• 센서학회지
• /
• 제32권2호
• /
• pp.100-104
• /
• 2023

In this study, a device was fabricated to check the possibility of a memory device by controlling the oxygen functional groups in graphene oxide formed with a 45-second exposure time. We discovered that graphene oxide can be formed using the ultraviolet (UV) light treatment method with different exposure times. Moreover, Raman spectroscopy measurement revealed that the oxygen functional groups can be moved by controlling the voltage. We further studied the change in the local graphene oxide region, which was found to be related to the modulation of the electrical properties of the device. Therefore, the fabricated graphene oxide device can be used as a wettability switching membrane and graphene-based ion transport device.

• 대한기계학회논문집B
• /
• 제36권5호
• /
• pp.477-485
• /
• 2012

수평 덕트 내 임계점부근의 유체 유동 및 열전달특성은 중력과 함께 임계영역에서의 열역학 및 전달 물성치의 많은 변화와 직접적으로 연관되어 있다. 본 연구에서는 수평 직사각 덕트 내 임계점부근의 물에 대한 대류열전달특성을 전산해석을 통하여 분석하였다. 이를 통해 국부적인 열전달계수와 유속, 온도, 그리고 물성치분포를 포함한 대류열전달특성에 대해 임계점 근접효과와 함께 비교하였다. 벽으로부터의 열전달에 따른 유체 밀도감소로 덕트 내 유동방향으로의 유속증가와 함께 유체가 액체에서 기체 같은 상태로 천이하는 형태의 유동장특성을 보여준다. 덕트의 윗면, 옆면, 그리고 아래면 각각의 국부적인 열전달계수분포에 큰 차이가 있으며 준임계점 온도부근에서 난류전달특성의 향상으로 열전달계수의 최대치에 이르게 된다. Nu 수는 덕트 내 압력과 종횡비에 영향을 받으며 임계압에 가까워질수록 최대 Nu 수는 급격히 증가하게 된다. 이와 함께 기존의 열전달상관식을 통한 결과와 예측된 Nu 수 분포를 비교하였다.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
• /
• pp.62-63
• /
• 2003

Electron-phonon interaction plays a significant role in forming of colossal magnetoresistance effect (CMR). Polaron formation was observed by neutron diffraction and by extended X-ray absorption fine structure (EXAFS) analysis. Local probe as given by the EXAFS is a useful method to study the polaronic charge and its dependence on temperature and ions size. Here we present the EXAFS study of polaronic charge in $La_{0.7}Ca_{0.3-x}Ba_{x}MnO_3$ compositions.

• 한국신재생에너지학회:학술대회논문집
• /
• 한국신재생에너지학회 2011년도 추계학술대회 초록집
• /
• pp.47.1-47.1
• /
• 2011

We report on a direct measurement of two-dimensional chemical and electrical distribution on the surface of photovoltaic Cu(In,Ga)$Se_2$ thin-films using a nano-scale spectroscopic and electrical characterization, respectively. The Raman measurement reveals non-uniformed surface phonon vibration which comes from different compositional distribution and defects in the nature of polycrystalline thin-films. On the other hand, potential analysis by scanning Kelvin probe force microscopy shows a higher surface potential or a small work function on grain boundaries of the thin-films than on the grain surfaces. This demonstrates the grain boundary is positively charged and local built-in potential exist on grain boundary, which improve electron-hole separation on grain boundary. Local electrical transport measurements with scanning probe microscopy on the thin-films indicates that as external bias is increases, local current is started to flow from grain boundary and saturated over 0.3 V external bias. This accounts for carrier behavior in the vicinity of grain boundary with regard to defect states. We suggest that electron-hole separation at the grain boundary as well as chemical and electrical distribution of polycrystalline Cu(In,Ga)$Se_2$ thin-films.

• 한국유체기계학회 논문집
• /
• 제7권2호
• /
• pp.14-20
• /
• 2004

In this study, the overall performance and the local flow field of the centrifugal compressor with the refrigerant HFC-l34a were numerically studied using CFX-TASCflow. The thermodynamic and transport properties of the refrigerant gas were modeled by REFPROP which is NIST refrigerant properties database. The impacts of a grid qualify, discretization scheme, turbulent model and interaction between a impeller and a cascade diffuser were analyzed comparatively. The results were compared with experimental data and 1-D design results using COMPAL and agreed well with others. The numerical method and data obtained in this study can be applied to the design and modification of centrifugal compressors with real gases

• 대한자원환경지질학회:학술대회논문집
• /
• 대한자원환경지질학회 2005년도 춘계 학술발표회 논문집
• /
• pp.148-151
• /
• 2005

Field-scale DNAPL dissolution is controlled by the topology of DNAPL distributions with respect to the velocity field. A high resolution percolation model was developed and employed to simulate the distribution of DNAPL within source zones. Statistically anisotropic permeability values and capillary parameters were generated for 10${\times}$10${\times}$10 m domains at a resolution of 0.05 to 0.1 m for various statistical properties. TCE leakage was simulated at various rates and the distribution of residual DNAPL in 'fingers' and 'lenses' was computed. Variations in finger and lens geometries, frequencies, average DNAPL saturations, and overall source topology were predicted to be strongly influenced by statistical properties of the medium as well as by injection rate and fluid properties. Model results were found to be consistent with observations from controlled DNAPL release experiments reported in the literature. The computed distributions of aquifer properties and DNAPL were utilized to perform high-resolution numerical simulations of groundwater flow and dissolved transport. Simulations were performed to assess the effect of grout or foam injection in bore holes within the source zone and of shallow point-releases of fluids with various properties on dissolution in DNAPL dissolution rate, even for widely spaced injection points. The results indicate that measures that induced partial flow reductions through DNAPL source zones can significantly decrease dissolution rates from residual DNAPL. The benefit from induced partial flow reductions is two-fold: 1) local flow reduction in DNAPL contaminated zones reduces mass transfer rates, and 2) contaminant flux reductions occur due to the decrease in groundwater velocity

• Progress in Superconductivity
• /
• 제6권1호
• /
• pp.13-18
• /
• 2004

High-.ate in-situ$ YBa_2$Cu$Cu_3$$O_{7-x}$ (YBCO) film growth was demonstrated by means of the electron beam co-evaporation. Even though our oxygen pressure is low, ∼$5 ${\times}$10^{-5}$ Torr, we can synthesize as-grown superconducting YBCO films at a deposition rate of around 10 nm/s. Relatively high temperatures of around 90$0^{\circ}C$ was necessary in this process so far, and it suggests that this temperature at a given oxygen activity allows a Ba-Cu-O liquid formation along with an YBCO epitaxy. Local critical current density shows a clear correlation with local resistivity. Homogeneous transport properties with a large critical current density ($4 ∼ 5 MA/\textrm{cm}^2$ at 77K, 0T) are observed in top faulted region while it is found that the bottom part carries little supercurrent with a large local resistivity. Therefore, it is possible that thickness dependence of critical current density is closely related with a topological variation of good superconducting paths and/or grains in the film bodies. The information derived from it may be useful in the characterization and optimization of superconducting films for electrical power and other applications.

• Applied Microscopy
• /
• 제47권3호
• /
• pp.105-109
• /
• 2017

The effect of temperature and vanadium metal concentration on the electronic and thermoelectric properties of Si in the diamond cubic structure has been investigated using a combination of density functional theory simulations and the semi classical Boltzmann's theory. The BotzTrap code within the constant relaxation time approximation has been used to obtain the Seebeck coefficient and other transport properties of interest for alloys of the structure $Si_{1-x}V_x$, where x is 0, 0.125, 0.25, 0.375, and 0.5. The thermoelectric properties have been extracted for a temperature range of 300 K to 1,000 K. The general trend with V atom substitution for Si causes the Seeback coefficient to increase and the thermal conductivity to decrease for the various alloys. The optimum values are for $Si_5V_3$ and $Si_4V_4$ alloys for charge carrier concentrations of $10^{21}cm^{-3}$ in the mid temperature range of 500~800 K. This is a very desirable effect for a promising thermoelectric and the figure of merit ZT approaches 0.2 at 600 K for the p-type $Si_5V_3$ alloy.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2013년도 제45회 하계 정기학술대회 초록집
• /
• pp.128.1-128.1
• /
• 2013

We investigated the correlation between electrical transport and mechanical stress in $Bi_2Te_2Se$ by using a conductive probe atomic force microscopy in an ultra-high vacuum environment. Uniform distribution of measured friction and current were observed over a single quintuple layer terrace, which is an indication of the uniform chemical composition of the surface. By measuring the charge transport of $Bi_2Te_2Se$ surface as a function of the load applied by a tip to the sample, we found that the current density varies with applied load. The variation of current density was explained in light of the combined effect of the changes in the in-plane conductance and spin-orbit coupling that were theoretically predicted. We suppose that the local density of states is modified by tip-induced strain, but topological phase still remains. We exposed a clean topological insulator surface by tip-induced indentation. The surface conductance on the indented $Bi_2Te_2Se$ surface was studied, and the role of surface oxide on the surface conductance is discussed.

• 한국재료학회지
• /
• 제9권6호
• /
• pp.635-653
• /
• 1999

The present work considers work considers research strategies to address global warming. Specifically, this work considers the development of technologies of importance for the reduction of greenhouse gas emission and, especially, the materials that are critical to these technologies. It is argued that novel materials that are essential for the production of environmentally friendly energy may be developed through a special kind of engineering: interface engineering, rather than through classical bulk chemistry. Progress on the interface engineering requires to increase the present state of understanding on the local properties of materials interfaces and interfaces processes. This, consequently, requires coordinated international efforts in order to establish a strong background in the science of materials interfaces. This paper considers the impact of interfaces, such as surfaces and grain boundaries, on the functional properties of materials. This work provides evidence that interfaces exhibit outstanding properties that are not displayed by the bulk phase. It is shown that the local interface chemistry and structure and entirely different than those of the bulk phase. In consequence the transport of both charge and matter along and across interfaces, that is so important for energy conversion, is different than that in the bulk. Despite that the thickness of interfaces is of an order to a nanometer, their impact on materials properties is substantial and, in many cases, controlling. This leads to the conclusion that the development of novel materials with desired properties for specific industrial applications will be possible through controlled interface chemistry. Specifically, this will concern materials of importance for energy conversion and environmental monitoring. Therefore, there is a need to increase the present state of understanding of the local properties of materials interfaces and the relationship between interfaces and the functional properties of materials. In order to accomplish this task coordinated international efforts of specialized research centres are required. These efforts are specifically urgent regarding the development of materials of importance for the reduction of greenhouse gases. Success of research in this area depends critically on financial support that can be provided for projects on materials of importance for a sustainable environment, and these must be considered priorities for all of the global economies. The authors of the present work represent an international research group economies. The authors of the present work represent an international research group that has entered into a collaboration on the development of the materials that are critical for the reduction of greenhouse gas emissions.