• Title/Summary/Keyword: Liquid-solid

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Analysis of A356 alloys filling behavior considering Two-Phase flow (Two-Phase Flow를 이용한 A356 합금의 충전거동 해석)

  • Seol, D.E.;Kang, C.G.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.425-428
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    • 2006
  • A semi-solid forming technology has some advantages compared with conventional forming processes such as die casting, squeeze casting and hot/cold forging. In this study, the numerical analysis of semi-solid filling has been studied with solid fraction fs = 30% of A356 aluminum alloys. The finite difference program of two-phase flow model of Navier Stokes' equation coupled with heat transfer and solidification has been developed to predict a filling pattern, liquid segregation and temperature distribution of semi-solid metals. It gives die filling patterns and final solidification area. It can predict mechanical properties of semi-solid forming processes.

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Study on Yield Behavior of Semi-Solid Material by Finite Element Method and Upper-Bound Method (유한요소법과 상계법에 의한 반용융 재료의 항복거동 연구)

  • Choi, Jae-Chan;Park, Joon-Hong;Kim, Byung-Min
    • Journal of the Korean Society for Precision Engineering
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    • v.16 no.9
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    • pp.89-95
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    • 1999
  • The compression behavior of semi-solid materials in studied from a viewpoint of yield criteria and analysis methods. To describe the behavior of materials in semi-solid state, several theories have been proposed by extending the concept of plasticity of porous compressible materials. in the present work, the upper-bound method and the finite element method are used to model the simple compression process using yield criteria of Kuhn and Doraivelu. Segregation between solid and liquid which cause defect of product is analysed for Sn-15%Pb alloy is compared with the experimental result of Charreyron et al..

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Molecular Dynamics Simulation for Bilayers of Alkyl Thiol Molecules at Solid-Solid Interfaces

  • 이송희;김한수;박형숙
    • Bulletin of the Korean Chemical Society
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    • v.19 no.10
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    • pp.1047-1054
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    • 1998
  • We present the results of molecular dynamics simulations for three different systems of bilayers of long-chain alkyl thiol [S(CH2)15CH3] molecules on an solid-solid interface using the extended collapsed atom model for the chain-molecule. It is found that there exist two possible transitions: a continuous transition characterized by a change in molecular interaction between sites of different chain molecules with increasing area per molecule and a sudden transition from an ordered lattice-like state to a liquid-like state due to the lack of interactions between sites of chain molecules on different surfaces with increasing distance between two solid surfaces. The third system displays a smooth change in probability distribution characterized by the increment of gauche structure in the near-tail part of the chain with increasing area per molecule. The analyses of energetic results and chain conformation results demonstrate the characteristic change of chain structure of each system.

Review of the Solid Propulsion Trend in the Launch Vehicle(1) (발사체 고체 추진기관 동향 리뷰(1))

  • Lee, Tae-Ho
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2012.05a
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    • pp.201-212
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    • 2012
  • In general solid propulsion offers cost effective, large thrust capabilities comparing to the liquid propulsion which offers high specific impulse and restart capabilities. Therefore solid propulsion is well fitted for the first stage and boosters. BBL approach has been studied for the launch vehicle because of cost effectiveness, limited development time and low risk. Using of the carbon fiber epoxy resin in the solid rocket motor case is expanded, and specially high strength fibers are more attracted since its inert mass reduction.

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Biological activities of Fusarium isolates from soil and plants (토양 및 식물체로부터 분리한 Fusarium속 균주들의 생물활성)

  • Park, Joong-Hyeop;Choi, Gyung-Ja;Kim, Heung-Tae;Hong, Kyung-Sik;Song, Cheol;Kim, Jin-Seog;Kim, Jeong-Gyu;Cho, Kwang-Yun;Kim, Jin-Cheol
    • The Korean Journal of Pesticide Science
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    • v.4 no.3
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    • pp.19-26
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    • 2000
  • In order to select potent bioactive isolates, 70 Fusarium isolates obtained from soil and 21 plant species were screened by antifungal, insecticidal, herbicidal, and duckweed bioassays after culturing in potato dextrose broth and rice solid media. Eight (11.4%) of the 70 liquid broth cultures showed disease-controlling activities more than 80% against at least one of the 6 plant diseases tested. Fusarium sp. FO-68 isolate exhibited the most potent antifungal activity; it controlled rice blast, wheat leaf rust, and barley powdery mildew with control values more than 95%. Out of 70 solid cultures, 21 (30.0%) controlled at least one plant disease more than 80% and F. equiseti FO-68 isolate showed disease-controlling activities more than 95% against 3 plant diseases such as rice blast, tomato late blight, and wheat leaf rust. As for tile insecticidal activities, 2 liquid and 1 solid cultures showed potent insecticidal activities against pest insects more than 80%, Liquid cultures of F. oxysporum FO-61 and Fusarium sp. FO-80 isolates exhibited insecticidal activities more than 80% against green peach aphid and diamondback moth, respectively. The solid culture of Fusarium sp. FO-510 isolate had 80% insecticidal activity against green peach aphid. However, none of liquid and solid cultures of the 70 Fusarium isolates showed potent herbicidal activities against 10 upland weeds. As the results of duckweed assay, 3 liquid cultures showed 70% growth inhibitory activity at concentrations less than 1.25% of culture supernatants and 9 solid cultures had a potent inhibitory activity against duckweed growth. On the other hand, there was a significant correlation between antifungal activities and herbicidal activities against duckweed of both liquid and solid cultures of tile 70 Fusarium isolates.

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Interfacial Reaction between Li Metal and Solid Electrolyte in All-Solid-State Batteries (리튬금속과 고체전해질의 계면 반응)

  • Jae-Hun Kim
    • Corrosion Science and Technology
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    • v.22 no.4
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    • pp.287-296
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    • 2023
  • Li-ion batteries have been gaining increasing importance, driven by the growing utilization of renewable energy and the expansion of electric vehicles. To meet market demands, it is essential to ensure high energy density and battery safety. All-solid-state batteries (ASSBs) have attracted significant attention as a potential solution. Among the advantages, they operate with an ion-conductive solid electrolyte instead of a liquid electrolyte therefore significantly reducing the risk of fire. In addition, by using high-capacity alternative electrode materials, ASSBs offer a promising opportunity to enhance energy density, making them highly desirable in the automotive and secondary battery industries. In ASSBs, Li metal can be used as the anode, providing a high theoretical capacity (3860 mAh/g). However, challenges related to the high interfacial resistance between Li metal and solid electrolytes and those concerning material degradation during charge-discharge cycles need to be addressed for the successful commercialization of ASSBs. This review introduces and discusses the interfacial reactions between Li metal and solid electrolytes, along with research cases aiming to improve these interactions. Additionally, future development directions in this field are explored.

Microstructures and Mechanical Properties of Al-Cu Eutectic Composite by Upward Continuous Casting (상향식 연속주조법으로 제조한 Al-Cu 공정 복합재료의 응고조직 및 기계적 성질)

  • Kwon, Kee-Kyun;Sunwoo, Kuk-Hyun;Lee, Kye-Wan
    • Journal of Korea Foundry Society
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    • v.10 no.1
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    • pp.57-63
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    • 1990
  • Continuous casting of the $Al-CuAl_2$ eutectic composite was carried out by the upward continuous casting process. The morphology of the eutectic growth and the stability of solid-liquid interface were investigated under various growth conditions. It was possible to get the planar solid-liquid interface at the condition of $G_L/R$$3.6{\times}10^3^{\circ}Csec/mm^2$. And the colony structures were formed at the conditions of $G_L/R$ < $R=0.33{\times}10^3^{\circ}Csec/mm^2$. The inter-lamellar spacing of $Al-CuAl_2$ eutectic composite was decreased with the increase of pulling speed. The reduction of inter-lamellar spacing & value of $G_L/R$ caused the increase of ultimate tensile strength and Rockwell hardness in $Al-CuAl_2$ eutectic composite.

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Effects of the Furnace Temperature on the Growth Behavior of Directionally Solidified Al-Cu-Mg Alloy (Al-Cu-Mg합금의 일방향응고시 로온도에 따른 응고거동변화)

  • Moon, Cheol-Hee
    • Journal of Korea Foundry Society
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    • v.17 no.6
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    • pp.545-551
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    • 1997
  • 14 cm length Al-15Cu-1Mg alloys have been directionally solidified in 3 mm diameter alumina tubes in a furnace moved with a constant velocity V=12 cm/hr under various furnace temperatures of 660, 710 and $760^{\circ}C$. By analysing the evolution of the temperature profiles along the alloy length during the solidification, the growth characteristics such as the position of the solid/liquid interface, the local growth velocity (R) and the temperature gradient at the solid/liquid interface (G) have been determined. The effects of the furnace temperature on the growth behavior have been investigated by the comparison of R and G values for each temperature. Under the furnace temperature of $760^{\circ}C$, steady state growth region was observed for the latter half of the growth period.

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Measurement of Aldehydes in Replacement Liquids of Electronic Cigarettes by Headspace Gas Chromatography-mass Spectrometry

  • Lim, Hyun-Hee;Shin, Ho-Sang
    • Bulletin of the Korean Chemical Society
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    • v.34 no.9
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    • pp.2691-2696
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    • 2013
  • The electronic cigarette (E-cigarette) is a battery-powered device that aerosolizes nicotine so that it is readily delivered into the respiratory tract. The analytical data regarding the substances present in E-cigarettes are very limited. The aim of this study was to measure the concentration of aldehydes-formaldehyde (FA), acetaldehyde (AA) and, acrolein (AL)-in 225 replacement liquid brands from 17 E-cigarette shops sold in the Republic of Korea by headspace solid-phase micro extraction and gas chromatography-mass spectrometry (HS-SPME GC-MS). The concentration range of FA and AA was 0.02-10.09 mg/L (mean = 2.16 mg/L, detected in 207 of 225 samples) and 0.10-15.63 mg/L (mean = 4.98 mg/L, detected in all samples), respectively. AL was not detected in any of 225 replacement liquids. FA and AA were originally present in almost all replacement liquids of electronic cigarettes.

A Study on the Solid-liquid Equilibria for Benzene+aniline, Benzene+nitrobenzene, p-xylene+cyclohexane (Benzene+aniline, benzene+nitrobenzene, p-xylene+cyclohexane계의 고액평형에 관한 연구)

  • Park, So-Jin;Paik, Seung-Kwan
    • Applied Chemistry for Engineering
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    • v.9 no.6
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    • pp.864-869
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    • 1998
  • In this work, the solid-liquid equilibria (SLE) of some aromatic organic mixtures including benzene, widely used as an industrial solvent, were measured by static method using our own made experimental apparatus. The accuracy and reproducibility of apparatus were tested by comparing experimental results with literature values for 1-dodecanol+cyclohxane and benzene + p-xylene systems. The SLE for new binary systems of benzene+aniline, benzene+nitrobenzene, p-xylene+cyclohexane were measured afterwards and compared with the calculated values by modified UNIFAC(Dortmund) equation.

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