• Journal of the Korean Institute of Gas
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• v.25 no.2
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• pp.1-12
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• 2021

MILD(Moderate or Intense Low-oxygen Dilution) combustion has attracted attention as the clean thermal energy technology due to the lower emissions of unburnt carbon and NO_x. MILD combustion aims to enlarge the combustion reaction zone using the spontaneous ignition phenomenon of the reactants. In this study, the ignition delay time of CH₄ according to the initial temperature of reactants and the addition of CO, H₂ was investigated using a numerical approach. Ignition delay time became shorter as the increases of initial temperature and H₂ addition. But, CO addition to the fuel increase the ignition delay time. In case of H₂ addition to the fuel, the ignition delay time decreased because the higher fraction of HO₂ promotes the decomposition of methyl radical(CH₃) and produce OH radical. However, in case of CO addition to the fuel, ignition delay time inceased because a high proportion of HCO consumes H radical. There was no significant effect of HCO on the reduction of ignition delay time. Also, the increase rates of NO emissions by the addition of CO and H₂ were approximately 7% and 1%, respectively. A high proportion of NCO affects the increase in NO production rate.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.3
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• pp.170-177
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• 2006

Hydrogen can extend the lean misfire limit to a large extent when it is mixed with conventional fuels for a spark ignition engine. In this study, hydrogen-enriched gaseous fuels by reforming process were simulated according to their proportions of $H_2$, CO, $CO_2$ and $N_2$ gases. Pure hydrogen and two different hydrogen-enriched gaseous mixtures(A-, B-composition) were tested for their basic effects on the engine performances and emissions in a single cylinder research engine. A- and B-composition showed different results from 100% $H_2$ addition because air/fuel mixtures were more diluted by their additions. Even though the energy fraction of reformed gases was increased, combustion stabilities and lean misfire limits were not sensitively improved. It means that combustion augmentation by $H_2$ addition was offset by the charge dilution of $N_2$ and $CO_2$. In addition, the low flammability of CO gas deteriorated thermal efficiencies. CO emission was drastically increased with B-composition which included higher CO component. However, $NO_x$ was reduced as energy fraction($X_e$) rised except for the case of 100% $H_2$ addition at $\lambda=1.2$ and was, for A-composition, lowered to a factor of ten when compared with that of $H_2$ addition. HC emissions were largely influenced by $COV_{imep}$ due to misfire and partial burns.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.3
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• pp.75-80
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• 2006

Since air pollution has become a globally critical issue and exhaust emissions from automobiles cause a major source of air pollution, many countries including advanced countries have stipulated stringent emission regulations. Particularly in diesel vehicles, NOx and particulate matters exhaust in significant amounts even though diesel vehicles provide merits in aspects of higher thermal efficiency and lower $CO_2$. To reduce Particulate matters and NOx, after-treatment technology such as filter trap, oxidation catalysts and EGR has been applied. This test was conducted on the effect of continuous regeneration diesel particulate filter and cooled-EGR, and 15ppm low sulfur diesel was used as a test fuel. Exhaust emissions, PM, NOx, CO, HC and Soots were measured and compared under D-13 and D-3 modes.

• Journal of Korean Society for Atmospheric Environment
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• v.32 no.3
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• pp.280-288
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• 2016

Greenhouse gas (GHG) emissions have given rise to climate change which is one of the most serious environmental challenges that the world faces today. In response, Republic of Korea has proposed "Low Carbon, Green Growth" as a new economic paradigm accompanying with the ultimate aim of building a sense of responsibility for the environment. Korean government has set the ambitious national GHG emission reduction target which aims 37% reduction in the business-as-usual (BAU) level of 2030. The transportation sector plays a key role in this target. In the transportation sector, the GHG reduction target of 34.3% in the BAU level by 2020 has been allocated in order to consider the industrial specificity. Furthermore, it is known that the GHG reduction in the transportation sector has relatively minimal side effects compared to those of other sectors. In order to meet this national GHG reduction target, Korean government has set $CO_2$ emission regulation of vehicle for 2020. The purpose of this study is to evaluate the reduction effects by the average GHG regulation of vehicles. $CO_2$ emissions, between 2009 and 2013 were analysed by reduction measure such as technology improvement, light-weight, segment shift, diesel vehicle sales. During this period, $CO_2$ of vehicle was reduced every year by 19.9 g/km (i.e., 3.3% reduction per year). $CO_2$ reduction of imported vehicle is greater than domestic vehicle because of segment shift toward small size vehicle and higher diesel vehicle sales.

• Journal of Environmental Science International
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• v.15 no.8
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• pp.719-725
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• 2006

Since low-floor apartments ate vertically closer to patting lots and roadways, it is hypothesized that residents in low-floor apartments may be exposed to elevated ambient levels of motet vehicle emissions compared to residents in high-floor apartments. The present study examined this hypothesis by measuring two motor vehicle source-related pollutants(CO and PM10) in ambient air of high-rise apartment buildings within the boundary of industrial complexes according to atmospheric stability The ambient air concentrations of CO and PM10 were higher for low-floor apartments than for high-floor apartments, regardless of atmospheric stability, The median concentration ratio of the low-floor air to high-floor alt ranged from 1.3 to 2.0, depending upon atmospheric stabilities, seasons and compounds. Moreover, the CO and PM10 concentrations were significantly higher in the winter and in the summer, regardless of the Hoot height. Atmospheric stability also was suggested to be important for the residents' exposure of high-rise apartment buildings to both CO and PM10. The median ratios of surface inversion air to non-surface inversion air ranged from 1.2 to 1.7 and from 1.0 to 1.6 lot PM10 and CO, respectively, depending upon seasons. Conclusively, these parameters(apartment floor height, season, and atmospheric stability) should be considered when evaluating the exposure of residents, living in high-rise apartment buildings, to CO and PM10. Meanwhile, the median PMl0 outdoor concentrations were close to or higher than the Korean annual standards for PM10, and the maximum PM10 concentrations substantially exceeded the Korean PM10 standard, thus suggesting the need for a management strategy for ambient PM 10. Neither the median nor the maximum outdoor CO concentrations, however, were higher than the Korean CO standard.

• Journal of Environmental Science International
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• v.25 no.10
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• pp.1381-1387
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• 2016

This study aims to establish baseline data for sustainable monitoring by applying the green city index (GCI), which is set up to evaluate the city level, to the city of Gangneung-si, which was designated as a pilot city for the Low-carbon Green Growth City project by the Ministry of Land, Infrastructure, and Transportation. The GCI was applied in the framework of European systems, while considering the social and economic status of Korea. Indicators from 7 areas-$CO_2$, energy, building, transportation, water, waste, and quality of atmosphere were analyzed, except for qualitative indicators. Results indicate that total $CO_2$ emissions were 30.8 tons per capita, or 2.2 tons per one million units of real GDP. The total final energy consumption was 0.231 TOE/capita, or 0.317 TOE per one million units of real GDP. The percentage of total energy derived from renewable resources was 0.41% and energy consumption by the building was $433.5Mwh/1,000m^2$. The total percentage of the working population travelling to work daily by public transportation (limited to bus) was 19%. Further, the total annual water consumption was $99m^3/capita$, and the water lost in the water distribution system was $0.057m^3/capita/day$. The total annual waste collected was 0.0077 ton per capita, The annual mean emission were 0.014 ppm/day for $NO_2$, 0.005 ppm/day for $SO_2$, and 0.019 ppm/day for $O_3$. The annual mean for PM10 emissions was $39{\mu}g/m^3/day$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.37 no.12
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• pp.1129-1135
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• 2013

In this, three types of natural gas were employed to investigate the effect of low-calorific natural gas on the performance of and emissions from a heavy-duty CNG engine. The performance and emission characteristics were analyzed by conducting a full-load test, WHSC mode test, and WHTC mode test. The results showed that the torque of low-calorific natural gas with $9,800kcal/Nm^3$ of higher heating value decreased by 4.4 compared to that of the current natural gas with $10,400kcal/Nm^3$ of heating value. With low-calorific fuels, CO, $CO_2$, and $NO_x$ emissions decreased. However, THC emissions increased. According to the WHSC and WHTC mode test results, the thermal efficiency increased and the emission characteristics showed a similar trend to the full-load test results. Low-calorific natural gases cause a decrease in torque at full-load operation conditions and an increase in hydrocarbon emissions.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.153-156
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• 2008

MILD combustion has been successfully applied to gaseous fuels and few commercial systems are now in operation. Extending MILD combustion applicability to solid fuel of sawdust is the focus of the present work. The MILD combustion furnace at the University of Adelaide in Australia was used in this study. A measurement of $O_2$ and CO emissions have been carried out in parallel with consideration of NOx emission and compared in each modes of conventional natural gas combustion, natural gas MILD combustion, NOx emission in natural gas MILD combustion mode can be reduced to 20% in comparison with conventional combustion. Emission in cases of air carrying sawdust combustion and $CO_2$ carrying sawdust combustion were also compared. Air and $CO_2$ were sued as a carry gas for the sawdust. It was found that MILD conditions are possible for sawdust particles of less than $355{\mu}m$ without additional air pre-heating. It was also found that when using $CO_2$ as the carry gas the flame inside the furnace was not visible anymore and that NOx emission dropped to less than two folds.

• 한국연소학회:학술대회논문집
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• 2013.06a
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• pp.19-20
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• 2013

The cofiring of renewable fuel in coal fired boilers is an attractive option to mitigate $CO_2$ emissions, since it is relatively low cost option for efficiently converting renewable fuel to electricity by adding biomass as partial substitute of coal. However, it would lead to reduce plant efficiency and flexibility in operation, and increase operation cost and capital cost associated with renewable fuels handling and firing equipment. The aim of this study is to investigate reduction of carbon dioxide at varying percentage of biomass in fuel blend to the boiler biomass, and estimate operation and capital cost. Wood pellet, PKS (palm kernel shell), EFB (empty fruit bunch) and sludge are considered as a renewable fuels for a cofiring with coal. Several approaches by the cofiring ratio are chosen from past plant demonstrations and commercial cofiring operation, and they are evaluated and discussed for CO2 reduction and cost estimation.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.1
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• pp.21-27
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• 2016

Global warming due to greenhouse gas emissions is considered as a major problem worldwide, and many countries are making great efforts to reduce carbon dioxide emissions. Many technologies in post-combustion, pre-combustion and oxy-fuel combustion $CO_2$ capture have been developed. Among them, a hybrid pre-combustion $CO_2$ capture system of a water gas shift (WGS) reactor and a membrane gas separation unit was investigated. The 2 stage WGS reactor integrated high temperature shift (HTS) with a low temperature shift (LTS) was used to obtain a higher CO conversion rate. A Pd/Cu dense metal membrane was used to separate $H_2$ from $CO_2$ selectively. The performance of the hybrid system in terms of CO conversion and $H_2$ separation was evaluated using a 65% CO, 30 % $H_2$ and 5% $CO_2$ gas mixture for applications to pre-combustion $CO_2$ capture. The experiments were carried out over the range of WGS temperatures ($200-400^{\circ}C$), WGS pressures (0-20bar), Steam/Carbon (S/C) ratios (2.5-5) in a feed gas flow rate of 1 L/min. A very high CO conversion rate of 99.5% was achieved with the HTS-LTS 2 stage water gas shift reactor, and 83% $CO_2$ was concentrated in the retentate using the Pd/Cu membrane.