• 제목/요약/키워드: Lithium ion cells

검색결과 158건 처리시간 0.03초

Tin Oxide-flyash Composite 전극의 리튬 이온 Intercalation 메카니즘과 임피던스 특성에 관한 연구 (A Study on the Impedance Characteristics and Mechanisms of Li Intecalation on the Tin Oxide-flyash Composite Electrodes)

  • 구할본;김종욱
    • 한국전기전자재료학회논문지
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    • 제17권11호
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    • pp.1224-1229
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    • 2004
  • The purpose of this study is to research and develop tin oxide-flyash composite for lithium Ion polymer battery. Tin oxide is one of the promising material as a electrode active material for lithium Ion polymer battery (LIPB). Tin-based oxides have theoretical volumetric and gravimetric capacities that are four and two times that of carbon, respectively. We investigated cyclic voltammetry, AC impedance and charge/discharge cycling of SnO$_2$-flyash/SPE/Li cells. The first discharge capacity of SnO$_2$-flyash composite anode was 639 mAh/g. The discharge capacity of SnO$_2$-flyash composite anode was 563 and 472 mAh/g at 6th and 15th cycle, respectively. The SnO$_2$-flyash composite anode with PVDF-PMMA-PC-EC-LiClO$_4$ electrolyte showed good capacity with cycling.

Influence of Lithium Ions on the Ion-coordinating Ruthenium Sensitizers for Nanocrystalline Dye-sensitized Solar Cells

  • Cho, Na-Ra;Lee, Chi-Woo;Cho, Dae-Won;Kang, Sang-Ook;Ko, Jae-Jung;Nazeeruddin, Mohammad K.
    • Bulletin of the Korean Chemical Society
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    • 제32권spc8호
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    • pp.3031-3038
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    • 2011
  • Ion-coordinating ruthenium complexes [cis-Ru(dcbpy)(L)(NCS)$_2$, where dcbpy is 4,4'-dicarboxylic acid-2,2'-bipyridine and L is 1,4,7,10-tetraoxa-13-azacyclopentadecane, JK-121, or bis(2-(2-methoxy-ethoxy)ethyl) amine, JK-122] have been synthesized and characterized using $^1H$ NMR, Fourier transform IR, UV/vis spectroscopy, and cyclic voltammetry. The effect of $Li^+$ in the electrolyte on the photovoltaic performance was investigated. With the stepwise addition of $Li^+$ to a liquid electrolyte, the device shows significant increase in the photo-current density, but a small decrease in the open circuit voltage. The solar cell with a hole conductor, the addition of $Li^+$ resulted in a 30% improvement in efficiency. The JK-121 sensitized cells in the liquid and solid-state electrolyte give power conversion efficiencies of 6.95% and 2.59%, respectively, under the simulated sunlight.

리튬이온 배터리의 화재 시험을 통한 열 전달 메커니즘 및 손상 평가 (Evaluation of Heat Transfer Mechanisms and Damage Assessment through Fire Testing of Lithium-Ion Batteries)

  • 신정호;김용현;김은주;배영철
    • 한국전자통신학회논문지
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    • 제19권4호
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    • pp.669-676
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    • 2024
  • 본 논문은 리튬이온 배터리의 화재 시험을 통해 배터리 손상 및 열 전달 메커니즘을 평가하고, 배터리 관리 시스템(BMS)의 효율성과 안전성을 향상시키기 위한 방안을 모색한다. 각 섹터의 온도 변화는 T1, T2, T3 지점에서 측정하며, 발화 전극에 전기 투입 후 10분 동안 주변 셀들의 반응을 관찰하고 기록한다. 시험 결과, A 섹터와 B 섹터의 배터리는 완전 발화하여 심각한 물리적 손상을 입고, C 섹터의 배터리는 발화되지 않고 큰 손상을 입지 않는다. 이를 통해 섹터 간 간격이 발화 및 열 전파를 저감하는 데 중요한 역할을 한다는 것을 확인한다. 본 논문은 리튬이온 배터리의 열 관리 시스템 설계 시 섹터 간 간격을 고려하여 발화 및 열 전파를 저감할 수 있는 중요한 설계 요소임을 시사하며, 향후 다양한 배터리 모델과 조건을 통해 추가적인 시험을 수행하여 BMS의 효율성과 안전성을 더욱 향상시킬 방안을 제안한다.

Sol-Gel 방법을 이용한 리튬이차전지용 $Li_4Ti_5O_{12}$의 제조 및 특성 (Preparation and Characterization of $Li_4Ti_5O_{12}$ using Sol-Gel Method for Lithium Secondary Battery)

  • 오미현;김한주;김규식;김영재;손원근;임기조;박수길
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1989-1991
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    • 2005
  • Lithium titanium oxide as anode material for energy storage prepared by novel synthesis method. $Li_4Ti_5O_{12}$ based spinel-framework structures are of great interest material for lithium-ion batteries. We describe here $Li_4Ti_5O_{12}$ a zero-strain insertion material was prepared by novel sol-gel method and by high energy ball milling (HEBM) of precursor to from nanocrystalline phases. According to the X-ray diffraction and scanning electron microscopy analysis, uniformly distributed $Li_4Ti_5O_{12}$ particles with grain sizes of 100nm were synthesized. Lithium cells, consisting of $Li_4Ti_5O_{12}$ anode and lithium cathode showed the 173 mAh/g in the range of $1.0{\sim}3.0V$. Furthermore, the crystalline structure of $Li_4Ti_5O_{12}$ didn't transfer during the lithium intercalation and deintercalation process.

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전자선을 이용한 PVDF-HFP/Silylated Al2O3가 코팅된 리튬 이차 전지용 폴리에틸렌 분리막의 전기화학적 특성 연구 (Electrochemical Study on PVDF-HFP/Silylated Al2O3-coated PE Separators using the Electron Beam Irradiation for Lithium Secondary Battery)

  • 손준용;신준화;노영창
    • 방사선산업학회지
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    • 제4권4호
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    • pp.359-364
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    • 2010
  • PVDF-HFP (binder)/silylated alumina (inorganic particle)-coated PE (polyethylene) separators were with various compositions of binder and inorganic particle were prepared by a dip-coating process with humidity control (R.H. 25% and 50%) using electron beam irradiation. The morphology of the coated PVDF-$HFP/Al_2O_3$ layer with various compositions of PVDF-HFP and $Al_2O_3$, and humidity condition was found to be an important factor in determining ionic conductivity of the prepared separators. The PVDF-$HFP/Al_2O_3$ (5/5)-coated PE separator prepared at R.H. 50% followed by electron beam irradiation at 200 kGy was applied for lithium-ion polymer battery and the cell test results showed improved high-rate discharge performance and better cyclic stability compared to the cells with the bare PE and the PVDF-HFP-coated PE separators.

A New Modularized Balancing Circuit for Series Connected Battery cells

  • Lee, Hyo-Jae;Jung, Young-Seok
    • 동력기계공학회지
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    • 제18권6호
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    • pp.193-199
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    • 2014
  • The series connected battery cells are mainly used in high voltage battery pack application. However parameter inequality of each battery cell makes battery voltage imbalance problem. In this paper, a new balancing circuit utilizing converter scheme for the series connected battery cells is proposed. Proposed circuit offers easy control and fast equalization time. Moreover the circuit can be used in a practical application because it has high modularity and can operate during the charging/discharging cycle. To show its superiorness and effectiveness, the principle of proposed circuit is explained with computer simulation and experiment is carried out using lithium-ion battery.

Effect of Mo-doped LiFePO4 Positive Electrode Material for Lithium Batteries

  • Oh, Seung-Min;Sun, Yang-Kook
    • Journal of Electrochemical Science and Technology
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    • 제3권4호
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    • pp.172-177
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    • 2012
  • Mo-doped $LiFePO_4$ was synthesized via co-precipitation method using sucrose as the carbon source. Structure, surface morphology, and the electrochemical properties of the synthesized olivine compounds were investigated using Rietveld refinement of X-ray diffraction data (XRD), scanning electron microscopy (SEM), and electrochemical charge-ischarge tests. Spherical morphology with the particle size of ${\sim}8{\mu}m$ authenticated the enhanced tap density and volumetric energy density of the synthesized materials. Charge-discharge behavior of $LiFePO_4$ and Mo-doped $LiFePO_4$ cells demonstrated a specific capacity of 130 and 145 mAh $g^{-1}$, respectively. Mo-doped $LiFePO_4$ cells exhibited an excellent discharge capacity at 96 mAh $g^{-1}$ at 7 C-rate.

실리콘 재료의 표면개질에 따른 리튬이차전지 음극 특성 (Electrochemical Properties of Surface-Modified Silicon as Anode for Lithium Secondary Batteries)

  • 박철완;도칠훈;문성인;윤문수
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.602-606
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    • 2003
  • Silicon has been developed as an alternate anode material for lithium secondary batteries. A simple approach to improve the electrical contact of silicon powder has described. Carbon-coated and silver-coated silicon have been prepared by chemical vapor deposition and electroless plating respectively. Assembled cells, which consisted of surface modified silicon, lithium foil and $Li^+$ contained organic electrolyte, have been studied using electrochemical methods. Carbon-coated silicon was improved in the electrochemical performance such as reversibility and resistance compared to surface-unmodified silicon.

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셀프에너지 밸런싱을 고려한 리튬이온전지의 Battery Management System 구현 (Implementation of Battery Management System for Li-ion Battery Considering Self-energy Balancing)

  • 김지명;이후동;태동현;페레이라 마리토;박지현;노대석
    • 한국산학기술학회논문지
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    • 제21권3호
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    • pp.585-593
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    • 2020
  • 현재까지 총 29건의 전기저장장치의 화재가 발생되었는데, 이 중 22건이 신재생에너지 연계용이며, 완전충전 이후, 운전대기 상태인 휴지기간 동안에 계절과 무관하게 화재사고가 발생되었다. 이것은 병렬로 연결된 셀들의 SOC 상태가 서로 다른 경우, 의도하지 않게 SOC가 높은 셀에서 낮은 셀로 전류가 이동하는 셀프에너지 밸런싱 현상으로, 일부 셀이 과충전되어 열폭주로 인한 화재의 원인으로 평가되고 있다. 따라서, 본 논문에서는 전기저장장치의 셀프에너지 밸런싱을 방지하는 새로운 BMS의 회로구성과 운용 알고리즘 그리고 SOC 평가알고리즘을 제안한다. 제안한 알고리즘과 구현한 BMS를 바탕으로 리튬이온전지의 열화 특성과 열화 및 정상 셀 간의 셀프에너지 밸런싱 특성을 분석한 결과, 정상 셀 대비 열화 셀의 방전 용량 비율은 91.75[%]이며, 열화율이 8.25[%]임을 알 수 있었고, SOC가 높은 정상 셀에서 SOC 낮은 열화 셀로 전류가 이동하는 셀프에너지 밸런싱 현상이 발생함을 확인하였다. 또한, 셀프에너지 밸런싱 전류가 과도하게 높아지는 경우, BMS가 확실하게 셀들의 병렬연결을 분리하여, 리튬이온전지의 안전성을 향상시킬 수 있어, 본 논문에서 제안한 BMS의 유용성을 확인하였다.

Synthesis of $Li_xNi_(0.85)Co_(0.15)O_2$ by the PVA-procursor Method and the Effect of Air Flow During the Pyrolysis

  • 권호진;김근배;김수주;송미영;박선희;권혜영;박동곤
    • Bulletin of the Korean Chemical Society
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    • 제20권5호
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    • pp.508-516
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    • 1999
  • Polycrystalline powder of LixNi0.85Co0.15O2 was synthesized by pyrolyzing a powder precursor obtained by the PVA-precursor method. Coin cells of lithium-ion rechargeable battery were assembled, whose the cathodes were fabricated from the crystalline powders of LixNi0.85Co0.15O2 synthesized by the method. The effect of synthetic variation on the property of the cell was tested by carrying out 100 consecutive cycles of charge-dis-charge on the cells. The property of the cell was largely influenced by the pyrolysis conditions applied for the synthesis of the LixNi0.85Co0.15O2. Depending on whether the pyrolysis was carried out in standing air or in the flow of dry air, the discharge capacity and cycle-reversibility of the cell varied in large extent. When the powder precursor was pyrolyzed in standing air, a minor phase of lithium carbonate was remained in the LixNi0.85Co0.15O2. The carbon containing powder precursor had to be pyrolyzed in the flow of dry air to eliminate the minor phase. In the flow of dry air, the lithium carbonate in the precursor was eliminated over 500-700。C without any prominent heat event. By controlling the flow of air over the precursor during its pyrolysis, particle size could also be altered. The effect of flowing dry air, during first step pyrolysis or during second step heat treatment, on the property of the cell was discussed.