• Title/Summary/Keyword: Loss on ignition

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Estimation of Contamination Level of Sediments at the Below of Busan Gwang-an Bridge (부산 광안대교 하부 퇴적토 오염도 평가)

  • Kim, Seog-Ku;Ahn, Jae-Whan;Kang, Sung-Won;Yun, Sang-Leen;Lee, Jungwoo;Lee, Jea-Keun;Lim, Jun-Heok;Kim, Dong-Soo;Lee, Tae-Yoon
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.11
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    • pp.809-814
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    • 2013
  • In this study, physical properties and heavy metal contents of sediments obtained from the bottom of Gwangan bridge were measured to determine pollution level of the sediments. From the results of the oxide contents of the sediments, $SiO_2$ was decreased as the sampling points became more distant from the stream of river. On the contrary, CaO showed opposition aspect to $SiO_2$. Ignition loss of sediments ranged from 7.2 and 14.3% and 0.9 and 5.5% for TOC. For EPA guidelines of ignition loss, all sampling points were classified as heavily polluted areas. When TOC was considered, all areas were classified as lowest effect level except for GW7 where classified as no effect level. All areas were free of heavy metal contamination evaluated by USEPA and Canadian guidelines. However, all areas were classified as heavily contaminated areas due to the high value of ignition loss when USEPA was used.

Theoretical Analysis on Bifurcation Behavior of Catalytic Surface Reaction on Nonadiabatic Stagnation Plane (비단열 정체면에서 촉매 표면반응의 천이 거동에 대한 이론적 해석)

  • Lee, Su- Ryong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.6
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    • pp.697-704
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    • 2004
  • Bifurcation behavior of ignition and extinction of catalytic reaction is theoretically investigated in a stagnation-point flow. Considering that reaction takes place only on the catalytic surface, where conductive heat losses are allowed to occur, activation energy asymptotics with a overall one-step Arrhenius-type catalytic reaction is employed. For the cases with and without the limiting reactant consumption, the analysis provides explicit expressions, which indicate the possibility of multiple steady-state solution branches. The difference between the solutions with and without reactant consumption is in the existence of an upper solution branch, and the neglect of reactant consumption is inappropriate for determining extinction conditions. For larger values of reactant consumption, the solution response is all monotone, suggesting that multiple solutions are not possible. It is shown that bifurcation Damkohler numbers increase (decrease) with increasing of conductive heat loss (gain) on the catalytic surface, which means that smaller (larger) values of the strain rate allow the surface reaction to tolerate larger heat losses (gains). Lewis number of the limiting reactant can also significantly affect bifurcation behavior in a similar way to the effect of heat loss.

Overview on The Measurement Methods of Unburned Carbon Contents in Coal Fly-Ash (석탄 비산회(Fly-Ash)의 미연탄소 함량 측정방법에 대한 고찰)

  • Hong, EunPyo;Kim, Jung Hyeun
    • Particle and aerosol research
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    • v.10 no.4
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    • pp.131-136
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    • 2014
  • The importance of waste treatments is increasing because of the lack of resources and environmental problems resulted from economic growth policy. Especially, the pollutant dust which is one of the wastes should be treated considerately because it could cause secondary damages on the human health as well as environmental systems. Recently, massive amount of coal fly-ash is being produced in thermoelectric power plants. In this study, we compared two general methods used in estimating the amount of unburned carbon in fly-ashes to categorize the coal fly-ashes into several groups following their carbon contents. One is the "loss on ignition(KS L 5405) method" which estimates the change of mass after combustion, and it is generally used. Another one is measuring $CO_2$ gas content by burning solid carbon in the fly-ash, and it is called "$CO_2$ analysis method."

Characteristics of the Sedimentary Environment in Yoja Bay in the Summer of 1998 (1998년 하계 여자만의 저질환경 특성)

  • 허회권;김도현;안승환;박경원
    • Korean Journal of Environmental Biology
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    • v.18 no.2
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    • pp.227-235
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    • 2000
  • As a part of basic investigation to Fishery Purge Project for the Special Administrative in Chollanamdo Province, the sedimentary environmental characteristics of Yoja Bay at 15 stations were studied. The analysis was carried out in July, 1998, through studies of Loss On Ignition (LOI) by depth, Total Sulfide (T-5), Chemical Oxygen Demand (COD) concentrations and Grain-size distribution. The LOI value was found to be 6.20-12.20% (mean of 8.89%), with the neighboring Sunhakri and Haksanri areas showing slightly higher values. These values were similar to the LOI values observed in the Hansan-Koje Bay and Jinju Bay areas on the southern coast of Korea. T-S and COD concentrations were found to be, respectively, 0.060-0.104 mg/gㆍd (mean of 0.052 mg/gㆍd) and 5.53-29.71 mg/gㆍd(mean of 13.24 mg/gㆍd), not exceeding eutrophication limits. T-S concentration was especially high at stations close to the central areas of the bay and inland areas, which caused by organic matter input from the nearby agricultural areas. COD concentration was very high at stations nearby the bay entrance and Doonbyungdo, but the mean value was lower than that of Hansan-Koje Bay. This leads us to believe that the level of pollution in Yoja Bay is not significant. The prevailing sediment composition was mud, consisting of 61.38% silt and 34.87% clay. [Sediments in Yoja Bay, Loss On Ignition, Total Sulfide, Chemical Oxygen Demand, Grain-Size Distribution].

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A Study on the Function of Organic Admixture in Fly Ash Substituting Fresh Concrete (플라이애쉬를 혼합(混合)한 굳지않은 콘크리트에 있어서 유기혼화제(有機混和劑)의 기능(機能)에 관한 연구(研究))

  • Moon, Han Young;Sea, Joung Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.117-124
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    • 1988
  • From the test results of the adsorption characteristics of AE admixture, it was shown that the adsorption of AE admixture on fly ash was mearly completed in 30 minutes and the higher was ignition loss, the larger the quantity of saturation adsorption. Because most of the ignition loss of the fly ash was due to the unburned carbon, it could be said that the unburned carbon is the main reason of reduction of air content in AE concrete. On the other hand, in the case of superplasticizer, the amount of saturation adsorption in fly ash was lower than in cement and the same result was obtained in the dispersive effect. But, when using superplasticizer in fly ash substituting concrete, the fludity in the concrete was not decreased.

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A Study on the Combustion Characteristics of Phenol Foam (페놀 폼의 연소특성에 관한 연구)

  • Park, Hyung-Ju
    • Fire Science and Engineering
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    • v.24 no.1
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    • pp.122-127
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    • 2010
  • The combustion characteristics of phenol foam were analysed using variable external irradiation level (20, 25, 35, 50, and $70kW/m^2$) and in the mixture gas of oxygen/nitrogen. The oxygen index were carried out from the oxygen index tester (KS M ISO 4589-2) and ignition time, critical heat flux, and mass loss rate were carried out from the mass loss calorimeter (ISO 5660-1). As the results of this study, the critical heat flux and average mass loss rate were $28.99kW/m^2$ and $0.56{\sim}1.77g/m^2s$ respectively at the variable external irradiation level. And the limited oxygen index were 45.1% in mixture gas of oxygen/nitrogen. In conclusion, we knew that phenol foam had the best performance than other foam materials in fire safety from all data of this study.

Numerical analysis on in-core ignition and subsequent flame propagation to containment in OPR1000 under loss of coolant accident

  • Song, Chang Hyun;Bae, Joon Young;Kim, Sung Joong
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.2960-2973
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    • 2022
  • Since Fukushima nuclear power plant (NPP) accident in 2011, the importance of research on various severe accident phenomena has been emphasized. Particularly, detailed analysis of combustion risk is necessary following the containment damage caused by combustion in the Fukushima accident. Many studies have been conducted to evaluate the risk of local hydrogen concentration increases and flame propagation using computational code. In particular, the potential for combustion by local hydrogen concentration in specific areas within the containment has been emphasized. In this study, the process of flame propagation generated inside a reactor core to containment during a loss of coolant accident (LOCA) was analyzed using MELCOR 2.1 code. Later in the LOCA scenario, it was expected that hydrogen combustion occurred inside the reactor core owing to oxygen inflow through the cold leg break area. The main driving force of the oxygen intrusion is the elevated containment pressure due to the molten corium-concrete interaction. The thermal and mechanical loads caused by the flame threaten the integrity of the containment. Additionally, the containment spray system effectiveness in this situation was evaluated because changes in pressure gradient and concentrations of flammable gases greatly affect the overall behavior of ignition and subsequent containment integrity.

ANALYSIS OF HEAT LOSS IN A CONSTANT VOLUME MICRO COMBUSTOR (초소형 정적 연소실의 열손실 분석)

  • Na, Han-Bee;Lee, Dae-Hoon;Kwon, Se-Jin
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.231-235
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    • 2002
  • A theoretical and experimental study on the combustion process in a constant volume micro combustor is described. Unlike in a macro scale constant volume combustor, the heat loss to the wall plays a major role in flame propagation in a micro micro combustor. In order to analyze the effect of heat loss on combustion phenomena, pressure transition from ignition was measured. A number of cylindrical micro combustors with different diameter and depth were used for experiment to study the effect of length scales and shape factor. The diameter of combustor ranged from 7.5mm to 22.5 mm and the height of cylinder was from 1mm to 4mm. Initial pressure was also varied for the experiment. The diagnostic methods were severely limited due to the size of the apparatus and uncertainties of certain quantities to be measured in a small-scale environment. An analytical method to derive physical quantities that are essential for performance prediction from the pressure measurements is described.

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Influence of Piston Bowl Geometry on Combustion of a Diesel/CNG Reactivity Controlled Compression Ignition Engine (디젤/천연가스 반응성제어 압축착화 엔진에서 피스톤 형상에 따른 연소 특성)

  • Kim, Hyunsoo;Kim, Wooyeong;Bae, Choongsik
    • Journal of ILASS-Korea
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    • v.26 no.2
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    • pp.57-66
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    • 2021
  • The reactivity controlled compression ignition (RCCI) is the technology that provides two different types of fuel to the combustion chamber with the advantage of significantly reducing particulate matter and nitrogen oxides emissions. However, due to the characteristics of lean combustion, combustion efficiency is worsened. The conventional type of pistons for conventional diesel combustion (CDC) has mostly been used in the researches on RCCI. Because the pistons for CDC are optimized to enhance flow and target spray, the pistons are unsuitable for RCCI. In this study, a piston that is suitable for RCCI is designed to improve combustion efficiency. The new piston was designed by considering the factors such as squish geometry, bowl depth, and surface area. The experiment was carried out by fixing the energy supply to 0.9kJ/cycle and 1.5kJ/cycle respectively. The two pistons were quantitatively compared in terms of thermal efficiency and combustion efficiency.

Experimental and Theoretical Study on the Effect of Pressure on the Surface Reaction over Platinum Catalyst (백금촉매의 표면반응에 미치는 압력의 영향에 관한 실험 및 이론적 연구)

  • Kim, Hyung-Man
    • Journal of the Korean Society of Combustion
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    • v.5 no.1
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    • pp.1-6
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    • 2000
  • Surface reaction occurs at a certain surface temperature when a catalyst is heated up in a reactive mixture. If homogeneous ignition does not occur, a steady state is observed because the heat produced by the surface reaction is balanced with the heat loss caused by convection, conduction and radiation. The present paper treats the effects of pressure on the surface temperature at the steady state. Hydrogen and oxygen are used as reactants and nitrogen as an inert gas. A spherical platinum catalyst of 1.5 mm in diameter is sustained in the chamber with two wires of 0.1 mm in diameter. As results, there exists a maximum steady temperature at a certain relative hydrogen concentration which increases with total pressure. At the steady state, it can be approximated that the heat release is estimated by the mass transfer considering the effect of natural convection. The experimental results are explained qualitatively by the approximation.

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