• 제목/요약/키워드: Liquid-solid

검색결과 2,346건 처리시간 0.238초

Numerical Analysis of Cold Storage System with Array of Solid-Liquid Phase Change Module (저온의 고-액상변화 모듈 용기의 배열에 따른 축냉시스템의 수치해석)

  • Mun, Soo-Beom
    • Journal of the Korean Society of Marine Environment & Safety
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    • 제21권5호
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    • pp.577-582
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    • 2015
  • This paper is the fundamental study for the application of cold storage system to the transportation equipment by sea and land. This numerical study presents the solid-liquid phase change phenomenon of calcium chloride solution of 30wt %. The governing equations are 1-dimensional unsteady state heat transfer equations of $1^{st}$ order partial differential equations. This type of latent heat storage material is often usable in fishery vessel for controlling the temperature of container with constant condition. The governing equation was discretized with finite difference method and the program was composed with Mathcad program. The main parameters of this solution were the initial temperature of heat storage material, ambient temperature of cold air and the velocity of cold air. The data of boundary layer thickness becomes thin with the increasing of cold air flowing velocity and also the heat storage completion time become shorten.

Effects of Nucleating Agents on the Morphological, Mechanical and Thermal Insulating Properties of Rigid Polyurethane Foams

  • Kang, Ji-Woung;Kim, Ji-Mun;Kim, Min-Soo;Kim, Youn-Hee;Kim, Woo-Nyon;Jang, Won;Shin, Dae-Sig
    • Macromolecular Research
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    • 제17권11호
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    • pp.856-862
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    • 2009
  • This study examined the effects of liquid and solid additives on the morphological, mechanical and thermal insulating properties of rigid polyurethane foams (PUFs). The PUFs synthesized with tetramethylsilane (TEMS) as a liquid-type additive showed a smaller average cell size and lower thermal conductivity than those with the aerosil 200 and clay 30B as solid-type additives. When TEMS was added, the average cell size of the PUF became more uniform and finer due to the reduced surface tension of the polymer solution, which increased the nucleation rate and number of bubbles produced and reduced cell size. The PUFs with TEMS showed the highest closed cell contents among the PUFs prepared using TEMS, aerosil 200 and clay 30B. This suggests that the insulation properties of PUF can be determined by both the size of the cell structure and the amount of closed cell contents in the system. The compression and flexural strengths of the PUF increased slightly when the aerosil 200, clay 30B and TEMS were added compared those of the neat PUF. The reaction profiles of the PUFs showed a similar gel and tack tree time with the reaction time among the PUFs synthesized with three different additives and neat PUF. This suggests that the nucleating additives used in this study do not affect the bubble growth of the chemical reaction, and the additives may act as nucleating agents during the formation of PUF. From the above results of the cell size, thermal conductivity, closed cell contents and reaction profile of the PUFs, liquid-type nucleating agent, such as TEMS, is more effective in decreasing the thermal conductivity of the PUF than solid-type nucleating agent, such as aerosil 200 and clay 30B.

Measurement of the Refractive Index of a Mixed Polymer by a Prism Spectrometer and its Application (프리즘 분광계를 이용한 혼합 폴리머의 굴절률 측정과 응용)

  • Kim, Ji-Young;Ju, Young-Gu
    • Korean Journal of Optics and Photonics
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    • 제28권5호
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    • pp.221-228
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    • 2017
  • We measured the refractive index of a mixed polymer (NOA61, NOA84) in the liquid and solid states. First we made a hollow prism and filled it with UV (ultraviolet) epoxy. Measurement of the apex angle and the minimum-deviation angle gave the refractive index of the liquid polymer. To measure the refractive index of the solid polymer, an additional structure was included in the hollow prism, and the UV epoxy filling in the hollow prism was hardened. In both cases of liquid and solid polymers, the refractive index of the mixed polymer turned out to be proportional to the mix ratio. These results provide a method to vary the focal length of a double stacked cylindrical microlens array using UV epoxy.

Trends in the Isolation Rates and Species Distribution of Mycobacteria from 2014 to 2021 at Referral Clinical Laboratories in South Korea

  • Tae Soung Kim;Ga Yeon Kim;Young Ki Lee;Jae Kyung Kim
    • International Journal of Advanced Culture Technology
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    • 제11권3호
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    • pp.260-267
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    • 2023
  • We aimed to investigate the proportions of MTB- and NTM-positive tests and the distribution patterns of species isolated by contracted testing agencies in South Korea. Respiratory specimens submitted to contracted testing agencies in South Korea for AFB culture from January 2014 to December 2021 were included (533,713 specimens in total). Trends based on MTB and NTM detection, patient sex and age, culture medium type, and testing year were analyzed. MTB and NTM positive detection increased in the patients. The average ages of MTB- and NTM-positive patients increased in those aged ≥61 years. For solid culture, the MTB detection rate decreased from 5.9% in 2014 to 3.3% in 2018 and increased to 4.7% in 2021; the NTM detection rate increased from 2.1% in 2014 to 3.4% in 2018 and 3.7% in 2021. For liquid culture, the MTB detection rate decreased from 8.3% in 2014 to 5.5% in 2018 and increased to 6.0% in 2021; the NTM detection rate increased from 3.5% in 2014 to 5.5% in 2018 and decreased to 5.3% in 2021. An isolation ratio reversal between MTB and NTM was observed in 2018. In this study, we provide information on mycobacterial isolation rates and species distributions using AFB culture test results from Korea's referral laboratories. Increased MTB- and NTM-isolation rates were observed in individuals aged ≥60 years, indicating the need for regular testing and focused management for them. Expanding liquid culture applications, which show higher positivity rates than solid culture methods, is necessary.

Determination of thyroid hormones by solid-phase extraction using high performance liquid chromatograph/diode array detector/electro-spray ionization mass spectrometry in urine samples (HPLC/DAD/ESI-MS 및 고체상 추출법을 이용한 뇨시료중 갑상선 호르몬 분석)

  • Kwak, Sun Young;Moon, Myeong Hee;Pyo, Heesoo
    • Analytical Science and Technology
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    • 제19권6호
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    • pp.519-528
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    • 2006
  • An analytical method for the determination of thyroid hormones in urine samples has been studied by using solid-phase extraction and high-performance liquid chromatography/diode array detector/electro-spray mass spectrometry. Seven thyroid hormones were successfully separated by gradient elution on the reverse phase Hypersil ODS column (4.6 mm I.D., 100 mm length, particle size $5{\mu}m$) with ammonium formate buffer and acetonitrile, and UV spectra and mass fragment could be confirmed. The extraction recoveries of thyroid hormones in the urine samples (pH 3) were in the range of 89.0-113.1% with solid-phase extraction by C18, followed by elution with 4 ml of methanol/ammonium hydroxide (9 : 1). The calibration curves showed good linearity with the correlation coefficients ($r^2$) varying from 0.992 to 0.998 and the detection limits of all analytes were obtained in the range of 2-4 ng/ml (3.8-13.0 pmol/ml).

INFLUENCE OF CAPILLARITY AND ELASTICITY ON MICRO-CONTACTS

  • Zheng, J.;Streator, J.L.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 한국윤활학회 2002년도 proceedings of the second asia international conference on tribology
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    • pp.65-66
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    • 2002
  • One aspect of the stiction problem may be explained by the action of capillary forces in conjunction with surface elasticity. In the present work, the interaction between two elastic half-spaces separated by a small liquid bridge is investigated. By minimizing the total free energy stored in the interface (including elastic energy and surface energy), the equilibrium interface geometry is determined analytically in the case where there is no solid-solid contact. A non-dimensional number, $N_c=299\frac{{\gamma}^2_{LA}cos^2{\theta}V_o}{E^{'2}H^5}$ is found to govern the structure stability. When $N_c{\ge}1$, the two surfaces jump into solid-solid contact and, once this occurs, the contact area will continue to expand until the two surfaces are in full contact.

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Effects of anode and current collector materials on the power density of solid oxide electrolyte direct carbon fuel cell (고체산화물 전해질 직접탄소 연료전지의 전극 및 집전부 재질이 출력밀도에 미치는 영향)

  • Hwang, J.Y.;Yoon, J.E.;Kang, K.;Kim, J.H.;Lee, B.J.
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 춘계학술대회 논문집
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    • pp.392-394
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    • 2009
  • Direct Carbon Fuel Cells (DCFCs) generates electricity directly converting the chemical energy in coal. In the present study, effects of anode and current collector materials on the power density of DCFC are investigated experimentally. The adopted DCFC system is combined type of solid oxide fuel cells (SOFC) and molten carbonate fuel cells (MCFC) with the use of a liquid-molten salt anode and a solid oxide electrolyte, proposed by SRI. Power densities of 25 mm button cells with various combination of anode materials and current collector materials are measured.

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New Polymer Electrolytes for Solid State Dye-Sensitized Solar Cells (고분자 전해질을 이용한 고체형 염료감응 태양전지)

  • Kang, Yong-Soo;Lee, Yong-Gun;Kang, Moon-Sung;Kim, Jong-Hak;Char, Kook-Chen
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2007년도 춘계학술대회
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    • pp.231-234
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    • 2007
  • The solid state dye-sensitized saolrc cells (DSSCs) employing polymer electrolytes show high overall energy conversion efficiency as high as 4.5% at 1 sun conditions. The improved efficiency may be primarily due to the enlarged interfacial contact area between the electrolyte and dyes in addition to the increased ionic conductivity, which were done by utilizing liquid oligomers, followed by in situ self-solidification, to form the solid DSSCs "Oligomer Approach". The effect of the charge transfer resistance at the counter electrode side on the effciency has also been investigated.

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Fabrication of a Part by Heating and Forming in the Semi-solid State of the SKH51 Material (SKH51의 반응고 상태에서의 가열 및 성형에 의한 부품 제조)

  • Lee, Sang Yong
    • Journal of the Korean Society for Heat Treatment
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    • 제27권3호
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    • pp.127-132
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    • 2014
  • The semi-solid metal forming process has been applied to realize a near-net shape fabrication of a high speed tool steel. A complicatedly shaped part out of SKH51 was successfully manufactured by introducing pertinent materials, tooling and processing conditions. A SKH51 billet with globular grains was heated at temperatures between 1300 and $1350^{\circ}C$ using high frequency induction heater to get semi-solid microstructure before high rate injection of mushy metal into a die cavity for the forming process. It was necessary to control the preheating of dies between 300 and $400^{\circ}C$ to maintain the homogeneous microstructure during the semi-solid metal forming process. Significant defects such as pores, high fraction of liquid fraction and segregation could be removed from the part by using air vents.

Solid State Dynamic Nuclear Polarization of 1H Nuclear Spins at 0.3 T and 4.2 K

  • Shim, Jeong Hyun
    • Journal of the Korean Magnetic Resonance Society
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    • 제21권4호
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    • pp.114-118
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    • 2017
  • Here, I report solid state Dynamic Nuclear Polarization (DNP) of $^1H$ nuclear spins at 0.3 T and 4.2 K. The DNP polarizer was developed based on a commercial X-band Electron Spin Resonance (ESR) modified for DNP, in combination with a NMR console and a liquid-Helium cryostat. By detuning magnetic field, DNP spectrum was measured to find the optimal condition. At +3 mT detuned from on-resonance field, $^1H$ NMR signal of 60:40 glycerol/water frozen solution doped with 20 mM perdeuterated-Tempone was amplified 43 times. The $^1H$ spin polarization obtained at 4.2 K is over 3100 times higher than that at 300 K. The width of the DNP spectrum, which is five times broader than ESR spectrum, is inconsistent with solid effect or thermal mixing, and presumably suggests a different DNP mechanism.