particularly on the fundamental characteristics of various plastic substrates and then, suggested novel methods that improve the fabrication processes of plastic LCD panel. In order to maintain stable substrate surface and uniform cell gap during panel assembly, we utilized newly-invented iii and vacuum chuck. Electro-optical characteristics of fabricated plastic LCD are better than or equivalent to those of typical glass based LCDs though it is thinner, lighter-weight and more robust.

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Influence of the Recombination Parameters at the Si/SiO2 Interface on the Ideality of the Dark Current of High Efficiency Silicon Solar Cells

  • Kamal, Husain;Ghannam, Moustafa
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제15권2호
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    • pp.232-242
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    • 2015
  • Analytical study of surface recombination at the $Si/SiO_2$ interface is carried out in order to set the optimum surface conditions that result in minimum dark base current and maximum open circuit voltage in silicon solar cells. Recombination centers are assumed to form a continuum rather than to be at a single energy level in the energy gap. It is shown that the presence of a hump in the dark I-V characteristics of high efficiency PERL cells is due to the dark current transition from a high surface recombination regime at low voltage to a low surface recombination regime at high voltage. Successful fitting of reported dark I-V characteristics of a typical PERL cell is obtained with several possible combinations of surface parameters including equal electron and hole capture cross sections.

ECL용 유리기판의 레이저 저온 실링처리 (The Low Temperature Laser Treatment of Sealing Glass Substrate for ECL)

  • 최혜수;박차수;곽동주;성열문
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2015년도 제46회 하계학술대회
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    • pp.1134-1135
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    • 2015
  • In this paper, we reported fabrication of sealing the glass substrate using laser treatment at low temperature for electrochemical luminescence (ECL) cell. The laser treatment at temperature is using laser diode. The glass substrate sealing by laser treatment tested at 1-5 W, 1-5 mm/s for builted and tested. The sealing laser treatment method will allow associate coordination between the two glass substrate was enclosed. The effect of laser treatment to sealing the glass substrate was found to have cracks and air gap at best thickness of about $845-780{\mu}m$ for condition 5 W, 1-5 mm/s. The surface of sealing was roughness which was not influent to electrodes So, it is more effective viscosity between two glasses substrate.

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고속응답용 STN flexible display 기술 연구 (Study on the technique of fast response STN flexible display)

  • 배유한;김상훈;강형구;이휘원;황정연;서대식
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.291-292
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    • 2005
  • Comparing with conventional STN-LCD, a good electro-optical characteristics were observed on the STN-LCDs of low cell gap using liquid crystals that have large refractive indices. Especially, A stable voltage-transmittance(V-T) curve of the plastic STN-LCD was measured and fast response time characteristics were obtained. We suggested that fast response STN-LCD is promising technique in the flexible display of small size because it has lots of advantages such as low cost, simple manufacture process comparing with other modes.

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A Single Low Twisted Nematic Mode for a Transflective LCD with a Self-Integrated Retardation Layer

  • Kim, Jin-Yool;Na, Jun-Hee;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2005년도 International Meeting on Information Displayvol.I
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    • pp.411-414
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    • 2005
  • We have developed a transflective liquid crystal display (LCD) with a single cell gap and a low twisted nematic (LTN) mode in combination with a self-integrated retardation layer. The retardation layer was made of UV curable liquid crystalline material in one step of photo masking process and has both the homeotropic and the planar parts. The proposed transflective configuration has advantages in a simple fabrication process, and the possibility for a single driving scheme due to the similarity between the transmittance and the reflectance.

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