• 전력전자학회논문지
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• 제25권4호
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• pp.303-310
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• 2020

Estimating the accurate internal state of lithium ion batteries to increase their safety and efficiency is crucial. Various algorithms are used to estimate the internal state of a lithium ion battery, such as the extended Kalman filter and sliding mode observer. A state-space model is essential in using algorithms to estimate the internal state of a battery. Two principal methods are used to express the state-space model, namely, continuous time and discrete time. In this work, the extended Kalman filter is employed to estimate the internal state of a battery. Moreover, this work presents and analyzes the estimation performance of algorithms consisting of a continuous time state-space model and a discrete time state-space model through static and dynamic profiles.

• Journal of Advanced Marine Engineering and Technology
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• 제30권5호
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• pp.623-628
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• 2006

Laser material processing is a very fast advancing technology for various industrial applications. because of many advantages. Its major advantage of less and controlled heat input has been exploited successfully for the very critical application of aluminium alloy welding. This study suggested the occurrence source of weld-defects and its solution methods in a welding of lithium ion battery by pulsed Nd:YAG laser. In experiment. battery case has changed over joint geometry from welding of side position to flat one. In the case of a electrolyte injection hole in order to seal it. welding is carried out after pressing Al ball. At this time. an eccentric degree. contact length and gap are worked as a major parameters. As improving the method of Al ball pressing. it was able to reduce an eccentricity. increase the contact length and decrease gap. As a results of a experiment. a sound weld bead shape and crack-free weld bead can be obtained.

• 한국마린엔지니어링학회:학술대회논문집
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• 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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• pp.339-343
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• 2005

Laser material processing is a very fast growing technology for various industrial applications, because of many advantages. Its major advantage of less and controlled heat input has been exploited successfully for the very critical application of aluminium alloy welding. This study suggested the occurrence source of weld-defects and its solution methods in a welding of lithium ion battery by pulsed Nd:YAG laser. In experiment, battery case has changed over joint geometry from welding of side position to flat one. In case of a electrolyte injection hole in order to seal it, welding is carried out after pressing Al ball. At this time, an eccentric degree, contact length and gap are worked as a major parameters. As improving the method of Al ball pressing, it was able to reduce an eccentricity, increase the contact length and decrease gap. As a results of a experiment, a sound weld bead shape and crack-free weld bead can be obtained.

• 전력전자학회:학술대회논문집
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• 전력전자학회 2008년도 추계학술대회 논문집
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• pp.13-15
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• 2008

Charging or discharging secondary batteries such as a lithium-ion battery is essential in the stage of production and takes long time over two hours. And the charge/discharge system is operated with high switching frequency over several tens kHz. Therefore, to simulate such a system in the conventional way takes very long time and huge files are produced. Finally, the simulation would be unable with general PC class. In this paper, the lithium-ion battery charge/discharge system is analyzed by using state space averaging method. As a result, the simulation time is reduced dramatically and the charge/- discharge characteristics of the lithium-ion battery can be observed.

• 한국안전학회지
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• 제37권2호
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• pp.76-87
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• 2022

Lithium-ion batteries (LIBs) have attracted much interest for their high energy density (>150 mAh/g), high capacity, low self-discharge rate, and high coulombic efficiency. However, with the successful commercialization of LIBs, fire and explosion incidents are likely to increase. The thermal runaway is known as the major factor in battery-related accidents that can lead to a series of critical conditions. Considering this, recent studies have shown an increased interest in countering the safety issues associated with LIBs. Although safety standards for LIB use have recently been formulated, little attention has been paid to the safety around the manufacturing process for battery products. The present study introduces a risk assessment method suitable for assessing the safety of the LIB-manufacturing process. In the assessment method, a compensation parameter (Z-factor) is employed to correctly evaluate the process's safety on the basis of the type of material (e.g., metal anode, liquid electrolyte, solid-state electrolytes) utilized in a cell. The proposed method has been applied to an 18650 cell-manufacturing process, and three sub-processes have been identified as possibly vulnerable parts (risk index: >4). This study offers some crucial insights into the establishment of safety standards for battery-manufacturing processes.

• Journal of Electrochemical Science and Technology
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• 제12권4호
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• pp.415-423
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• 2021

For a battery module where single cells are connected in series, the single cells should each have a similar state of charge (SOC) to prevent them from being exposed to an overcharge or over-discharge during charge-discharge cycling. To detect the existence of unbalanced SOC cells in a battery module, we propose a simple measurement method using a single-frequency response of electrochemical impedance spectroscopy (EIS). For a commercially available graphite/nickel-cobalt-aluminum-oxide lithium-ion cell, the cell impedance increases significantly below SOC20%, while the impedance in the medium SOC region (SOC20%-SOC80%) remains low with only minor changes. This impedance behavior is mostly due to the elementary processes of cathode reactions in the cell. Among the impedance values (Z, Z', Z"), the imaginary component of Z" regarding cathode reactions changes heavily as a function of SOC, in particular, when the EIS measurement is performed around 0.1 Hz. Thanks to the significant difference in the time constant of cathode reactions between ≤SOC10% and ≥SOC20%, a single-frequency EIS measurement enlarges the difference in impedance between balanced and unbalanced cells in the module and facilitates an ~80% improvement in the detection signal compared to results with conventional EIS measurements.

• 한국수소및신에너지학회논문집
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• 제33권1호
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• pp.85-94
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• 2022

To detect anomaly signs of thermal runaway in advance, this study analyzed the signals from various sensors installed in lithium-ion batteries. The thermal runaway mechanism was analyzed, and measurement variables for anomalies of a battery cell were surface temperature, strain, and gas concentration. The changes and characteristics of three variables during the thermal runaway process were analyzed under the abuse environment: the overheat and the overcharge. In experiment, the thermal runaway of the battery proceeded in the initial developing stage, the outgassing stage, and the ignition stage. Analysis from the measured data indicated that the suitable variable to detect all stages of thermal runaway is the surface temperature of the battery, and surface strain is alternative.

• 전기화학회지
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• 제4권3호
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• pp.132-137
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• 2001

최근 리튬이온전지를 채용한 노트북 PC의 수요는 계속 증가하고 있으며, 노트북 PC용 전지로는 잔존용량과 사용가능 시간을 정확하게 예측하며, 스스로 최적조건으로 충방전을 제어할 수 있는 SBP(smart battery pack)를 많이 채용하고 있다. SBP는 과충전, 과방전 및 과전류로부터 리튬이온전지의 안전성을 확보하기 위한 보호회로부 (protection IC)와 잔존용량 및 사용가능시간 등의 계산을 위한 지능회로부 (smart IC)로 구성되어있다. 보호회로는 충전 및 방전 FET를 이용하여 이상전류를 차단하며, SBS(smart battery system)는 system host, smart battery 및 smart battery charger로 구성되어 있다. 향후, SBP에 사용되는 IC는 저가이면서, 소비전류가 낮고, 소형화가 요구된다. 또한, microcomputer control type의 IC를 사용하고, 최적의 알고리즘을 개발하여 잔존용량 및 사용가능시간을 정확하게 예측할 필요가 있다. 이러한 SBS 기술은 노트북 PC 이외에도 전기자전거, 전기자동차, 전력저장용, 군사분야 등 광범위한 분야에서 사용될 것으로 예상된다.

• Carbon letters
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• 제11권2호
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• pp.127-130
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• 2010

Boron doped fullerene $C_{60}$ ($B:C_{60}$) films were prepared by the thermal evaporation of $C_{60}$ powder using argon plasma treatment. The morphology and structural characteristics of the thin films were investigated by scanning electron microscope (SEM), Fourier transform infra-red spectroscopy (FTIR) and x-ray photo electron spectroscopy (XPS). The electrochemical application of the boron doped fullerene film as a coating layer for silicon anodes in lithium ion batteries was also investigated. Cyclic voltammetry (CV) measurements were applied to the $B:C_{60}$ coated silicon electrodes at a scan rate of $0.05\;mVs^{-1}$. The CV results show that the $B:C_{60}$ coating layer act as a passivation layer with respect to the insertion and extraction of lithium ions into the silicon film electrode.

• 산업기술연구
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• 제40권1호
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• pp.7-12
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• 2020

Lithium-ion cells have become the go-to energy source across all applications; however, dendritic growth remains an issue to tackle. While there have been various research conducted and possible solutions offered, there is yet to be one that efficiently rules out the problem without, however, introducing another. This paper seeks to present a fast charging method and system to which lithium-ion batteries are charged while maintaining their lifetime. In the proposed method, various lithium cells are charged under multiple profiles. The parameters of charge profiles that inflict damage to the cell's electrodes are obtained and used as thresholds. Thus, during charging, voltage, current, and temperature are actively controlled under these thresholds. In this way, dendrite formation suppressed charging is achieved, and battery life is maintained. The fast-charging system designed, comprises of a 1.5kW charger, an inbuilt 600W battery pack, and an intelligent BMS with cell balancing technology. The system was also designed to respond to the aging of the battery to provide adequate threshold values. Among other tests conducted by KCTL, the cycle test result showed a capacity drop of only 0.68% after 500 cycles, thereby proving the life maintaining capability of the proposed method and system.