• 한국산학기술학회논문지
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• 제19권9호
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• pp.474-481
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• 2018

친환경자동차의 보급 확대를 위한 정책수립과 기술개발이 지속적으로 이루어지고 있는 실정이나 아직까지도 내연기관이 차지하는 비중은 약 95% 차지하고 있다. 화석연료를 기반으로 하는 내연기관의 엄격한 배기가스규제를 충족시키기 위해 자동차와 선박용 후처리장치의 비중이 점차로 증가하고 있다. 디젤엔진은 이산화탄소 배출량이 적고 강력한 파워와 연료의 경제성을 가지고 있으며, 상용차뿐만 아니라 승용차에서도 시장의 수요가 증가하고 있다. 디젤 연료 특성으로 인하여 질소산화물은 국부적인 고온연소 영역에서 생성되며, 입자상물질은 확산연소 영역에서 생성된다. 희박한 LNT(질소산화물 흡장촉매)와 urea-SCR(선택적인촉매환원장치)는 디젤엔진에서 질소산화물을 저감시키기 위한 후처리장치로 개발되어져왔다. 이 연구는 가혹해지고 있는 배기가스 규제 대응을 위해 선택적인촉매환원장치의 촉매에 포함됨 조촉매의 영향을 파악하는 것이다. 망간-선택적인촉매환원장치의 질소산화물 저감 성능이 가장 우수하였으며, 망간 이온과 Zeolyst의 Al과의 이온교환이 잘 되었고, 활성화 에너지가 낮아 반응 속도가 빨라짐에 따라 질소산화물 저감 성능이 향상되었다. 7Cu-15Ba/78Zeolyst SCR 촉매의 질소산화물 저감 성능은 200도에서 32%, 500도에서 30%를 나타내며 가장 높은 성능을 나타내었고, 조촉매로 첨가된 산화바륨의 질소산화물의 흡장 물질이 Cu-SCR 촉매에 잘 분산되어 있고 Cu-SCR 촉매의 환원 반응과 더불어 산화바륨의 추가적인 질소산화물 저감 성능이 영향을 끼쳤기 때문이다. 7Cu-15Ba/Zeolyst SCR 촉매는 3종 촉매 중 열적 열화에서 내구성이 강하였다. 열적 열화에 따른 동종 성분 산화구리가 이동하여 응집되는데, 산화바륨이 주촉매 산화구리 입자의 응집을 감소시켰기 때문이다.

• 에너지공학
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• 제13권1호
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• pp.20-27
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• 2004

본 연구에서는 고점도 저질유를 연료로 사용하는 디젤기관에 있어서 연료에 저비점 함산소물질을 혼합하였을 때의 배기배출물 특성변화에 대해 조사하였다. 실험은 6종류의 혼합물을 여러 혼합비로 베이스 연료에 첨가하여 기관 성능과 배기배출물 특성 변화에 대해 실시하였으며, 다음과 같은 결론을 얻었다. 저질유로의 저비점물질 흔합에 의해 매연 CO, PM, SOF 및 열소비율이 대폭적으로 개선되었다. 이러한 경향은 분사시기 지연시에 현저하였으며, 혼합물질의 비점이 낮을 수록 혼합비율이 클수록 또한 비함산소 물질보다는 함산소물질에 있어서 더 현저하였다. 또한, 저질유에 함산소물질 DMM을 20 vo1.% 흔합하고 연료분사시기를 지연시킬 경우에는 통상의 경유 운전을 상회하는 NOx-매연 트레이드 오프 관계가 얻어졌다. 따라서, 고점도의 저질유연료를 사용하는 디젤운전에 있어서도 저비점 함산소물질의 혼합에 의해 효과적이고 청정하게 사용될 수 있을 것으로 기대된다.

• Journal of Advanced Marine Engineering and Technology
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• 제37권6호
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• pp.611-616
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• 2013

선박운항의 경제성, 효율성 및 편리성을 높이면서 친환경적인 선박에 대한 연구가 지속적으로 추진되고 있는데, 그 중 한 예로 전자제어식 디젤엔진의 개발을 들 수 있다. 그러나 전자제어식 엔진으로 추진되는 선박은 안전성과 신뢰성이 우려되고 있어 이들을 선박에 널리 보급하는데 어려움을 겪고 있다. 본 연구에서는 이러한 문제를 해결하기 위하여 전자제어식과 캠구동식 연료분사시스템을 탑재하고 있는 선박의 주기관을 이용하여 시스템별 배기성능을 비교 분석하였다. 그 결과 전자제어식의 경제적 운항 모드에서는 캠구동식과 비슷한 배기특성을 나타내었지만, 유해가스 저배출 모드의 100% 부하상태에서는 NOx를 100ppm 이상, HC의 경우 50% 부하상태에서는 10~20ppm을, 25% 부하상태에서는 35~40ppm을 캠구동식에 비해 저감시킨다. 연료소비율에 있어서는 25% 부하상태에서 압축압력을 캠 구동식에 비해 200bar 이상 증가시킨 700bar로 유지할 때 7g/kWh 정도 저감되었다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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• pp.817-820
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• 2009

Research on usage of syngas produced by waste gasification is on going all around the world. Syngas which consists of $H_2$, CO, $CO_2$, $N_2$, has different combustion characteristics from current city gas; due to distinct flame propagation speed of the fuel, syngas has different spark timing and air fuel ratio at maximum generating efficiency. This is why finding both the optimum point of spark timing and air fuel ratio is so important in order to improve thermo efficiency and secure stable running of gas generated by relatively low heating value syngas. Moreover, since emission of $NO_x$ is strictly regulated, it is important to operate lean burn condition that reduces NOx emission.

• 대한기계학회논문집
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• 제19권3호
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• pp.858-867
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• 1995

Characteristics of premixed flames in counter-flow system are numerically studied using a detailed chemical reaction mechanism including gas phase radiation. Without radiation effect accounted, low CO and high NO$_{x}$ emission indices are observed, when strain rate decreases, due to increased residence time and higher flame temperature. Higher NO$_{2}$ production has been also observed when two premixed flames are interacting or cold air stream is mixed with burned gas. The rate of NO$_{x}$ production and destruction is dependent upon the diffusional strength of H and OH radicals, the existence of NO and the concentration of HO$_{2}$. For radiating flames, the peak temperature and NO$_{x}$ production rate decreases as the strain rate decreases. At high strain rate, it is found that the effect of radiation on flame is little due to its negligible radiating volume. It is also found that NO$_{x}$ production from the interacting premixed flame is reduced due to reduced temperature resulting from radiation heat loss. It is concluded that the radiation from gas has significant effect of flame structure and on emission characteristics.ristics.

• 동력기계공학회지
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• 제12권5호
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• pp.34-39
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• 2008

The combustion purpose of diesel engine is to reduce the emission of green gas and to produce high output. Generally, the regulation matter of emission gas is largely diveded by 'THC', 'NOx', 'CO' and 'PM'. Among those matters, the most problem is to disgorge into 'PM', the character of diesel combustion. Diesel PM can be controlled using Diesel Particulate Filter, which can effectively reduce the level of soot emissions to ambient background levels. $NO_2$ generated by the DOC is used to combust the carbon collected in the DPF at low temperature. To certificate DPF device that is suitable to domestic circumstances, it is necessary to exactly evaluate the DPF devices according to the regulation of DPF certificate test procedure fur retrofit. To do carry out the above-mentioned description the understanding of that regulation like the standard of PM reduction is needed. In this study the test procedure including test cycle and BPT test condition was examined, and also the test result for specific DPF was analyzed. In every test like field test, PM reduction efficiency test and Seoul-10 mode test, no defect was showed.

• 한국수소및신에너지학회논문집
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• 제28권6호
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• pp.691-696
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• 2017

An experimental study on engine performance and emission characteristics for bio-alcohol fuels considered as RFS fuel. The Bio-alcohol fuel were mixed ethanol and butanol and used in a 1.8 liter mpi engine. The efficiency of the BSFC is excellent in the maximum torque operation condition and the part load operation condition. As the bio-alcohol mixing ratio increased, the lambda <1 and ignition timing advanced $5^{\circ}CA$. As the mixing concentration increased, NOx emission increase and $CO_2$ emission decreased.

• 한국자동차공학회논문집
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• 제13권4호
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• pp.145-151
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• 2005

Natural gas is one of clean fuels that can replace petroleum-based fuels, because it has low exhaust emission, comparatively high thermal efficiency and abundant deposits. In this addition, owing to high octane number and wide lean flammability limit, it has a strong point to increase the compression ratio. For this reason, the research is being actively executed to increase the generating power and thermal efficiency of the engine by raising the compression ratio through utilization of high octane number relevant to development of CNG engine. In this study, 0.63L single cylinder diesel engine has been used to alter easily compression ratio. Compression ratio has gotten under control by modifying the thickness of gasket between cylinder head and block without major structural modifications. As the result, as compression ratio has increased, generating power and fuel consumption ratio have been improved. As for emission concentration, as compression ratio has increased, THC concentration has been decreased while exhause concentration of NOx increased. In case compression ratio has excessively increased, brake output decrease and cycle variation have been increased. As the result acquired by analyzing brake output, fuel consumption ratio, cycle variation and exhaust, the engine driving condition has acquired $\varepsilon=13$ as the optimal compression ratio in this study.

• 신재생에너지
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• 제6권2호
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• pp.27-32
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• 2010

Low Calorific Gas Turbine (LCGT) has been developed as a next generation power system using landfill gas (LFG) and biogas made from various organic wastes, food Waste, waste water and Livestock biogas. Low calorific fuel purification by pretreatment system and carbon dioxide fixation by green house system are very important design target for the optimum applications of LCGT. Main troubles of Low Calorific Gas Turbine system was derived from the impurities such as hydro sulfide, siloxane, water contained in biogas. Even if the quality of the bio fuel is not better than natural gas, LCGT may take low quality gas fuel and environmental friendly power system. The mechanical characterisitics of LCGT system is a high energy efficiency (>70%), wide range of output power (30 kW - 30 MW class) and very clean emission from power system (low NOx). A green house has been designed for four different carbon dioxide concentration from ambient air to 2000 ppm by utilizing the exhaust gas and hot water from LCGT system. LCGT is expected to contribute achieving the target of Renewable Portfolio Standards (RPS).

• 한국자동차공학회논문집
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• 제22권3호
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• pp.81-89
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• 2014

This study researched on the effect of HP/LP-EGR system to improve fuel consumption of Low Temperature Combustion Engine. Firstly, low temperature combustion engine with HP/LP-EGR system was established using 6.0L wastegate turbocharger HDDI engine. And suppliable EGR rate of the engine was proven to be enough to realize stable low temperature combustion. Then, optimum operating strategy was founded to develop fuel consumption of the engine. Control parameters were HP/LP-EGR valve and IPCV(Intake Pressure Control Valve) duty. Experiments method was that characteristics of the engine were measured and analyzed according to HP/LP-EGR strategies while EGR rate was fixed. Operating range for the strategy were divided into three parts, low load for low temperature combustion, high load for conventional diesel combustion, and transient condition. Finally, with the above strategy of this study, BSFC of the engine was improved about 2% compared to the base engine, and emission level, NOx and PM, met Tier4Final emission regulation.