• 제목/요약/키워드: Liquid-phase reduction

검색결과 172건 처리시간 0.027초

원관내 수직상향 2상유동에서 고분자물질이 유동양식에 미치는 영향 (The Effect of Flow Patterns with Polymer Additivies From Two Phase Flow at Vertical up Ward in Circular Tube)

  • 김재근
    • Journal of Advanced Marine Engineering and Technology
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    • 제22권4호
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    • pp.505-514
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    • 1998
  • Flow pattern of air-water two phase flow depends on the conditions of pressure void fraction and channel geometry. We classify the flow pattern by measuring the output signal of the conductivity probe. under the classified flow pattern we mount a visualization equipment on the test section and take pictures. We vary the concentration of pure solvent and polymer to measure local void fraction. We know that the maximum point position of local void fraction distribution move from the center of the pipe to the wall of the pipe as JSL increase when JSA is constant in two phase flow. But we find that the maximum point position of local void friction move from the wal of the pipe to the center of the pipe when polymer concentration increase.

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이상 혐기성 소화 공정을 통한 슬러지 발생량 저감과 바이오가스 생산에 관한 연구 (A Study on the Sludge Reduction and Biogas Production through a Two-phase Anaerobic Digestion Process)

  • 우미희;한기봉
    • 대한환경공학회지
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    • 제32권9호
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    • pp.894-899
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    • 2010
  • 슬러지 감량 효율을 높이기 위해 오존전처리와 고 액분리조를 이용한 이상 혐기성 소화 공정 통해 다음과 같은 결과를 얻었다. 오존전처리를 통한 슬러지의 고형물 농도는 평균 TSS $8.3{\pm}2.0%$, VSS $9.2{\pm}2.8%$의 감소율을 나타내었다. 유기물 농도인 TCOD는 평균 $5.1{\pm}2.4%$ 감소하는 반면 SCOD는 평균 $72.0{\pm}6.5%$ 증가하였는데, 이는 오존으로 인해 세포내의 고분자 유기물이 용출되어 가용화되었기 때문이다. 이상 혐기성 소화 공정의 반응조별 소화가 진행됨에 따라 평균 TSS $21.5{\pm}3.4%$, VSS $20.2{\pm}8.4%$, TCOD $32.1{\pm}7.9%$, SCOD $22.1{\pm}7.2%$의 농도가 감소하였다. 최대 메탄생성량은 177.6 mL $CH_4/g$ TSS, 210.8 mL $CH_4/g$ VSS, 127.0 mL $CH_4/g$ TCOD, 1452.0 mL $CH_4/g$ SCOD이었다. 이상 혐기성 소화와 MLE 하수처리 공정의 연계처리 후 고형물 물질수지 결과 TSS 93.8%, VSS 92.0%의 감소율을 보였다. 이상 혐기성 소화 공정은 슬러지 처리 문제 해결과 신 재생에너지인 바이오가스 회수의 가능성을 보여줌으로서 향후 슬러지 감량에 해결책이 될 수 있을 것으로 사료된다.

Dependence of Phase Stability of Tetragonal Zirconia Polycrystal on Dopants

  • Chon, Uong
    • The Korean Journal of Ceramics
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    • 제4권4호
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    • pp.297-303
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    • 1998
  • The effect of aliovalent dopants, $ Nb_2O_5$ and MnO, on the phase stability of 12 mol% ceria partially-stabilized zirconia (Ce-TZP) polycrystals was studied. Both dopants (MnO and $ Nb_2O_5$) significantly increased the stability of the tetragonal zirconia phase (Mb temperature lower than liquid nitrogen temperature). The enhancement of the stability of the tetragonal phase in Ce-TZP doped with 1 mol% of Mno(Ce-TZP/MnO) andCe-TZP doped with 1 mol% of $ Nb_2O_5$(Ce-TZP/$ Nb_2O_5$) were explained by the significant reduction of the driving force, -${\Delta}$Gchem, for the tetragonal-to-mono-clinic phase transformation caused by the addition of MnO and $ Nb_2O_5$. The enhanced stability of the tetragonal phase in the Ce-TZP and Al2O3 composite (Ce-TZP/$Al_2O_3$) is believed to be caused by smaller grain size, moderate reduction in the chemical driving force and increase in the strain energy barrier to the transformation. Mechanical properties of the Ce-TZP and the Ce-TZP/$Al_2O_3$ with (i) the same grain size and (ii) the same Mb temperature were examined by measuring stress-strain behavior in 3 point bending. The Ce-TZP/$Al_2O_3$ composite doped with 1.3w% MnO (Ce-TZP/$Al_2O_3$/MnO), which had the same grain size as the Ce-TZP and De-TZP/$Al_2O_3$ showed more transformation plasticity than either the Ce-TZP or the Ce-TZP/$Al_2O_3$ composite. The Ce-TZP wihch had the same Mb temperature as that of the Ce-TZP/$Al_2O_3$/MnO did not show any transformation plasticity.

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액상환원침전법 및 수열반응법을 이용한 주석산화물 결정 합성에 관한 연구 (A study on the synthesis of tin oxide crystalline by the liquid reduction precipitation method and hydrothermal process)

  • 박일정;김건홍;김대원;최희락;정항철
    • 한국결정성장학회지
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    • 제26권3호
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    • pp.95-100
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    • 2016
  • 본 연구에서는 염화주석, 하이드라진 그리고 수산화나트륨을 원료로 하여 용액환원침전법과 수열반응법을 이용하여 주석산화물 결정을 제조하여, 주요 실험 변수에 의한 결정상 및 형상을 XRD와 SEM을 이용하여 분석하였다. 원료의 몰 비에 따라 구형 및 판상의 주석산화물 결정을 얻을 수 있었으며, 그 결정상은 SnO, $Sn_6O_4(OH)_4$이었다. 그리고 수열반응법에 의하여 얻어진 결정 모양은 온도 조건에 따라 판상 및 꽃 모양의 SnO 결정이 얻어졌다.

Reduction of viewing-angle dependent color shift in a reflective type cholesteric liquid crystal color filter

  • Jang, Won-Gun;Beom, Tae-Won;Cui, Hao;Park, Jong-Rak;Hwang, Seong-Jin;Lim, Young-Jin;Lee, Seung-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1656-1659
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    • 2008
  • The reflective type color filter for the liquid crystal displays (LCD) was produced using cholesteric liquid crystal monomers whose phase is characterized by the unique optical features of selective reflection. Periodic micrometer scale hemi-spherical photoresist (PR) patterns were formed on glass substrates by thermal reflow method after photolithography. Cholesteric color filter films for red, green and blue light reflections were then produced and the viewing angle dependence was investigated and compared with that of reflected light on the non-patterned substrates.

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주위조건 변화에 대한 증발 디젤분무 거동특성 연구 (Study on the Behavior Characteristics of the Evaporative Diesel Spray under Change in Ambient Conditions)

  • 염정국
    • 대한기계학회논문집B
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    • 제33권6호
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    • pp.454-460
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    • 2009
  • To analyze the mixture formation process of evaporating diesel spray is important for emissions reduction in actual engines. Then the effects of change in density of ambient gas on spray structure in high temperature and pressure field have been investigated in this study. The ambient gas density was changed from ${\rho}_a=5.0kg/m^3$ to ${\rho}_a=12.3kg/m^3$ with CVC(Constant Volume Chamber). Also, simulation study by modified KIVA-II code was conducted and compared with experimental results. The ambient temperature and injection pressure are kept as 700K and 72MPa, respectively. The images of liquid and vapor phase in the evaporating free spray were simultaneously taken by exciplex fluorescence method. As experimental results, with increasing ambient gas density, the tip penetration of the evaporating free spray decreases due to the increase in the drag force from ambient gas. The spatial structure of a diesel spray can be verified as 2-regions consisted of liquid with momentum decrease and vapor with large-scale vortex. The calculated results obtained by modified KIVA-II code show good agreements with experimental results.

Combination of ultrasonic assisted liquid phase exfoliation process and oxidation-deoxidation method to prepare large-sized graphene

  • Qi, Lei;Guo, Ruibin;Mo, Zunli;Wu, Qijun
    • Carbon letters
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    • 제25권
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    • pp.50-54
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    • 2018
  • Large-size graphene samples are successfully prepared by combining ultrosonic assisted liquid phase exfoliation process with oxidation-deoxidation method. Different from previous works, we used an ultrasound-treated expanded graphite as the raw material and prepared the graphene via a facile oxidation-reduction reaction. Results of X-ray diffraction and Raman spectroscopy confirm the crystal structure of the as-prepared graphene. Scanning electron microscopy images show that this kind of graphene has a large size (with a diameter over $100{\mu}m$), larger than the graphene from graphite powder and flake graphite prepared through single oxidation-deoxidation method. Transmission electron microscopy results also reveal the thin layers of the prepared graphene (number of layers ${\leq}3$). Furthermore, the importance of preprocessing the raw materials is also proven. Therefore, this method is an attractive way for preparing graphene with large size.

광합성 세균을 이용한 고농도 양돈슬러리의 무취화 관리방안에 관한 연구 (Deodorization Management of Swine-Slurry by Addition of Phototrophic Bacteria)

  • 이명규;권오중;정진영;태민호;허재숙
    • 한국축산시설환경학회지
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    • 제4권2호
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    • pp.137-147
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    • 1998
  • This study was carried out to find deodorization effect of swine-slurry by addition of phototrophic bacteria(PTB). The pilot-scale reactors operation conditions was designed by the inoculum amounts of PTB and light-conditions. Treatment conditions was divided into 3 types; 106 MPN/ml$.$Dark(T-1), 108 MPN/ml$.$Dark(T-2), 108 MPN/ml$.$Natural light(T-3). The changes of the concentration of volatile fatty acids(VFAs), hydrogen sulfide(H2S), ammonia (NH3) and odor intensity were analyzed during the treatment period(35 days). From results of this study, the maximum intensity of odor in the headspace of the reactor T-1 was 4.82 and T-2, T-3 was 2.63, respectively. In swine-slurry of reactors used, it almost took 10 days until to be stabilized with solid and liquid phase. Intensity of odor in headspace was mainly derived from the liquid phase. The PTB inoculum method to swine-slurry was very effective in reduction of VFAs, H2S and Sulfate-reducing bacteria(SRB) concentration. Expecially, It was interested in reverse growth behaviour of SRB and PTB in these conditions.

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Aspergllus oryza와 그 변이주의 연적배양에 의한 amylase 생성에 관한 연구 (Amylase Production by Continuous Cultures of Aspergillus oryzae and its Mutants)

  • Han, Hong-Eui
    • 미생물학회지
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    • 제15권2호
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    • pp.63-76
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    • 1977
  • Irradiation with high doses of gamma rays induced the reduction of mycelial weight and anaylase activity, and increased relative amylase activity in surface cultures. Biphase in growth curves was shown in aeration-agitation cultures but the behavior of the first phase of growth could be eliminated by replacing the amylasehydrolysed starch substrates, so that enzyme production was shortened ca. 40 hours and relative amylase activity was increased about 3 times higher before onset of autolysis. In the effect of gibberellin on amylase production, the positive stimulation was appeared to only surface culturs of the liquid medium and the negative effect to shake-cultures in a mutant. Trials of various continuous culture were resulted not only the approalch to the value of amylase activity in surface cultures of liquid medium, but also higher productivity than in batch cultures. The culture-degeneration was observed in two-stage continuous culture, but did not appear in continuous elevation culture.

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Group Contribution Method for Group Contribution Method for Estimation of Vapor Liquid Equilibria in Polymer Solutions

  • Oh, Suk-Yung;Bae, Young-Chan
    • Macromolecular Research
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    • 제17권11호
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    • pp.829-841
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    • 2009
  • This study introduces a specified group-contribution method for predicting the phase equilibria in polymer solutions. The method is based on a modified double lattice model developed previously. The proposed model includes a combinatorial energy contribution that is responsible for the revised Flory-Huggins entropy of mixing, the van der Waals energy contribution from dispersion, a polar force and specific energy contribution. Using the group-interaction parameters obtained from data reduction, the solvent activities for a large variety of mixtures of polymers and solvents over a wide range of temperatures can be predicted with good accuracy. This method is simple but provides improved predictions compared to those of the other group contribution methods.