• Title/Summary/Keyword: Lithium air battery

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Techno-economic Analysis on the Present and Future of Secondary Battery Market for Electric Vehicles and ESS (전기차와 ESS용 이차전지 시장의 현재와 미래에 대한 기술경제적 분석)

  • Jung Seung Lee;Soo Kyung Kim
    • Journal of Information Technology Applications and Management
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    • v.30 no.1
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    • pp.1-9
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    • 2023
  • Interest in the future of the battery market is growing as Tesla announces plans to increase production of electric vehicles and to produce batteries. Tesla announced an action plan to reduce battery prices by 56% through 'Battery Day', which included expansion of factories to internalize batteries and improvement of materials and production technology. In the trend of automobile electrification, the expansion of the battery market, which accounts for 40% of the cost of electric vehicles, is inevitable, and the size of the electric vehicle battery market in 2026 is expected to increase more than five times compared to 2016. With the development of materials and process technology, the energy density of electric vehicle batteries is increasing while the price is decreasing. Soon, electric vehicles and internal combustion locomotives are expected to compete on the same line. Recently, the mileage of electric vehicles is approaching that of an internal combustion locomotive due to the installation of high-capacity batteries. In the EV battery market, Korean, Chinese and Japanese companies are fiercely competing. Based on market share in the first half of 2020, LG Chem, CATL, and Panasonic are leading the EV battery supply, and the top 10 companies included 3 Korean companies, 5 Chinese companies, and 2 Japanese companies. All-solid, lithium-sulfur, sodium-ion, and lithium air batteries are being discussed as the next-generation batteries after lithium-ion, among which all-solid-state batteries are the most active. All-solid-state batteries can dramatically improve stability and charging speed by using a solid electrolyte, and are excellent in terms of technology readiness level (TRL) among various technology alternatives. In order to increase the competitiveness of the battery industry in the future, efforts to increase the productivity and economy of electric vehicle batteries are also required along with the development of next-generation battery technology.

Development of Zinc Air Battery for Cellular Phone (휴대전화기용 아연공기전지 개발)

  • 엄승욱;김지훈;문성인;윤문수;김주용;박정식
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.9
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    • pp.936-941
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    • 2004
  • In recent years, the rapid growth of portable electronic devices requires the high-energy density characteristics of batteries. Zinc air batteries have specific capacity as high as 820mAh/g. However, Zinc air batteries used for hearing aid applications only so far, because the atmosphere could affect it, and it has weakness in the rate capability. However, recent developments of electrode manufacturing technologies made us to overcome that weakness. And the efforts of applying zinc air batteries to portable electronic devices, especially in cellular phone application have been increased. In this paper, the effects of conducting material and polymer binder in cathode on the electrochemical characteristics were investigated. Our research team succeeded in producing 2.4Ah class zinc air battery for cellular phone application. Its volumetric energy density was 920 wh/l, and gravimetric energy density was 308 wh/kg. The volumetric energy density of our zinc air battery is two times higher than one of lithium secondary battery, and three times higher than that of alkaline manganese battery.

Technology Trends in Post-Lithium Secondary Batteries (포스트 리튬 이차전지 기술 동향)

  • Y.H. Choi;H.S. Chung
    • Electronics and Telecommunications Trends
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    • v.38 no.6
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    • pp.128-136
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    • 2023
  • Lithium accounts for only 0.0017% of the earth crust, and it is produced in geographically limited regions such as South America, the United States, and China. Since the first half of 2017, the price of lithium has been continuously increasing, and with the rapid adoption of electric vehicles, lithium resources are expected to be depleted in the near future. In addition, economic blocs worldwide face intensifying scenarios such as competition for technological supremacy and protectionism of domestic industries. Consequently, Korea is deepening its dependence on China for core materials and is vulnerable to the influence of the United States Inflation Reduction Act. We analyze post-lithium secondary battery technologies that rely on more earth-abundant elements to replace lithium, whose production is limited to specific regions. Specifically, we focus on the technological status and issues of sodium-ion, zinc-air, and redox-flow batteries. In addition, research trends in post-lithium secondary batteries are examined. Post-lithium secondary batteries seem promising for large-capacity energy storage systems while reducing the costs of raw materials compared with existing lithium-based technologies.

Numerical Analysis of Moisture Ventilation in the Dry Room (Dry room내 수분환기에 대한 수치적 연구)

  • 이관수;임광옥;정영식
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.10
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    • pp.908-916
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    • 2000
  • In this paper, the characteristics of moisture ventilation in the lithium ion battery manufacturing dry room are studied numerically using standard $k-\varepsilon$ turbulence model. Both the steady-state and the unsteady behaviors of moisture ventilation are analyzed by considering local and uniform moisture generation. In order to evaluate the characteristics of moisture ventilation, three scales of ventilation efficiency and characteristic ventilation time are presented from the numerical results. It was shown that moisture distribution was dependent strongly on the flow field. The characteristics of moisture ventilation were improved by 20% and 40% in terms of the 1st scale of ventilation efficiency (SVE1) and the 2nd scale of ventilation efficiency (SVE2), respectively, through the modifications of design variables such as the addition of inlets, outlets and partition. A significant improvement in the characteristic ventilation time and the moisture exhaust efficiency was also made by these modifications.

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Carbon nanoballs: formation mechanism and electrochemical performance as an electrode material for the air cathode of a Li-air battery

  • Kang, Jun
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.8
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    • pp.838-842
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    • 2015
  • The Li-air battery is a promising candidate for the most energy-dense electrochemical power source because it has 5 to 10 times greater energy storage capacity than that of Li-ion batteries. However, the Li-air cell performance falls short of the theoretical estimate, primarily because the discharge terminates well before the pore volume of the air electrode is completely filled with lithium oxides. Therefore, the structure of carbon used in the air electrode is a critical factor that affects the performance of Li-air batteries. In a previous study, we reported a new class of carbon nanomaterial, named carbon nanoballs (CNBs), consisting of highly mesoporous spheres. Structural characterization revealed that the synthesized CNBs have excellent a meso-macro hierarchical pore structure, with an average diameter greater than 10 nm and a total pore volume more than $1.00cm^3g^{-1}$. In this study, CNBs are applied in an actual Li-air battery to evaluate the electrochemical performance. The formation mechanism and electrochemical performance of the CNBs are discussed in detail.

Synthesis of $Li_xNi_(0.85)Co_(0.15)O_2$ by the PVA-procursor Method and the Effect of Air Flow During the Pyrolysis

  • 권호진;김근배;김수주;송미영;박선희;권혜영;박동곤
    • Bulletin of the Korean Chemical Society
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    • v.20 no.5
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    • pp.508-516
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    • 1999
  • Polycrystalline powder of LixNi0.85Co0.15O2 was synthesized by pyrolyzing a powder precursor obtained by the PVA-precursor method. Coin cells of lithium-ion rechargeable battery were assembled, whose the cathodes were fabricated from the crystalline powders of LixNi0.85Co0.15O2 synthesized by the method. The effect of synthetic variation on the property of the cell was tested by carrying out 100 consecutive cycles of charge-dis-charge on the cells. The property of the cell was largely influenced by the pyrolysis conditions applied for the synthesis of the LixNi0.85Co0.15O2. Depending on whether the pyrolysis was carried out in standing air or in the flow of dry air, the discharge capacity and cycle-reversibility of the cell varied in large extent. When the powder precursor was pyrolyzed in standing air, a minor phase of lithium carbonate was remained in the LixNi0.85Co0.15O2. The carbon containing powder precursor had to be pyrolyzed in the flow of dry air to eliminate the minor phase. In the flow of dry air, the lithium carbonate in the precursor was eliminated over 500-700。C without any prominent heat event. By controlling the flow of air over the precursor during its pyrolysis, particle size could also be altered. The effect of flowing dry air, during first step pyrolysis or during second step heat treatment, on the property of the cell was discussed.

Trend on the Recycling Technologies for the used Manganese Dry Battery by the Patent Analysis (특허(特許)로 본 폐망간전지 재활용(再活用) 기술(技術) 동향(動向))

  • Shon, Jeong-Soo;Kang, Kyung-Seok;Han, Hye-Jung;Kim, Tae-Hyun;Shin, Shun-Myung
    • Resources Recycling
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    • v.17 no.2
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    • pp.76-84
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    • 2008
  • There are several kinds of battery such as zinc-air battery, lithium battery, manganese dry battery, silver oxide battery, mercury battery, sodium-sulphur battery, lead battery, nickel-hydrogen secondary battery, nickel-cadmium battery, lithium ion battery and alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents on the recycling technologies of the used manganese dry battery were analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), and Korea (KR) from 1986 to 2006. Patents were collected using key-words searching and filtered by filtering criteria. The trends of the patents were analyzed by the years, countries, companies, and technologies.

Trend on the Recycling Technologies for Spent Batteries by the Patent and Paper Analysis (특허(特許)와 논문(論文)으로 본 폐전지 재활용(再活用) 기술(技術) 동향(動向))

  • Shin, Shun-Myung;Joo, Sung-Ho;Kim, Soo-Kyung;Cho, Young-Ju;Cho, Bong-Gyoo
    • Resources Recycling
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    • v.21 no.4
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    • pp.16-25
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    • 2012
  • There are several kinds of batteries such as zinc-air battery, lithium battery, Manganese dry battery, silver oxide battery, sodium-sulphur battery, lead acid battery, metal hydride secondary battery, nickel-cadmium battery, lithium ion battery, alkaline battery, etc. These days it has been widely studied for the recycling technologies of the used battery from view points of economy and efficiency. In this paper, patents and published papers on the recycling technologies of the used battery were analyzed. The range of search was limited in the open patents of USA (US), European Union (EU), Japan (JP), Korea (KR) and SCI journal articles from 1972 to 2011. Patents and journal articles were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journal articles were analyzed by the years, countries, companies, and technologies.

Electrochemical Properties of Carbon Composites Prepared by Using Graphite Ball-milled in Argon and Air Atmosphere

  • Lee, Kyoung-Muk;Oh, Seh-Min;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • v.29 no.6
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    • pp.1121-1124
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    • 2008
  • A carbon composite was synthesized by mechanical mixing of ball-milled graphite and PVC powders, followed by pyrolysis reaction of PVC. Natural graphite ball milled under atmosphere of argon or air leads to a disordered structure. It appears that the electrochemical lithium intercalation reaction is dependent on the atmosphere in which the graphite is ball milled. The carbon composite obtained using air-milled graphite shows a high reversible capacity and high initial coulombic efficiency compared to argon-milled graphite. This is attributed to the enhanced thermal stability of a disordered structure in the air milled sample. For the one with air-milled graphite, the disordered structure is maintained during heat treatment, while argon-milled graphite is partially crystallized.

Study on the Development of Hybrid NMP Recovery System for Recovering the Used NMP in Lithium Ion Battery Cathode Manufacturing Process (리튬이온전지 양극제조 공정에서 사용된 NMP를 회수하기 위한 하이브리드형 NMP 회수시스템 개발에 관한 연구)

  • Hwang, Soon Ho;Nam, Seung Beak;Kim, Dong-Kwon;Kim, Yang Jun;Kang, Sung Eun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.5
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    • pp.289-296
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    • 2016
  • The availability of NMP, a solvent used in the manufacturing process of cathode material for lithium ion battery, depends on importation, and the price remains high because of the monopoly of BASF and ISP. For these reasons, most Lithium ion battery manufacturers reuse NMP after recovering it from the exhaust air in the drying process. In Korea, absorption method is mainly used for recovering NMP from the absorption tower using the hydrophilicity of NMP. However, this system has a few disadvantages, such as low purity (80%) of the recovered NMP and 100% emission due to high water content of the treated gas. In this study, we develop a hybrid NMP recovery system by combining cooling condensation method with concentration method, by which it is possible to obtain an NMP recovery rate of 99.6%, and a high purity (96.1%) of the recovered NMP.