• Journal of Korean Society of Environmental Engineers
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• v.36 no.8
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• pp.579-587
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• 2014

Various kinds of micro organic pollutants have frequently been detected from a water system. Therefore, it is considered to be very important part in the drinking water treatment system. And the research about removal process and processing efficiency have been being conducted briskly. In this study, the removal efficiency was evaluated using advanced water treatment process and nanofiltration process. The removal efficiency of nanofiltration process was very different according to physical and chemical characteristics of materials. The molecular weight of cutoff was the most influential factor in the removal efficiency. And when pKa value was higher than pH of raw water or Log Kow value was below 2, the removal efficiency of material was decreased. In case of oxidation reaction, the bigger the molecular weight of material was and the more hydrophobic a material was, the less oxidation reaction occurred. And the removal efficiency was decreased. Most unoxidized materials were removed by absorption. And the more actively oxidation reaction occurred by $H_2O_2$, the more absorption reaction increased.

• Biotechnology and Bioprocess Engineering:BBE
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• v.6 no.1
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• pp.25-30
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• 2001

Viral safety is a prerequisite for manufacturing clinical albumin and immunoglobulins from human plasma pools. This study was designed to evaluate the efficacy of cold ethanol fractionation and pasteurization (60$\^{C}$ heat treatment for 10h) for the removal/inactivation of human immunodeficiency virus type 1 (HIV-1) during the manufacturing of albumin and immunoglobulins. Samples from the relevant stages of the production process were spiked with HIV-1, and the amount of virus in each fraction was quantified by the 50% tissue culture infectious dose(TCID(sub)50). Both fraction IV fractionation and pasteurization steps during albumin processing were robust and effective in inactivating HIV-1, titers of which were reduced from an initial 8.5 log(sub)10 TCID(sub)50 to undetectable levels. The log reduction factors achieved were $\geq$ 4.5 and $\geq$ 6.5, respectively. In addition, fraction III fractionation and pasteurization during immunoglobulins processing were robust and effective in eliminating HIV-1. HIV-1 titers were reduced from an initial 7.3 log(sub)10 TCID(sub)50 to undetectable levels. The log reduction factors achieved in this case were $\geq$ 4.9 and $\geq$ 5.3, respectively. These results indicate that the process investigated for the production of albumin and immunoglobulins have sufficient HIV-1 reducing capacity to achieve a high margin of safety.

• Journal of Korean Society on Water Environment
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• v.23 no.1
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• pp.138-143
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• 2007

This study goes in for the observation of the characteristics of nitrogen removal from swine wastewater by struvite crystallization. In addition, the struvite formation potential in supernatants after struvite crystallization was investigated. In the study for nitrogen removal by struvite crystallization, the effects of pH and molar ratio of magnesium (Mg) injected using bittern as Mg source were investigated. Also, the potential of struvite formation in the supernatant with amount of Mg added was carefully observed. As the results, the optimum pH in the removal of nitrogen was 8.8 and sludge volume was increased as pH was raised from 7 to 12 under the condition that the molar ratio of $Mg^{2+}$ to ${NH_4}^+$-N to ${PO_4}^{3-}$-P was 1:1:1. An optimum removal efficiency of ammonia-N was observed at 1 molar ratio of Mg to ${NH_4}^+$-N, showing no further increase at over 1 molar ratio and dramatical deterioration at under 1 molar ratio. However, the sludge volume was increased by increasing the molar ratio of Mg. In the experiments for the potential of struvite formation in the supernatants, initial -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was much lower than $pK_{sp}$ and gradually reached $pK_{sp}$ at 2 days, as the molar ratio of Mg increased over 1.2. At 31 days, -log([$Mg^{2+}$][${NH_4}^+$][${PO_4}^{3-}$]) value was returned to the initial value. In addition, the supernatants had a potential precipitation of hydroxylapatite due to calcium contained in bittern, $K_2Mg(SO_4)_3$ and $K_3Na(SO_4)_2$ resulting from the decrease of sodium and potassium in supernatants formed after struvite crystallization as times go by. Based on the results, it appears that some retention time and proper dosage of Mg may be needed for the prevention of scale in pipe line.

• Journal of Korean Society on Water Environment
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• v.26 no.5
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• pp.871-879
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• 2010

To figure out the removal efficiency of indicator and pathogenic bacteria by unit processes of a sewage treatment plant using activated sludge process, analyses were done for incoming sewage, influent and effluent of primary clarifier, aeration tank, secondary clarifier and final discharge conduit of the plant. A matrix of bacterial items (average of bacterial reduction [log/ml], p value of paired t-test, number of decreased cases of twenty analyses, removal percentage only for decreased cases) between incoming sewage and final effluent of the plant were heterotrophic plate counts (1.54, 0.000, 20, 95.01), total coliforms (1.38, 0.000, 19, 83.94), fecal coliforms (0.90, 0.000, 20, 94.84), fecal streptococci (0.90, 0.000, 20, 98.08), presumptive Salmonella (0.23, 0.561, 7, 99.09), and presumptive Shigella (1.02, 0.002, 15, 92.98). Total coliforms, fecal coliforms, heterotrophic plate counts, and fecal streptococci showed highest decrease through secondary clarifier about 1-log (p<0.001) between 88% and 96%, and primary clarifier represented the significant (p<0.05) decrease. However, final effluent through discharge conduit showed higher total coliforms and fecal streptococci than effluent of secondary clarifier (p<0.05). In addition, final effluent once violated the water quality standard while effluent of secondary clarifier satisfied the standard. Hence some control measures including elimination of deposits in discharge conduit or disinfection of final effluent are necessary.

• Journal of Korean Society of Water and Wastewater
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• v.18 no.6
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• pp.801-806
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• 2004

The pilot study was conducted to (i) investigate the ability of various membrane integrity monitoring methods to detect changes in membrane integrity during operation, and (ii) determine the impact of membrane damage on microbial removal by microfiltration. Two variations of air pressure hold tests were investigated for direct integrity monitoring: pressure decay (PD) and diffusive air flow (DAF) tests which are most commonly used integrity tests for microfiltration (MF) membranes. Both PD and DAF tests were sensitive enough to detect one damaged fiber out of 66,000 under field operaing conditions. Indirect integrity monitoring such as turbidity and particle counting, however, responded poorly to defects in membrane systems. Microbial challenge study was performed using both new and deliberately damaged membranes, as well as varying the state of fouling of the membrane. This study demonstrated that MF membrane with nominal pore size $0.2{\mu}m$ was capable of removing various pathogens including coliform, spore, and cryptosporidium, at the level required by drinking water regulations, even when high operating pressures were applied. A sharp decrease in average log reduction value (LRV) was observed when one fiber was damaged, emphasizing the importance of membrane integrity in control of microbial contamination.

• Journal of Korean Society on Water Environment
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• v.18 no.3
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• pp.327-336
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• 2002

Disinfection process in water treatment plants (WTPs) is one of the most important step in order to inactivate waterborne disease. However, what is the necessary disinfection in WTPs was not properly established in Korea. This study was conducted to evaluate disinfection performance in nationwide water treatment plants (n=474). Disinfection requirement based on the SWTR (Surface Water Treatment Rule) of the U.S. (1-log Giardia removal) was chosen in estimating the compliance. The scope of unit process for evaluating disinfection performance includes postdisinfection process in clearwells, pipeline, and storage tank. The worst water quality condition in individual WTPs was applied for the disinfection performance evaluation. The major results are as follows. First, it was appeared that 184 WTPs (39 %) provided insufficient disinfection performance. Disinfection performance was significantly improved during past 2 years. The ratio of the number of WTPs providing insufficient disinfection performance in 1999 and 2001 was 78 % and 41 %, respectively. One of major factors for this improvement was due to the improvement of $T_{10}/T$ value in clearwell, as a result of modification of clearwell facility. Second, if disinfection criteria is 3-log Giardia inactivation at worst water quality condition, then 19 % of all WTPs can not meet this disinfection criteria. And if disinfection criteria is strengthened to 4-log Giardia inactivation, then 58 % of all WTPs can not meet this disinfection criteria. Since disinfection criteria is decided by contamination level of Giardia in source water, it also needs the investigation of Giardia occurrence in source water.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.1
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• pp.31-39
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• 2007

The objective of this study was to investigate the inactivation characteristics of Cryptosporidium oocysts by ozone and UV and to suggest the better, disinfection method. The inactivation CT value of 1 log(90%) and 2 log(99%) in of one disinfection, which is an index of disinfection for inactivation effect by ozone, were respectively 5.77 $mg{\cdot}min/L$ and 21.30 $mg{\cdot}min/L$. The inactivation in UV disinfection was not affected by pHs(5, 7 and 9), low turbidity(5 and below NTU) and UV intensity(0.2 and 0.6 $mWs/cm^2$) but obviously decreased at high turbidity over 20 NTU. Therefore UV disinfection capacity can be obtained when a good turbidity removal in drinking water treatment process is achieved. And if oocysts is exposed by high UV over 0.6 mWs/cm2 during enough time, the better inactivation effect will be obtained.

• Journal of Forest and Environmental Science
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• v.30 no.1
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• pp.1-14
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• 2014

Timber harvest in natural forests and its implications on carbon sequestration were investigated in the Southwestern Nigeria. Data on timber harvest from forest estates for a 3-year period were collected from the official record of States' Forestry Department. The data registered the species, volume and number of timbers exploited during the study period. The data were analyzed accordingly for rate of timber harvest and carbon value of the exploited timbers using existing biomass functions. Values were compared for significant differences among states using one way analysis of variance. The results showed that the most exploited logs, in terms of volume and number of trees, have the highest amount of carbon removal. There was a variation in type of timber species being exploited from each state. The total number of harvested trees from Oyo, Ondo, Ogun, Ekiti and Osun were estimated at 100,205; 111,789; 753; 15,884 and 18,153 respectively. Total quantity of carbon removed for the 3-year period stood at 2.3 million metric tons, and this translated to 8.4 million metric tons of $CO_2$. The annual carbon and $CO_2$ removal therefore were estimated at 760,120.73 tons and 2.8 million tons/ year respectively. There were significant differences (p<0.05) in the amount of $CO_2$ removed from the five states. Based on our result, we inferred that there is increasing pressure on economic tree species and it is plausible that they are becoming scarce from the forests in Southwestern Nigeria.. If the present rate of log removal is not controlled, forests could become carbon source rather than carbon sink and the on biological conservation, wood availability and climate change may turn out grave. For the forest to perform its environmental role as carbon sink, urgent conservation measures and logging policies are needed to be put in place.

• Journal of Wetlands Research
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• v.16 no.2
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• pp.269-274
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• 2014

The purpose of this study is to compare CT (disinfectant concentration * time) values in removing the antibiotic resistance bacteria, antibiotic resistance gene and transfer of antibiotic resistance genes. Different concentration of chlorine(C) and contact time(T) according to the removal of antibiotic resistance was calculated for each. As a result, for the 90% removal of antibiotic resistant bacteria, around 176~353 mg min/L CT values are needed. For the removal of the antibiotic resistance gene, 195~372 mg min/L CT values are required. For the 90% reduction of antibiotic resistance gene transfer by chlorine disinfection, 187~489 mg min/L CT values are needed. Based on our results, higher CT value was required for removing antibiotic resistant genes rather than antibiotic resistance bacteria.

• Membrane Journal
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• v.32 no.4
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• pp.253-263
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• 2022

This study suggests a guideline for designing unit process of wastewater reuse in terms of a maintenance of the process based on critical parameters to draw a high quality performance of RO unit. Defining the parameters was done by applying membrane integrity test (MIT) in pretreatment process utilizing lab-scale MF. SDI is utilized for judging whether permeate is suitable to RO unit. However, result said TOC concentration matching with particle count analysis is better for judging the permeate condition. When membrane test pressure (P_test) was measured to derive log removal value in PDT, virgin state of membrane fiber was used to measure dynamic contact angle utilizing surface tension of the membrane fiber. Actually, foulant affects to the state of membrane surface, and it decreases the P_test value along with time elapsed. Consequently, LRV_DIT is also affected by P_test value. Thus, sensitivity of direct integrity test descends with result of P_test value change, so P_test value should be considered not the virgin state of the membrane but its current state. Overall, this study focuses on defining design parameters suitable to MF pretreatment for RO process in wastewater reuse by assessing its impact. Therefore, utilities can acknowledge that the membrane surface condition must be considered when users conduct the direct integrity test so that P_test and other relative parameter used to calculate LRV_DIT are adequately measured.