• Title/Summary/Keyword: Lithium second batteries

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Performance Comparison Analysis of Artificial Intelligence Models for Estimating Remaining Capacity of Lithium-Ion Batteries

  • Kyu-Ha Kim;Byeong-Soo Jung;Sang-Hyun Lee
    • International Journal of Advanced Culture Technology
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    • v.11 no.3
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    • pp.310-314
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    • 2023
  • The purpose of this study is to predict the remaining capacity of lithium-ion batteries and evaluate their performance using five artificial intelligence models, including linear regression analysis, decision tree, random forest, neural network, and ensemble model. We is in the study, measured Excel data from the CS2 lithium-ion battery was used, and the prediction accuracy of the model was measured using evaluation indicators such as mean square error, mean absolute error, coefficient of determination, and root mean square error. As a result of this study, the Root Mean Square Error(RMSE) of the linear regression model was 0.045, the decision tree model was 0.038, the random forest model was 0.034, the neural network model was 0.032, and the ensemble model was 0.030. The ensemble model had the best prediction performance, with the neural network model taking second place. The decision tree model and random forest model also performed quite well, and the linear regression model showed poor prediction performance compared to other models. Therefore, through this study, ensemble models and neural network models are most suitable for predicting the remaining capacity of lithium-ion batteries, and decision tree and random forest models also showed good performance. Linear regression models showed relatively poor predictive performance. Therefore, it was concluded that it is appropriate to prioritize ensemble models and neural network models in order to improve the efficiency of battery management and energy systems.

Analysis of Car Fire Cases Related to a Lithium Battery and Cause Investigation Technique (리튬배터리와 관련된 차량화재 사례 및 원인조사 기법 분석)

  • Lee, Eui-Pyeong
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.98-106
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    • 2019
  • As lithium batteries have been used for car navigation systems and as the second battery for black boxes, lithium battery-related car fires have often occurred. In the case a lithium battery is the fire origin, a fire investigation technique has not been established to determine if a battery ignites or whether the lithium battery is damaged by fire. This study introduced car fire cases related to lithium batteries, analyzed the causes of a fire of a lithium battery, and proposed fire investigation techniques to objectively determine if a lithium battery ignites or whether a lithium battery is damaged by fire after external ignition.

Improving the Electrochemical Properties of Lithium Terephthalate-based Lithium-Organic Battery with A Graphite Coated Current Collector (흑연 코팅 집전체를 이용한 Lithium Terephthalate 기반 리튬-유기 이차전지의 전기화학적 특성 개선)

  • Kwon, O Hyeon;Kim, Jong Bin;Kim, Jae-Kwang
    • Journal of the Korean Electrochemical Society
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    • v.22 no.3
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    • pp.122-127
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    • 2019
  • In this study, we investigate the electrochemical performance of lithium terephthalate (LTA) battery using graphite coated metal current collector to overcome the disadvantages of organic batteries which is high interfacial resistance between current collector and electrode. The LTA anode material is synthesized by acid-based ion exchange reaction without impurities. The contact properties between stick-type LTA-based electrode and graphite coated current collector are estimated by the cross-section SEM and EIS. The graphite coated current collector significantly reduced the interfacial resistance of the LTA battery. The second discharge capacities of bare current collector LTA and graphite coated current collector LTA batteries are 107.6 mAh/g and 148.8 mAh/g at 0.1C, respectively. The graphite coated current collector LTA batteries show higher cycle life, higher discharge capacity, and higher rate-capability than bare LTA batteries.

Ni-P Coated Sn Powders as Anode for Lithium Secondary Batteries

  • Jo, Yong-Nam;Im, Dong-Min;Kim, Jae-Jung;Oh, Seung-M.
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.88-93
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    • 2007
  • Nano-sized Sn particles were coated with Ni-P layer using an electroless deposition method and their anodic performance was tested for lithium secondary batteries. Uniform coating layers were obtained, of which the thickness was controlled by varying the $Ni^{2+}$ concentration in the plating bath. It was found that the Ni-P layer plays two important roles in improving the anodic performance of Sn powder electrode. First, it prevents the inter-particle aggregation between Sn particles during the charge/discharge process. Second, it provides an electrical conduction pathway to the Sn particles, which allows an electrode fabrication without an addition of conductive carbon. A pseudo-optimized sample showed a good cyclability and high capacity ($>400mAh\;g^{-1}$) even without conductive carbon loading.

A Study on Optimizing Zinc-Air Batteries Using M&S (M&S를 이용한 아연-공기전지 최적화 연구)

  • Lee, Jae-In
    • Journal of the Korea Institute of Military Science and Technology
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    • v.17 no.5
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    • pp.688-693
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    • 2014
  • Zinc-air batteries which has various merits in the aspect of energy density, power density and price relative to lithium based second batteries were extensively investigated recently. To develope and optimize these zinc-air batteries, the method of M&S is so efficient solution to reduce price and time. Therefore, in this paper, after executing mathematical modeling, I optimized the zinc-air battery through the simulation and make bolt-cell and discharge it to compare with simulation result. As a result, predictions are well agreed with experimental results.

The Surface Micro-structures with the Atmospheres in Graphitizing the Carboneous Materials for Rechargeable Batteries and Their Effects on the Cell Performances (이차전지용 탄소재의 흑연화 분위기에 따른 표면미세구조와 전지성능에 미치는 영향)

  • Huh, Yoon;Lee, Jeong-Yong;Yoon, Sang-Young
    • Korean Journal of Materials Research
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    • v.10 no.11
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    • pp.743-748
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    • 2000
  • Amorphous carbons(neddle cokes), which are used as anode materials for lithium ion secondary batteries, were graphitized or heat-treated at high temperature in $N_2$ atmosphere and in Ar atmosphere, after adding $B_2O_3$. After then, using transmission eletron microscopy, their surface micro-structures and the formations and distributions of the second phases were analyzed. It was studied that such analyzed results were related to the cell capacities and efficiencies.

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Effect of Doping on the Ionic Conductivity of Li$_2$Po$_{4-x}$N$_{x}$ thin Film (Li$_2$Po$_{4-x}$N$_{x}$ 박막의 이온전도도에 미치는 Ti 첨가)

  • 이재혁;이유기;박종완
    • Journal of the Korean institute of surface engineering
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    • v.30 no.4
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    • pp.255-261
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    • 1997
  • Thin film batteries can be used as a micro power source for electronic in which minute power is needed. In this study, lithium phosphorous oxynitride(LIPON) thin films were deposited as an eletrolyte for lithium ion batteries using RF magentron sputtering of lithium phosphate in N2. Ti was also added into the LIPON films as a second network former to enhance the ioinc conductivity of the films. The optimum conditions for LIPON film deposition were sought and the electrolyte with the conductivity of $2.5 \times 10^{-6}$S/cm was obtained at the condition of RF power 4.4 W/$\textrm{cm}^2$, process pressure 10 mtorr and pure nitrogen ambience. Furthermore, the conductivity of LIPON films was increased from $2.5 \times 10^{-6}$S/cm to $8.6 \times 10^{-6}$S/cm by the doping of 2.4at.% Ti. It was also found that by adding Ti to LIPON films, Li content was increased and nitrogen content that reported having the cross-linking effect on LIPON films was also increased as confirmed XPS.

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An AC Impedance Spectrum Measurement Device for the Battery Module to Predict the Remaining Useful Life of the Lithium-Ion Batteries (리튬배터리의 잔여 유효 수명 추정을 위한 배터리 모듈용 AC 임피던스 스펙트럼 측정장치)

  • Lee, Seung-June;Farhan, Farooq;Khan, Asad;Cho, Woo-Jin
    • The Transactions of the Korean Institute of Power Electronics
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    • v.25 no.4
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    • pp.251-260
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    • 2020
  • A growing interest has emerged in recycling used automobile batteries into energy storage systems (ESSs) to prevent their harmful effects to the environment from improper disposal and to recycle such resources. To transform used batteries into ESSs, composing battery modules with similar performance by grading them is crucial. Imbalance among battery modules degrades the performance of an entire system. Thus, the selection of modules with similar performance and remaining life is the first prerequisite in the reuse of used batteries. In this study, we develop an instrument to measure the impedance spectrum of a battery module to predict the useful remaining life of the used battery. The developed hardware and software are used to apply the AC perturbation to the used battery module and measure its impedance spectrum. The developed instrument can measure the impedance spectrum of the battery module from 0.1 Hz to 1 kHz and calculate the equivalent circuit parameters through curve fitting. The performance of the developed instrument is verified by comparing the measured impedance spectra with those obtained by a commercial equipment.

Electrical Characteristics of Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$ Cathode Materials for Li-Ion Secondary Batteries (리튬 이온 이차전지 Cathode용 Li(Mn$_{1-}$$\delta$Nb$\delta$)$_2$O$_4$의 전기적 특성)

  • 오용주;유광수
    • Journal of the Korean Ceramic Society
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    • v.35 no.9
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    • pp.995-1001
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    • 1998
  • As a basic study for cathode materials of {{{{ { {LiMn }_{2 }O }_{4 } }}-based lithium-ion secondary batteries Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} ($\delta$=0.05, 0.1, 0.2) materials which Nb is substituted for Mn were synthesized by the solid state reaction at 80$0^{\circ}C$ and 110$0^{\circ}C$ respectively. The second phase {{{{ { LiNbO}_{3 } }} appeared above $\delta$=0.1 As the result of im-pedance analysis as the amount of substituted Nb increased the resistivity of grain boundary increased greatly. Compared to undoped-{{{{ { {LiMn }_{2 }O }_{4 } }} the electrical conductivity of Li({{{{ { { { {Mn }_{1-$\delta$ }Nb }_{$\delta$} )}_{2 }O }_{4 } }} decreased slightly but is charging capacity and potential plateau increased.

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Electrochemical Characteristics of Si/Mo Multilayer Anode for Lithium-Ion Batteries (리튬 이온 전지용 Si/Mo 다층박막 음극의 전기화학적 특성)

  • Park, Jong-Wan;Ascencio Jorge A.
    • Korean Journal of Materials Research
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    • v.16 no.5
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    • pp.297-301
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    • 2006
  • Si/Mo multilayer anode consisting of active/inactive material was prepared using rf/dc magnetron sputtering. Molybdenum acts as a buffer against the volume change of the Silicon. Multilayer deposited on RT (reversible treatment) copper foil current collector to enhance adhesion between Silicon and copper foil. Deposited Silicon was identified as an amorphous. Amorphous has a relatively open structure than crystal structure, thus prevents the lattice expansion and has many diffusion paths of Li ion. When deposited time of Silicon and Molybdenum is 30 second and 2 second respectably, electrode has more capacity and good cycle stability. A 3000 nm thick multilayer was maintained 99% of the initial capacity (1624 $mAhg^{-1}$) after 100 cycles. As the increase of the multilayer thickness (4500 nm, 6000 nm), Si/Mo mutilayer anodes show aggravation cycle stability.