• Title/Summary/Keyword: Lithium reduction

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Lightweight Model for Energy Storage System Remaining Useful Lifetime Estimation (ESS 잔존수명 추정 모델 경량화 연구)

  • Yu, Jung-Un;Park, Sung-Won;Son, Sung-Yong
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.13 no.5
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    • pp.436-442
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    • 2020
  • ESS(energy storage system) has recently become an important power source in various areas due to increased renewable energy resources. The more ESS is used, the less the effective capacity of the ESS. Therefore, it is important to manage the remaining useful lifetime(RUL). RUL can be checked regularly by inspectors, but it is common to be monitored and estimated by an automated monitoring system. The accurate state estimation is important to ESS operator for economical and efficient operation. RUL estimation model usually requires complex mathematical calculations consisting of cycle aging and calendar aging that are caused by the operation frequency and over time, respectively. A lightweight RUL estimation model is required to be embedded in low-performance processors that are installed on ESS. In this paper, a lightweight ESS RUL estimation model is proposed to operate on low-performance micro-processors. The simulation results show less than 1% errors compared to the original RUL model case. In addition, a performance analysis is conducted based on ATmega 328. The results show 76.8 to 78.3 % of computational time reduction.

Electrochemical Performance of Pitch coated Nano Silicon Sheets / Graphite Composite as Anode Material (피치로 코팅된 Nano Silicon Sheets/Graphite 음극복합소재의 전기화학적 특성)

  • Lee, Tae Heon;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.59 no.4
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    • pp.487-492
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    • 2021
  • In this study, the electrochemical properties of pitch coated silicon sheets/graphite anode materials were investigated. Using NaCl as a template, silicon sheets were prepared through the stöber method and the magnesiothermic reduction methode. In order to synthesize the anode composite, the silicon sheets and graphite were combined with SDBS. The pitch coated silicon sheets/graphite was synthesized using THF as a solvent for the anode material composite. The physical properties of the prepared anode composites were analysed by XRD, SEM, EDS and TGA. The electrochemical performances of the prepared anode composites were performed by the current charge/discharge, rate performance, cyclic voltammetry and EIS tests in the electrolyte LiPF6 dissolved solvents (EC:DMC:EMC=1:1:1 vol%). As the silicon composition of silicon sheets/graphite composite material increased, the discharge capacity also increased, but the cycle stability tended to decrease. The anode material of pitch coated silicon sheets/graphite composite (silicon sheets:graphite=3:7 weight ratio) showed the initial discharge capacity of 1228.8 mAh/g and the capacity retention ratio of 77% after 50 cycles. From these results, it was found that the cycle stability of pitch coated silicon sheets/graphite was improved.

Development of Screw-Type Handy Earth Auger for an Improved Digging Efficiency(I) - Design and Manufacture - (토양굴취력이 향상된 스크류형 경량 식혈기 개발(I) - 설계 및 제작 -)

  • Kim, Jin Hyun;Lee, Jae Hyun;Kim, Ki Dong;Ko, Chi Woong;Kim, Dong Geun
    • Journal of agriculture & life science
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    • v.50 no.3
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    • pp.31-41
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    • 2016
  • This study was conducted to develop a handy earth auger for use in sloppy and rugged forest terrains in order to reduce labor cost which comprises a major part of the production costs in forest afforestation projects. The first prototype is developed consist of two parts, the soil-digging screw and the battery power source. The specifications of the first prototype screw are: length of 170mm, a top diameter of 60mm, bottom diameter of 47mm, 23° angle for each helix, and a 50mm awl-head tip. The use of a single line of screw was selected for reduced weight. In addition, a power source of rotary DC Motor(WD-6G2425, WONILL, Korea) with a maximum torque of 30kgf-cm, rotation of 20-30rpm, K6G30C decelerator with a reduction ratio of 30:1 which could be used with no load for 48 was operated. In consideration of its weight, a lithium battery was utilized in line with the goal of developing a lightweight auger. In order to evaluate the performance of the first prototype, test sites were selected as 6 areas. The rotational force was found to be highest in area A(Solid area), followed by areas F(Mounted slope 40° area) and E(Mounted slope 30° area). It was also observed that in general, the rotational force increased along with the increase in soil depth with the maximum rotational force recorded at 10cm.

Effect of Mg Addition on the Microstructure and Mechanical Properties of Al-Li-Ce Alloys (Al-Li-Ce계 합금의 미세조직 및 기계적 특성에 미치는 Mg 첨가의 영향)

  • Byeong-Kwon Lee;Eun-Chan Ko;Yong-Ho Kim;Hyo-Sang Yoo;Hyeon-Taek Son;Sung-Kil Hong
    • Korean Journal of Materials Research
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    • v.33 no.10
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    • pp.393-399
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    • 2023
  • In this study, changes in the microstructure and mechanical properties of cast and extruded Al-2Li-1Ce alloy materials were investigated as the Mg content was varied. The density decreased to 2.485, 2.46 and 2.435 g/cm3 when the Mg content in the Al-2Li-1Ce alloy was increased to 2, 4 and 6 wt%, respectively. Intermetallic compounds of Al11Ce3 were observed in all alloys, while the β-phase of Al3Mg2 was observed in alloys containing 6 wt% of Mg. In the extruded material, with increasing Mg content the average grain size decreased to 84.8, 71.6 and 36.2 ㎛, and the fraction of high-angle grain boundaries (greater than 15°) increased to 82.8 %, 88.6 %, and 91.8 %, respectively. This occurred because the increased Mg content promotes dynamic recrystallization during hot extrusion. Tensile test results showed that as the Mg content increased, both the yield strength and tensile strength increased. The yield strength reached 86.1, 107.3, and 186.4 MPa, and the tensile strength reached 215.2, 285, and 360.5 MPa, respectively. However, it is worth noting that the ductility decreased to 27.78 %, 25.65 %, and 20.72 % as the Mg content increased. This reduction in ductility is attributed to the strengthening effect resulting from the increased amount of dissolved Mg, and grain refinement due to dynamic recrystallization.

Structural and optical properties of Ni-substituted spinel $LiMn_2O_4$ thin films (니켈 치환된 스피넬 LiMn2O4 박막의 구조적, 광학적 성질)

  • Lee, Jung-Han;Kim, Kwang-Joo
    • Journal of the Korean Vacuum Society
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    • v.15 no.5
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    • pp.527-533
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    • 2006
  • Spinel $LiNi_xMn_{2-x}O_4$ thin films were synthesized up to x = 0.9 by a sol-gel method employing spin-coating. The Ni-substituted films were found to maintain cubic structure at low x but to exhibit tetragonal structure for $x{\geq}0.6$. Such cubic-tetragonal phase transition indicates that $Ni^{3+}(d7)$ ions with low-spin $(t_{2g}^6,e_g^1)$ state occupy the octahedral sites of the compound, thus being subject to the Jahn-Teller distortion. By x-ray photoelectron spectroscopy both $Ni^{2+}$ and $Ni^{3+}$ ions were detected. Optical properties of the $LiNi_xMn_{2-x}O_4$ films were investigated by spectroscopic ellipsometry (SE) in the visible?ultraviolet range. The measured dielectric function spectra by SE mainly consist of broad absorption structures attributed to charge-transfer (CT) transitions, $O^{2-}(2p){\rightarrow}Mn^{4+}(3d)$ for 1.9 $(t_{2g})$ and $2.8{\sim}3.0$ eV $(e_g)$ structures and $O^{2-}(2p){\rightarrow}Mn^{3+}(3d)$ for 2.3 $(t_{2g})$ and $3.4{\sim}3.6$ eV $(e_g)$ structures. Also, sharp absorption structures were observed at about 1.6, 1.7, and 1.9 eV, interpreted as due to d-d crystal-field transitions within the octahedral $Mn^{3+}$ ion. The strengths of these absorption structures are reduced by the Ni substitution. Rapid reduction of the CT transition strength involving the eg states for x = 0.6 is attributed to the reduced wavefunction overlap between the $e_g$ and the $O^{2-}(2p)$ states due to the tetragonal extension of the lattice constant by the Jahn-Teller effect.

Study on LiFePO4 Composite Cathode Materials to Enhance Thermal Stability of Hybrid Capacitor (하이브리드 커패시터의 열안정성 개선을 위한 LiFePO4 복합양극 소재에 관한 연구)

  • Kwon, Tae-Soon;Park, Ji-Hyun;Kang, Seok-Won;Jeong, Rag-Gyo;Han, Sang-Jin
    • Korean Chemical Engineering Research
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    • v.55 no.2
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    • pp.242-246
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    • 2017
  • The application of composite cathode materials including $LiFePO_4$ (lithium iron phosphate) of olivine crystal structure, which has high thermal stability, were investigated as alternatives for hybrid battery-capacitors with a $LiMn_2O_4$ (spinel crystal structure) cathode, which exhibits decreased performance at high temperatures due to Mn-dissolution. However, these composite cathode materials have been shown to have a reduction in capacity by conducting life cycle experiments in which a $LiFePO_4$/activated carbon cell was charged and discharged between 1.0 V and 2.3 V at two temperatures, $25^{\circ}C$ and $60^{\circ}C$, which caused a degradation of the anode due to the lowered voltage in the anode. To avoid the degradation of the anode, composite cathodes of $LiFePO_4/LiMn_2O_4$ (50:50 wt%), $LiFePO_4$/activated carbon (50:50 wt%) and $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ (50:50 wt%) were prepared and the life cycle experiments were conducted on these cells. The composite cathode including $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ of layered crystal structure showed stable voltage behavior. The discharge capacity retention ratio of $LiNi_{1/3}Co_{1/3}Mn_{1/3}O_2$ was about twice as high as that of a $LiFePO_4/LiMn_2O_4$ cell at thermal stability experiment for a duration of 1,000 hours charged at 2.3 V and a temperature of $80^{\circ}C$.