• Title/Summary/Keyword: Liquid water

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Tritium radioactivity estimation in cement mortar by heat-extraction and liquid scintillation counting

  • Kang, Ki Joon;Bae, Jun Woo;Kim, Hee Reyoung
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3798-3807
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    • 2021
  • Tritium extraction from radioactively contaminated cement mortar samples was performed using heating and liquid scintillation counting methods. Tritiated water molecules (HTO) can be present in contaminated water along with water molecules (H2O). Water is one of the primary constituents of cement mortar dough. Therefore, if tritium is present in cement mortar, the buildings and structures using this cement mortar would be contaminated by tritium. The radioactivity level of the materials in the environment exposed to tritium contamination should be determined for their disposal in accordance with the criteria of low-level radioactive waste disposal facility. For our experiments, the cement mortar samples were heated at different temperature conditions using a high-temperature combustion furnace, and the extracted tritium was collected into a 0.1 M nitric acid solution, which was then mixed with a liquid scintillator to be analyzed in a liquid scintillation counter (LSC). The tritium extraction rate from the cement mortar sample was calculated to be 90.91% and 98.54% corresponding to 9 h of heating at temperatures of 200 ℃ and 400 ℃, respectively. The tritium extraction rate was close to 100% at 400 ℃, although the bulk of cement mortar sample was contaminated by tritium.

A Study on the Design of a Liquid Droplet Discharge System Using a Water Level Sensor (수위센서를 이용한 액적 토출 시스템 설계에 관한 연구)

  • Yun-Min Lee;Jin-Seob Shin
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.24 no.4
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    • pp.129-134
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    • 2024
  • In this paper, This paper is a liquid droplet discharge system using a water level sensor that can linearly detect changes in water level through experiments with an infrared sensor, a laser sensor, an ultrasonic sensor, and a capacitance sensor. SMPS, regulator 5V, and LDO 3.3V were designed for power supply. A water level sensor input ADC circuit and microprocessor were used. Solenoid valve control, pump output control unit for positive/negative pressure generation, CAN, Ethernet, UART communication, and USB for industrial communication were used. The change in pressure was confirmed through the change in water level, the change in pressure was minimized, and a system for discharging liquid droplets was implemented.

Minimizing Nutrient Loading from SCB Treated Paddy Rice Fields through Water Management (SCB 액비 시용 논에서 물관리를 통한 양분의 수계 부하 최소화 방안)

  • Kim, Min-Kyeong;Kwon, Soon-Ik;Kang, Seong-Soo;Jung, Goo-Bok;Hong, Seung-Chang;Chae, Mi-Jin;So, Kyu-Ho
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.671-675
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    • 2012
  • This study was conducted to establish the BMPs (Best Management Practices) for preventing pollutant loadings from paddy rice field applied livestock liquid manure from 2008 through 2011. Cultivated paddy rice fields (Gyeonggi province, Korea) were treated with SCB (Slurry composting and bio-filtration process) liquid fertilizer. The BMPs for paddy rice field developed in this study includes: 1) the controlling a drainage water gate in paddy rice field from right after SCB liquid fertilizer application to 3 weeks after rice transplanting; 2) livestock liquid fertilizer application to paddy rice soils in 20 days before rice transplanting to encourage the utilization of liquid fertilizer; 3) preservation of surface water depth to 5 cm in a paddy field right after SCB liquid fertilizer applied to minimize a water pollution and enhance the utilization of liquid fertilizer; and 4) blocking a water gate at least for 2 days to inactivate E. coli survival. The findings of this study will provide useful and practical guideline to applicators of agricultural soil in deciding appropriate handling and time frames for preventing pollution of water quality for sustainable agriculture.

Effects of Structural Difference of Ionic Liquids on the Catalysis of Horseradish Peroxidase

  • Hong, Eun-Sik;Park, Jung-Hee;Yoo, Ik-Keun;Ryu, Keun-Garp
    • Journal of Microbiology and Biotechnology
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    • v.19 no.7
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    • pp.713-717
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    • 2009
  • The dependence of the catalytic properties of horseradish peroxidase on the structural changes of ionic liquids was investigated with two water-miscible ionic liquids, N-butyl-3methypyridinium tetraftuoroborate ([$BMP_y$][$BF_4$]) and 1-butyl-3-methylimidazolium methylsulfate ([BMIM][$MeSO_4$]), each of which shares an anion ($BF_4^-$) or a cation ($BMIM^+$) with 1-butyl-3-methylimidazolium tetraftuoroborate ([BMIM][$BF_4$]), respectively. The oxidation of guaiacol (2-methoxyphenol) with $H_2O_2$was used as a model reaction. In order to minimize the effect of solution viscosity on the kinetic constants of the enzymatic catalysis, the enzymatic reactions for the kinetic study were performed in water-ionic liquid mixtures containing 25% (v/v) ionic liquid at maximum. Similarly to the previously reported results for [BMIM][$BF_4$], as the concentration of [$BMP_y$][$BF_4$] increased, the $K_m$value increased with a decrease in the $k_{cat}$value: the $K_m$value increased markedly from 2.8 mM in 100% water to 12.6 mM in 25% (v/v) ionic liquid, indicating that ionic liquid significantly weakens the binding affinity of guaiacol to the enzyme. On the contrary, [BMIM][$MeSO_4$] decreased the Km value to 1.4 mM in 25% (v/v) ionic liquid. [BMIM][$MeSO_4$] also decreased $k_{cat}$more than 3-folds [from 13.8 $s^{-1}$in 100% water to 4.1 $s^{-1}$in 25% (v/v) ionic liquid]. These results indicate that the ionic liquids interact with the enzyme at the molecular level as well as at a macroscopic thermodynamic scale. Specifically, the anionic component of the ionic liquids influenced the catalysis of horseradish peroxidase in different ways.

Extinguishment of Liquid Fuel Fire by Water Mist Containing Additives

  • Park, Jae-Man;Won, Jung-Il;Shin, Chang-Sub
    • International Journal of Safety
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    • v.4 no.2
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    • pp.24-29
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    • 2005
  • An experimental study was presented for extinguishing characteristics of liquid fuel fire by water mist($Dv_{0.99}{\leq}200{\mu}m$) containing potassium acetate and sodium acetate trihydrate. To evaluate the extinguishing performance of water mist containing additives, the evaporation characteristics of a water droplet on a heated surface was examined. The evaporation process was recorded by a charge-coupled-device camera. Also, small-scale extinguishing tests were conducted for n-heptane pool fire in ventilated space. During the experiments, flame temperatures were measured, and concentrations of oxygen and carbon monoxide were analyzed by a combustion gas analyzer. The average evaporation rate of water droplet containing additives was lower than that of pure water at a given surface temperature and decreased with the concentration increase due to the precipitation of salt in the liquid-film and change of surface tension. In case of using additives, the fire extinguishing times was shorter than that of pure water at a given discharge pressure and it was because the momentum of a water droplet containing additives was increased. And also dissociated metal atoms, potassium or sodium, were reacted as a scavenger of the major radical species OH, H which were generated for combustion process. Moreover, at a high pressure of 4 MPa, the fire was extinguished through blowing effect as well as primary extinguishing mechanisms.

Characteristics of Precipitable Water Vapor and Liquid Water Path by Microwave Radiometer (마이크로웨이브 라디오미터에서 관측된 가강수량 및 구름물량 특성 분석)

  • Yang, Ha-Young;Chang, Ki-Ho;Cha, Joo-Wan;Choi, Young-Jean;Ryu, Chan-Soo
    • Journal of the Korean earth science society
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    • v.33 no.3
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    • pp.233-241
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    • 2012
  • Based on the observation of the microwave radiometers at Cheongju, Hapcheon and Daegwallyeong in Korea, the precipitable water vapor and liquid water path have been analyzed for spatio-temporal characteristics. The observed datas have been validated by comparing precipitable water vapor between the microwave radiometer and the radiosonde near the sites. It resulted in the correlation coefficient of more than 0.8 in all three sites. For three regions, the precipitable water vapor shows similar seasonal variation and diurnal cycle, and that amount of precipitable water vapor increases from around 1000 LST and has a maximum value at 1900 LST. On the other hand, the liquid water path of microwave radiometer has regional differences for its seasonal variation, which seems to be caused by the geographical characteristics including the frequent fog and clouds in Daegwallyeong, a high mountain region (834 m from sea level), almost flat land in Chengju, and Sobaek Mountains in Hapcheon that blocks the westerly clouds.

The Distributions of Liquid Water Content(LWC) and the Potential Enhancement of Precipitation over Andong Area observed from Microwave Radiometer (Microwave radiometer를 이용한 안동지역의 수액량 및 증우가능량 추정)

  • 정관영;김효경;이선기;정영선
    • Korean Journal of Remote Sensing
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    • v.14 no.2
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    • pp.165-174
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    • 1998
  • The observation of liquid water content(LWC) and the estimation of precipitation enhancement by cloud seeding were made over the Andong in Korea from March 1997 through Feb 1998. A dual-channel microwave radiometer was used to measure the liquid water content and water vapor. It was shown that the 90% of observational period had the amount of less than 0.1 mm in LWC, and that the amount of precipitation was proportionally increased to liquid water content. The amount of LWC has maximum in summer and minimum in winter. The content of liquid cloud water was showed higher value from the time of 12 to the time of 17 except for summer season in which it extremely fluctuated with a large precipitation. The majority of liquid water content over the area occurred with westerly and southwesterly wind which were flowed from the Sobaek mountain. The ratio of horizontal LWC flux and vertical precipitation flux, $P_{en}$ is almost ranked in the interval of 0.0~0.5 with maximum of 0.5 in spring, 0.2 in summer and fall, and 0.1 in winter. Accordingly, it is estimated that the potential enhancement of precipitation over Andong area by cloud seeding has high value in spring with westerly wind.

Detection of tropospheric water vapor and liquid water density by using Raman lidar technique (라만Lidar기술을 이용한 대류권 수증기와 물방울 입자의 밀도 측정)

  • 김덕현;차형기;이종민;최성철;김영상
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.150-151
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    • 2000
  • 대기 중에 존재하는 수증기(water vapor)와 물방울 입자(liquid water)는 대기의 열 순환 과정에서 이산화탄소와 함께 매우 중요한 역할을 하는 중요한 변수이다. 대류권의 수증기 밀도를 라만 라이다 기술을 이용하여 원격으로 측정하려는 시도는 오래 전부터 있었으나, 물방울 입자의 밀도 측정은 최근에 연구가 시작되었으며, 특히 수증기의 밀도 측정에서 물방울 입자의 라만 신호가 심각한 오차요인으로 알려지면서 이에 대한 연구가 구체적으로 진행되었다.[1-2] 라만 라이다 연구는 대기 중에서 비교적 흡수가 적고 산란단면적이 큰 레이저 광원의 선택이 매우 중요하다. (중략)

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Transport of Phenol in Waste Water Through Liquid Surfactant Membrane (폐수중 액체막에 의한 페놀의 이동)

  • 우인성;김병석;김윤선
    • Journal of the Korean Society of Safety
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    • v.5 no.3
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    • pp.39-43
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    • 1990
  • The transport of phenol from waste water through the liquid surfactant membrane containing Aliquat 336 as a carrier was analyzed by a theoretical model. Extraction experiments was carried out to investigate the effect of process parameters, such as mixing intensity, concentration of sodium hydroxide in internal aqueous solution, and counter anions, and initial phenol concentration in waste water at $25^{\circ}C$. It was found that transport rate of phenol increased with increasing pH differents. The transport rate of phenol in waste water was influenced by counter anions.

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The Anomalies of Supercooled Water

  • Yoon, Byoung-Jip;Jhon, Mu-Shik
    • Bulletin of the Korean Chemical Society
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    • v.5 no.2
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    • pp.82-86
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    • 1984
  • The anomalous behaviors of supercooled water are explained by using a two-solid-like structure model in which an equilibrium is assumed between open structures and closed structures. Besides these structures, small fraction of monomer exists in liquid water. The anomalies of liquid water are classified into two groups: structural and energetic. The structural anomalies appear in enlarged fashions in a supercooled state where the free volume is small.