• 제목/요약/키워드: Local corrosion

검색결과 240건 처리시간 0.03초

연속용융 도금라인 용 고내침식 Fe계 합금 개발 (Development of High Erosion Resistant Fe-based Alloy for Continuous Hot Dipping Line)

  • 백민숙;김용철;백경철;곽준섭;윤동주
    • 한국표면공학회지
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    • 제53권3호
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    • pp.95-103
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    • 2020
  • In this study, the material used in the hot dip galvanizing equipment was poorly corrosion-resistant, so it was performed to solve the cost and time problems caused by equipment replacement. The theoretical calculation was performed using the DV-Xα method(Discrete Variational Local-density approximation method). The alloy (STS4XX series) of the equipment currently used has a martensite phase. Therefore, the theoretical calculation was performed by applying P4 / mmm, which is a tetragonal structure. The new alloy was chosen by designing theoretical values close to existing materials. Considering elements that contribute to corrosion, most have high prices. Therefore, the design was completed by adjusting the content using only the components of the reference material in the theoretical design. The final design alloys were chosen as D6 and D9. Designed D6 and D9 were dissolved and prepared using an induction furnace. After the heat treatment process was completed, the corrosion rate of the alloys was confirmed by using the potentiodynamic polarization test. The surface of the prepared alloys were processed horizontally and then polished to # 1200 using sand paper to perform potentiodynamic polarization test. Domestic products: 4.735 mpy (mils / year), D6: 0.9166 mpy, D9: 0.3372 mpy, alloys designed than domestic products had a lower corrosion rate. Therefore, the designed alloy was expected to have better erosion resistance.

고온용융염계 산화분위기에서 초합금의 부식거동 (Corrosion Behavior of Superalloys in Hot Molten Salt under Oxidation Atmosphere)

  • 조수행;임종호;정준호;이원경;오승철;박성원
    • 한국방사성폐기물학회:학술대회논문집
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    • 한국방사성폐기물학회 2004년도 학술논문집
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    • pp.285-291
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    • 2004
  • LiCl-$Li_2O-O_2$ 용융염계에서 용융염 취급장치의 구조재료를 위한 평가의 일환으로 Inconel 718, X-750, Haynes 75, 263 합금의 부식거동을 분위기온도; $650^{\circ}C$, 부식시간: 24~168h, $Li_2O$농도; 3wt%, 혼합가스농도; Ar-10%$O_2$에서 조사하였다. LiCl-$Li_2O-O_2$ 용융염계에서 부식속도는 Haynes 263 < Haynes 75 < Inconel X-750 < Inconel 718 순서로 나타났으며, Haynes 263 합금이 가장 우수한 내부식성을 나타내었다. Haynes 75의 부식생성물은 $Cr_2O_4$, $NiFe_2O_4$, $LiNiO_2$, $Li_2NiFe_2O_4$, Inconel 718의 부식생성물은 $Cr_2O_4$$NiFe_2O_4$ 이며 Haynes 263은 $Li(Ni,Co)O_2$, $NiCr_2O_4$$LiTiO_2$, Inconel X-750은 $Cr_2O_3$, $NiFe_2O_4$,$FeNi_3$, (Al,Nb,Ti)$O_2$의 부식생성물을 나타내었다. Haynes 263은 국부부식의 거동을 보이는 반면, Haynes 75, Inconel 718 및 Inconel X-750은 전면 부식 거동을 나타내었다.

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Characteristics Evaluation on Welding Metal Zones Welded with Inconel 625 Filler Metal to Cast Steel for Piston Crown Material

  • Jeong, Jae-Hyun;Moon, Kyung-Man;Lee, Sung-Yul;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Advanced Marine Engineering and Technology
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    • 제39권5호
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    • pp.542-547
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    • 2015
  • Since the oil price has been significantly jumped for several years, a heavy oil of low quality has been mainly used in the diesel engine of the merchant ship. Thus, a combustion chamber of the engine has been often exposed to severely corrosive environment more and more because temperature of the exhaust gas of the combustion chamber has been getting higher and higher with increasing of using the heavy oil of low quality. As a result, wear and corrosion of the engine parts such as exhaust valve, piston crown and cylinder head surrounded with combustion chamber are more serious compared to the other parts of the engine. Therefore, an optimum repair welding for these engine parts is very important to prolong their lifetime in a economical point of view. In this study, Inconel 625 filler metal were welded with GTAW method in the cast steel which would be generally used with piston crown material. And the corrosion properties of weld metal, heat affected and base metal zones were investigated using electrochemical methods such as measurement of corrosion potential, anodic polarization curves, cyclic voltammogram and impedance etc. in 35% $H_2SO_4$ solution. The weld metal and base metal zones exhibited the highest and lowest values of hardness respectively. Furthermore, the corrosion current density of the weld metal zone revealed the lowest value, having the highest value of hardness. The corrosive products with red color and local corrosion like as a pitting corrosion were considerably observed at the base metal zone, while these morphologies were not wholly observed in the weld metal zone. In particular, the polarization characteristics such as impedance, polarization curve and cyclic voltammogran associated with corrosion resistance property were well in good agreement with each other. Consequently, it is suggested that the mechanical and corrosion characteristics of the piston crown can be predominantly improved by repair welding method using the Inconel 625 electrode.

감육배관의 요한요소해석에 의한 파괴거동 평가 (Fracture Behavior Evaluation of Wall Thinned pipes by Finite Element Analysis)

  • 안석환;남기우;김진욱;이수식;윤자문
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.320-325
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    • 2004
  • Fracture behaviors and strength of pipes with local wall thinning are very important Jar the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on strength and fracture behaviors of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis.

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굽힘하중을 받는 배관의 파손에 미치는 감육의 영향 (Effect of Wall Thinning on the Failure of Pipes Subjected to Bending Load)

  • 안석환;남기우
    • 대한기계학회논문집A
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    • 제29권4호
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    • pp.606-613
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    • 2005
  • Effects of circumferentially local wall thinning on the fracture behavior of pipes were investigated by monotonic four-point bending. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area included an eroded ratio of d/t= 0.2, 0.5, 0.6, and 0.8, and an eroded length of ${\ell}\;=10mm,$ 25mm, and 120mm. Fracture type could be classified into ovalization, local buckling, and crack initiation depending on the eroded length and eroded ratio. Three-dimensional elasto-plastic analyses were also carried out using the finite element method, which is able to accurately simulate fracture behaviors excepting failure due to cracking. It was possible to predict the crack initiation point by estimating true fracture ductility under multi-axial stress conditions at the center of the thinned area.

내압을 받는 외부 국부 감육 직관의 파손 기준 (Failure Criterion of Straight Pipe with Outer Local Wall Thinning under Internal Pressure)

  • 김수영;남기우
    • 동력기계공학회지
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    • 제18권1호
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    • pp.76-83
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    • 2014
  • This study was carried out an experimental and finite element analysis on the fracture behavior of straight pipes with local wall thinning under internal pressure. Local wall thinning was machined on the pipes in order to simulate erosion/corrosion metal loss. The configurations of the eroded area has an eroded ratio of d/t=0.80~0.92 and an eroded length of l=25, 50 and 102 mm. Three-dimensional elastic-plastic analyses were also carried out using the finite element method, which is able to accurately simulate failure behaviors. In regards to the relation ship between pressure and eroded ratio, the criterion that can be used safely under operating pressure and design pressure were obtained from this calculation. The results of this calculation were in relatively good agreement with that of the experiment.

Al 7050 단조품의 국부적 불균일 조직 형성에 대한 연구 (A Study on the Local Inhomogeneous Structure of Al 7050 Forged Part)

  • 이정환;김대용;김재곤;이상용;이영선;전승문;이명건
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1995년도 제2회 단조심포지엄 단조기술의 진보
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    • pp.81-90
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    • 1995
  • Age hardenable aluminum alloys show high specific strength, good thermal and electrical conductivity as well as lightness, and are typical aircraft materials. High fatigue strength and good resistancy against stress corrosion cracking are also important for aircraft aluminum alloys. Al alloy 7050 has been developed to meet the above mentioned requirements and the use of this alloy as forged aircraft part becomes more important. However, forged 7050 parts showed undersirable structures such as severe local grain coarsening in surface area and unproper metal flow that is degrading mechanical properties. In this paper, microstructural aspects of die forging in the Al alloy 7050 are investigated. Also suggested are the optimal forging conditions for microstructural control of Al alloy 7050.

Al 7050 단조품 표면의 입도성장층 방지에 관한 연구 (A Study on the Local Grain Coarsening in Surface of Al 7050 Forged Part)

  • 이정환;이상용;이영선
    • 연구논문집
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    • 통권26호
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    • pp.113-120
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    • 1996
  • Age hardenable aluminium alloys show high specific strength, good thermal and electrical conductivity as well as lightness, and are typical aircraft materials. High fatigue strength and good resistancy against stress corrosion cracking are also important for aircraft aluminium alloys. Al alloy 7050 has been developed to meet the above mentioned requirements and the use of this alloy as forged aircraft part becomes more important. However, forged 7050 parts showed undersiable structures such as severe local grain coarsening in surface area and unproper metal flow that is degrading mechanical properties. In this paper, microstructural aspects of die forging in the Al alloy 7050 are investigated. Also suggested are the optimal forging conditions for microstructural control of Al alloy 7050.

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3차원 유한요소해석을 이용한 엘보우의 감육 결함 특성 평가 (Evaluation on Failure Characteristics of the Local Wall Thinning Elbows Using Three Dimensional Finite Element Analysis)

  • 김태순;박치용;김진원;박재학
    • 한국안전학회지
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    • 제18권3호
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    • pp.39-45
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    • 2003
  • The failure mode of a pipe due to local wall thinning is increasingly more attention in the nuclear power plant industry. To assess the integrity of locally wall thinned pipe, it is necessary to perform many simulations under various conditions. Because the modeling for locally wall thinned elbow is more complicated than that of straight pipe the efficient modeling method for finite element analysis is necessary. In this study, the more simple efficient modeling method of three-dimensional finite element analysis for locally wall thinned elbow has been suggested and verified. And using the method, the failure mode of local wall thinned elbows that have different thinning lengths and circumferential angles is evaluated. From the results, we concluded that the collapse load of elbows has been decreased by the increase of wall thinning shape factors such as thinning lengths and circumferential angles.

미소시험편에 의한 강 용접부의 응력부식 균열 평가에 관한 연구 (A Study on the Stress Corrosion Cracking Evaluation for Weld Joint of Steel by Using Miniaturized Small Specimen)

  • 유효선
    • Journal of Welding and Joining
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    • 제12권4호
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    • pp.63-75
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    • 1994
  • The conventional SCC(stress corrosion cracking) test methods have much difficulty in evaluating the SCC behaviors of the localized zone like HAZ, bond line and weld metal because of the specimen size. Accordingly, the purpose of this paper is to develop the new SCC test method of the welded zone by evaluating the SCC susceptibility on parent metal and various microstructures of the welded zone by SP(small punch) test method using miniaturized small specimen and SSRT(slow strain rate test) method(SP-SSRT). Besides, this study is to verify the efficiency of the SP-SSRT results through AE(acoustic emission) test which is a useful technique to monitor the microfracture processes of the material. From the results of SCC susceptibility, SEM observation and AE test, it can be concluded that the SP-SSRT test using miniaturized small specimen(10mm*10mm*0.5mm) will be a good test method to evaluate the SCC susceptibility on the local zone such as the welded zone.

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