• 제목/요약/키워드: Liquid-phase reduction

검색결과 172건 처리시간 0.027초

$CO_2$해양처리를 위한 액적 거동 시뮬레이션 기초연구 (Numerical Study of a Droplet Movement for the Ocean $CO_2$ Sequestration)

  • 정노택;강성길
    • 한국해양환경ㆍ에너지학회지
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    • 제8권1호
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    • pp.39-45
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    • 2005
  • 2004년 11월 러시아의 교토의정서 비준에 의하여 2005년 2월에 교토의정서의 발효를 앞두고 있다. 따라서 1차 감축대상국은 2008년부터 2012년까지 1990년 대비 각 국가당 설정된 GHG(Green House Gas)배출량을 감축해야하는 상황에 처해 있다. 본 논문에서는 대기 중에 뿜어내는 GHG중 가장 많은 비율을 차지하는 CO₂를 심해에 친환경적으로 처리하는 기술로서 해양격리기술에 대해 소개한다. 본 해양격리기술은 4개의 주요단계로 구분할 수 있는데, 해양수송기술, 해양분사기술, 해양저장효율평가기술, 해양처리생태영향 평가기술등으로 나눌 수 있다. 본 논문에서는 CO₂의 해양 분출시에 초기희석율에 영향을 미치는 해양분사기술 중, 액포의 거동과 용해에 관한 기초 연구를 수행하였다. 특히 본 연구에서는 전산유체역학 기법 (Computational Fluid Dynamics)을 통해 해수를 연속상(Continuous phase), 액적을 분산상(Disperse phase)으로 한 이상(Two-phase) 유체를 3차원 이동형 비구조 격자와 유한체적법을 이용하여 상 경계면이 거동하면서 거동에 따른 용해도의 변화를 추정하였다 따라서, 본 연구는 액적의 거동과 용해도의 유체역학적 관계를 밝히는 데 기초적 자료가 될 것으로 판단된다.

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Electrochemical Behavior of Li-B Alloy Anode - Liquid Cadmium Cathode (LCC) System for Electrodeposition of Nd in LiCl-KCl

  • Kim, Gha-Young;Shin, Jiseon;Kim, Tack-Jin;Shin, Jung-Sik;Paek, Seungwoo
    • 전기화학회지
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    • 제18권3호
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    • pp.102-106
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    • 2015
  • The performance of Li-B alloy as anode for molten salt electrolysis was firstly investigated. The crystalline phase of the prepared Li-B alloy was identified as $Li_7B_6$. The potential profile of Li-B alloy anode was monitored during the electrodeposition of $Nd^{3+}$ onto an LCC (liquid cadmium cathode) in molten LiCl-KCl salt at $500^{\circ}C$. The potential of Li-B alloy was increased from -2.0 V to -1.4 V vs. Ag/AgCl by increasing the applied current from 10 to $50mA{\cdot}cm^{-2}$. It was found that not only the anodic dissolution of Li to $Li^+$ but also the dissolution of the atomic lithium ($Li^0$) into the LiCl-KCl eutectic salt was observed, following the concomitant reduction of $Nd^{3+}$ by the $Li^0$ in Li-B alloy. It was expected that the direct reduction could be restrained by maintaining the anode potential higher that the deposition potential of neodymium.

기-액 복합 광반응기에서의 악취성 암모니아 제거를 위한 촉매개발과 반응시스템의 최적조건 색출 연구 (The Studies of Photocatalyst Development and the Optimum Operation Conditions for the Removal of Ammonia in a Mixed Reactor of Liquid-vapor Phase)

  • 김해리;전민규;김준우;주광태;정석진
    • 한국대기환경학회지
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    • 제24권5호
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    • pp.512-522
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    • 2008
  • Ammonia is a major compound of odor in livestock house. To enhance the performance of ammonia oxidation (decomposition). the gas-liquid, two phase photocatalytic oxidation system was designed and prepared in this study. Commercial P-25 as $TiO_2$ catalyst was used for ammonia decomposition. V/P-25 catalyst prepared by sol gel method was also used for the removal of by-producted $NO_x$ in $NH_3$ oxidation reaction. When $TiO_2$ was used as a photocatalyst, the conversion to $N_2$ in ammonia decomposition reached above 90% until 200hr (The air flow rate of 4L/min with the ammonia concentration up to 25ppm.). However, considerable amounts of NO and $NO_2$ were formed as a result of $NH_3$ oxidation (as a by-product). Therefore, we added Vanadia impregnated $TiO_2$(P-25) catalyst for the removal of $NO_x$ at the end of reaction trail. The results of a pilot-scale operation were successful to achieve the simultaneous removal of $NH_3\;and\;NO_x$ about 81 and 87%, respectively.

액상소결법에 의한 탄화규소 제조시 소결조제와 온도의 영향 (Influence of Sintering Additives and Temperature on Fabrication of LPS-SiC)

  • 정헌채;윤한기
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.266-270
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    • 2004
  • SiC materials have been extensively studied for high temperature components in advanced energy system and advanced gas turbine because it has excellent high temperature strength, low coefficient of thermal expansion, good resistance to oxidation and good thermal and chemical stability etc. However, the brittle characteristics of SiC such as low fracture toughness and low strain-to fracture still impose a severe limitation on practical applications of SiC materials. For these reasons, SiC/SiC composites can be considered as a promising for various structural materials, because of their good fracture toughness compared with monolithic SiC ceramics. But, high temperature and pressure lead to the degradation of the reinforcing jiber during the hot pressing. Therefore, reduction of sintering temperature and pressure is key requirements for the fabrication of SiC/SiC composites by hot pressing method. In the present work, monolithic Liquid Phase Sintered SiC (LPS-SiC) was fabricated by hot pressing method in Ar atmosphere at $1800^{\circ}C$ under 20MPa using $Al_2O_3,\;Y_2O_3\;and\;SiO_2$ as sintering additives in order to low sintering temperature and sintering pressure. The starting powder was high purity $\beta-SiC$ nano-powder with all average particle size of 30mm. The characterization of LPS-SiC was investigated by means of SEM and three point bending test. Base on the composition of sintering additives-, microstructure- and mechanical property correlation, tire compositions of sintering additives are discussed.

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고압 인젝터의 노즐 홀 수가 DME 연료분무의 미립화 특성에 미치는 영향 (Effect of Nozzle Hole Number on Atomization Characteristics of DME Fuel Spray using High Pressure Injector)

  • 이종태;이상훈;전문수
    • 한국분무공학회지
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    • 제19권4호
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    • pp.216-220
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    • 2014
  • This paper presents effect of nozzle hole number on atomization characteristic of DME fuel spray using three different type of injector having the hole number of 6, 7 and 8. For this study, PDPA(phase Doppler particle analyzer) experiment was performed in terms of $T_{ASOE}$ under various injection pressure. To compare general trend of atomization characteristic, the law data were ensemble averaged based on $T_{eng}$ of 0.2 ms. Results showed that the droplet diameter in terms of SMD(Sauter Mean Diameter) was reduced as increase in injection pressure. Increasing the number of hole lead to reduce in droplet diameter, but no significant reduction in diameter was observed between hole number of 7 and that of 8. In addition, increasing the number of hole resulted in decrease in droplet velocity which is considered as the effect of reduction in spray momentum due to decreasing of fuel quantity per each hole.

판형 및 다공형 배플을 포함한 탱크 내 슬로싱에 대한 유동해석 (A NUMERICAL ANALYSIS OF THE SLOSHING IN A TANK WITH PLATE/POROUS BAFFLES)

  • 이상혁;허남건
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2009년 춘계학술대회논문집
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    • pp.215-222
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    • 2009
  • In the present study, a numerical analysis on the sloshing in a tank with the harmonic motion was investigated. A VOF method was used for two-phase flows inside the sloshing tank and a source term of the momentum equation was applied for the harmonic motion. This numerical method was verified by comparing its results with the available experimental data. The sloshing in a tank causes the instability of the fluid flows and the fluctuation of the impact pressure on the tank. By these phenomena of the tank sloshing, the sloshing problems such as the failure and the noise of system can be generated. For the reduction of these sloshing problems, the various baffles such as the horizontal/vertical plate baffles and the porous baffles inside the tank are installed. With the installations of these baffles, the characteristics of the liquid behavior in the sloshing tank, the impact pressure on the wall, the amplitude of the free surface near the wall and the sloshing noise were numerically analyzed.

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디젤엔진 배출가스의 질소산화물 저감을 위한 Solid SCR용 가스분사 시스템의 전산유체해석 연구 (CFD Analysis on Gas Injection System of Solid SCR for NOx Reduction of Exhaust Emissions in Diesel Engine)

  • 이호열;윤천석;김홍석
    • 한국자동차공학회논문집
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    • 제22권5호
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    • pp.73-83
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    • 2014
  • CFD(computational fluid dynamics) model is developed to simulate direct injection of ammonia gas phase from ammonia transporting materials into the SCR catalyst in the exhaust pipe of the engine with solid SCR. Configurations of one-hole and four-hole nozzle, circumferential type, porous tube type, and the effect of mixer configurations which commonly used in liquid injection of AdBlue are considered for complex geometries. Mal-distribution index related to concentration of ammonia gas, flow uniformity index related to velocity distribution, and pressure drop related to flow resistance are compared for different configurations of complex geometries at the front section of SCR catalyst. These results are used to design the injection system of ammonia gas phase for solid SCR of target vehicle.

$SF_6$ 하이드레이트 결정의 성장 특성에 대한 연구 (Crystal growth studies of $SF_6$ clathrate hydrate)

  • 이윤석;이주동;이보람;이현주;이은경;김수민;김영석;윤석영;김양도
    • 한국결정성장학회지
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    • 제19권5호
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    • pp.228-236
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    • 2009
  • 본 연구에서는 $SF_6$ 가스 포접 하이드레이트 결정이 생성되고 성장하는 메커니즘의 특성을 기술하였다. 실험은 일정한 압력과 온도에서 2상 실험($SF_6$ 기상/수용액상)과 3상 실험($SF_6$ 기상/수용액상/$SF_6$ 액상)의 서로 다른 두 가지 상 조건에서 이루어졌다. 두 조건 모두 기체 영역과 수용액 영역 사이의 경계면에서 하이드레이트 결정의 수지상이 섬유상 형태로 상향 성장하는 거동을 보였다. 3상 실험의 경우 하이드레이트 생성이 진행됨에 따라, 반응기 내부압의 감소로$SF_6$ 액상에서 생성된 기포가 기체와 수용액 계면의 막에 도달하여 기포의 표면이 하이드레이트로 전환되었다. 본 논문에서는 결정의 핵생성과 이동, 성장, 간섭을 중심으로 $SF_6$ 가스하이드레이트 결정의 성장 특성을 기술하였다.

LPE에 의한 GaInAs/InP PIN Photodiode의 제작 및 특성 (A Fabrication and Characteristics of GaInAs/InP PIN Phtodiode Grown by LPE)

  • 박찬용;남은수;박경현;김상배;박문수;이용탁;홍창희
    • 대한전자공학회논문지
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    • 제27권5호
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    • pp.737-746
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    • 1990
  • Ga0.47In0.53As PIN photodiodes(PD) having various areas have been fabricated by liquid phase epitaxial techniques. Ternary melt has been baked out at 675\ulcorner in H2 atmosphere for 20 hours before growth, which resulted in reduction of background carrier concentration of grown epi-layer. Also, lattice mismatch has been controlled within 0.01%. The room temperature performance of 10**-4cm\ulcornerarea PIN PD at a bias voltage of -5V were` quantum efficiency(with no antireflection coating)=60% for 1.3\ulcorner light source, dark current\ulcorner5nA, and capacitance\ulcornerpE. Frequency response measurement of packaged PIN PD has shown that cut-off frequency (f-3dB) was 961MHz. This PD has shown a good eye pattern when it was incorporated in a 565Mbps optical receiver.

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초공동 수중운동체 주위 공동 특성과 추력 전산 해석 (Numerical Analysis of Cavity Characteristics and Thrust for Supercavitating Underwater Vehicle)

  • 김동현;박원규
    • 한국해양공학회지
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    • 제31권1호
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    • pp.8-13
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    • 2017
  • Cavitation is used in various fields. This study examined the drag reduction of an underwater vehicle using cavitation. In this study, the natural partial cavitation analysis results were verified using CFD code with the Navier-Stokes equation based on a mixture model. The momentum and continuity equations in the mixture phase were separately solved in the liquid and vapor phases. The solver employs an implicit preconditioning algorithm in curvilinear coordinates. The results of a computational analysis showed good agreement with the experiment. A computational analysis was also performed on the supercavity. The study investigated the cavity characteristics and drag of an underwater vehicle and studied the speed required to achieve a supercavity. Finally, a 1DOF analysis was carried out to investigate the thrust system for a supercavity. As a result, one of the methods for determining a suitable thrust system for a supercavitating underwater vehicle was presented.