• Title/Summary/Keyword: Liquid-phase reduction

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Effect of $TO_3$ and $NO_2$ on Net Photosynthesis, Transpiration and Accumulation of Nitrite in Sunflower Leaves

  • Park, Shin-Young;Lee, Sang-Chul
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.3 no.2
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    • pp.121-129
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    • 1999
  • Photosynthesis and transpiration rates were simultaneously measured in attached sunflower leaves(Helianthus annuusL. cv. Russian Mammoth) during exposure to $NO_2$ and $O_3$ to determine the effect of mixed gan on photosynthesis and the stomatal aperture. The application of $O_3$ alone reduced both the net photosynthetic and transpiration rates. An analysis of the $CO_2$ diffusive resistances indicated that the main cause affecting photosynthesis reduction during $O_3$ exposure was not the internal gas phase of the leaf $(rCO_2^{liq})$ but rather the liquid phase or mesophyll diffusive resistance $(rCO_2^{liq})$, suggesting that there is a very concomitant relation between photosynthetic reduction and $rCO_2^{liq}$. The application of NO2 alone caused a marked reduction of the net photosynthesis yet no significant reduction of transpiration, indicating that NO2 affects the $CO_2$ fixation processes with no inluence on the stomatal aperture. A greter reduction in the photosynthesis of sunflower plants was caused by the application of $NO_2$ alone as compared to a combination of $NO_2$ and $O_3$. $NO_2$ alone reduced the photosynthetic rate by 90%, whereas a mixture of NO2 and O3 reduced it by 50%.

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The Formulation of Semi-Transparent Gel Emulsion by the Liquid Crystal Emulsification Method

  • Kim, Jungil;Lee, Youngkeun;Kim, Yongmin;Yun, Seiyoung
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.4
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    • pp.1478-1486
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    • 2018
  • Liquid crystals offer plenty of useful activities as improving the stability of emulsion, increasing moisturizing power, drug release, improving skin feeling and visual effect for cosmetics fields. In order to prepare stable semi-transparent gel emulsion, liquid crystal emulsification method was used. The emulsion stabilities of systems containing glycerin, fatty alcohols, surfactants, water and oil were investigated at various temperatures as time passed. The stabilities of all emulsions were evaluated by means of a polarizing microscope, SEM, rheometer, colorimeter and DSC. Even though the samples stored at $50^{\circ}C$ thermostatic chamber were occurred the reduction of hardness, turbidity and ${\Delta}H$ and the peak shift, the semi-transparent gel emulsion was very stable without separation between water and oils phase in emulsion.

A STUDY ON THE LYOTROPIC LIQUID CRYSTALLINE COPOLYAMIDE

  • Lee, Chul-Joo;Min, Byoung-Gill;Son, Tea-Won;Yoon, Han-Sik
    • Proceedings of the Korean Fiber Society Conference
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    • 1987.06b
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    • pp.12-12
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    • 1987
  • To improve the fibrillation phenomenon and processibili to of poly(p-phenyleneterephthalamide) (PPD-T) , a P/E copolyamide was prepared by introducing 4,4'-ethylene dianiline (EDA) into rigid chain backbone. The effects of semi-flexible segment on the liquid crystalline properties were investigated. The EDA, used as a comonomer, was prepared by catalylitic reduction of p,p'-dinitrophenyl , obtained by oxidative coupling of p,p'-dinitrotoluene. Various high molecular weight PIE copolyamides were prepared by low temperature solution polycondensation of terephthaloyl chloride (TPC) with various mixtures of p-phenylene diamine (PPD) and EOA. The PfE copolyamides were completely dissolved in 100% svlfuric acid, and the phase transition of P/E copolyamide-sulfuric acid systems was examined in teams of concentration and temperature. Over the chemical compositions, PIE=911, 812, and 713, solutions of anisotropic single phase were acquired. In particular, the two mixing ratios, 911 and 812, gave a good anisotropic spinning dope.

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Elaboration of (Steel/Cemented Carbide) Multimaterial by Powder Metallurgy

  • Pascal, Celine;Chaix, Jean-Marc;Dutt, Ankur;Lay, Sabine;Allibert, Colette H.
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.291-292
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    • 2006
  • A steel/cemented carbide couple is selected to generate a tough/hard two layers material. Sintering temperature and composition are deduced from phase equilibria, and experimental studies are used to determine optimal conditions. Liquid migration from the hard layer to the tough one is observed. Microstructure evolution during sintering of the tough material (TEM, SEM, image analysis) evidences coupled mechanisms of pore reduction and WC dissolution. Liquid migration, as well as interface crack formation due to differential densification are limited by suitable temperature and time conditions.

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Size and Dispersion Characteristics of Silver Nanoparticles Prepared Using Liquid Phase Reduction Method (액상환원법으로 제조한 은 나노입자의 크기와 분산특성)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.5
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    • pp.10-16
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    • 2016
  • This work investigates the size and dispersion characteristics of silver nanoparticles synthesized by a liquid phase reduction method using PAA. The experimental variables were the molecular weight and doses of the PAA, reducing agent, dispersant, and organic solvent (ethanol-acetone). UV-visible spectrophotometer results confirm the formation of the silver particles, and SEM indicates size in the nanometer range. As the ultrasonication time increases, there is a tendency toward smaller agglomerates of nanoparticles. The agglomerates were dispersed into 1-5 agglomerates of particles by ultrasonication for 3 hours or more. Relatively spherical nanoparticles were produced with a completely homogeneous dispersion and size of 49.56-85.75 nm by ultrasonication using BYK-192, a dispersant containing copolymer with a pigment affinic group. The average size of the silver nanoparticles was increased to 36.82, 50.66, and 56.06 nm with increasing molecular weight of PAA. Also, the size of the nanoparticles increased with the capping of PAA on the surfaces of the nanoparticles when increasing the amount of PAA. The addition of hydrazine as a reducing agent produced relatively small particles because many nuclei were created by the reduction reaction. The ethanol-acetone solvent helped with the regular arrangement of the silver nanoparticles.

Development of an external twin-fluid nozzle for Selective Catalytic Reduction (선택적 촉매 환원법을 위한 외부 혼합형 이유체 노즐 개발에 대한 실험적 연구)

  • Park, J.K.;Lee, C.W.
    • Journal of ILASS-Korea
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    • v.9 no.2
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    • pp.24-33
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    • 2004
  • The effect of the working fluid flow conditions and nozzle geometry on the spray performance of a twin-fluid nozzle used in Selective Catalytic Reduction is investigated experimentally. The liquid pressure is varied in the range of 0.3atm to 1.5atm and the air pressure is varied from the 0.5atm to 3.0atm. relative position between liquid nozzle(internal nozzle) and air nozzle(external nozzle) tip changes front 1mm inside the air nozzle to 1mm outside the air nozzle. The orifice diameter of the air nozzle is varied with 5mm. 6mm and 7mm. Spray visualization is realized with CCD-Camera. SMD(Sauter Mean Diameter) and mean particle velocities are measured by PDPA(Phase Doppler Particle Analyzer) under various experimental conditions. The measuring point is 300mm away from the nozzle tip in the downstream spray. The experimental results are that spray angle is depended air flow rate because nozzle diameter, air pressure and nozzle tip relative positions are related air flow rate. SMD is depended air flow rate and water flow rate. Also, SMD is increased when water flow rate is bigger. SMD is decreased when Air flow rate is bigger.

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A NUMERICAL STUDY ON FLOWS IN A FUEL TANK WITH BAFFLES AND POROUS MEDIA TO REDUCE SLOSHING NOISE (연료탱크 슬로싱 소음 저감을 위한 배플 및 다공성 물질 설치에 따른 유동해석 연구)

  • Lee, Sang-Hyuk;Hur, Nahm-Keon
    • Journal of computational fluids engineering
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    • v.14 no.2
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    • pp.68-76
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    • 2009
  • The sloshing tank causes the instability of the fluid flows and the fluctuation of the impact pressure by the liquid on the tank. These flow characteristics inside the sloshing tank can generate the uncomfortable sloshing noise. In the present study, a numerical analysis for the reduction of a fuel tank sloshing noise was performed. To simulate the flow characteristics in a sloshing tank with partially filled liquid, a VOF method was used for interfacial flows by applying a momentum source term for the sloshing motion in a non-inertial reference frame. This numerical method was verified by comparing its results with the available experimental data. For the reduction of the sloshing noise, the horizontal and vertical baffles and porous media inside a sloshing tank were considered and numerically analyzed in the present study. For various installations of these baffles and porous media, the characteristics of the liquid behavior in the sloshing tank were obtained along with the impact pressure on the wall and the height of the free surface along the wall. These basic results can be used for the design of the actual vehicular fuel tank with the reduced sloshing noise.

Effects of the Liquid Manure Circulation System on the Environmental Improvement of Swine Farm (액비순환시스템의 양돈농장 환경개선 효과)

  • Ha, Duck-Min;Kim, Doo-Hwan
    • Journal of Environmental Science International
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    • v.28 no.1
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    • pp.137-145
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    • 2019
  • The purpose of this study was to evaluate the effect of implementing a Liquid Manure Circulation System (LMCS) on the environmental improvement of swine farms. Bacterial counts at different circulation phases of the LMCS were measured. Air in the swine facility and the liquid manure in each step of LMCS were sampled and gaseous composition detected in swine farms both with and without LMCS to compare the environmental conditions in either case. There were no differences in the total bacteria count at any circulation phase in the LMCS. Escherichia coli were detected at a very low abundance only at the outlet of the slurry pit ($1.5{\times}10^2CFU/m{\ell}$). Salmonella were not detected at any phase. The LMCS clearly affected the odor strength of the swine farm and improved the air quality in the swine facility. On-site odor strength - inside, at the exhaust, and at the border of the swine facility - were clearly lowered in farms applying LMCS. Furthermore, the levels of ammonia, hydrogen sulfide, and carbon dioxide were improved in swine facilities applying LMCS.

A Study on the Regeneration Energy Reduction through the Process Improvement of the Carbon Dioxide Capture Process (상전이 현상을 이용한 이산화탄소 포집공정개선 및 재생에너지 절감에 대한 연구)

  • Kim, Yu-Mi;Kim, Dong-Sun;Cho, Jung-Ho
    • Clean Technology
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    • v.18 no.2
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    • pp.221-225
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    • 2012
  • In this study, simulation works for a carbon dioxide capture process using solvent absorption method have been performed for decrease of regeneration energy in applying phase transition of liquid solvent. When carbon dioxide is dissolved in 30 wt% MEA solvent, liquid mixture divided into two phase according to mole loading of dissolved carbon dioxide. Using this phenomenon, we can decrease regeneration energy about 61% than primary absorber column-stripper column process.

Effects of Extracellular Electron Shuttles on Microbial Iron Reduction and Heavy Metals Release from Contaminated Soils

  • Hwang, Yun Ho;Shim, Moo Joon;Oh, Du Hyun;Yang, Jung-Seok;Kwon, Man Jae
    • Journal of Soil and Groundwater Environment
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    • v.19 no.2
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    • pp.16-24
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    • 2014
  • To test the potential effects of extracellular electron shuttles (EES) on the rate and extent of heavy metal release from contaminated soils during microbial iron reduction, we created anaerobic batch systems with anthraquinone-2,6-disulfonate (AQDS) as a surrogate of EES, and with contaminated soils as mixed iron (hydr)oxides and microbial sources. Two types of soils were tested: Zn-contaminated soil A and As/Pb-contaminated soil B. In soil A, the rate of iron reduction was fastest in the presence of AQDS and > 3500 mg/L of total Fe(II) was produced within 2 d. This suggests that indigenous microorganisms can utilize AQDS as EES to stimulate iron reduction. In the incubations with soil B, the rate and extent of iron reduction did not increase in the presence of AQDS likely because of the low pH (< 5.5). In addition, less than 2000 mg/L of total Fe(II) was produced in soil B within 52 d suggesting that iron reduction by subsurface microorganisms in soil B was not as effective as that in soil A. Relatively high amount of As (~500 mg/L) was released to the aqueous phase during microbial iron reduction in soil B. The release of As might be due to the reduction of As-associated iron (hydr)oxides and/or direct enzymatic reduction of As(V) to As(III) by As-reducing microorganisms. However, given that Pb in liquid phase was < 0.3 mg/L for the entire experiment, the microbial reduction As(V) to As(III) by As-reducing microorganisms has most likely occurred in this system. This study suggests that heavy metal release from contaminated soils can be strongly controlled by subsurface microorganisms, soil pH, presence of EES, and/or nature of heavy metals.