• 제목/요약/키워드: Liquid viscosity

검색결과 547건 처리시간 0.022초

Ni계 이원금속 촉매에 의한 혼합 바이오오일의 안정화를 위한 수소첨가 반응 (Hydrotreating for Stabilization of Bio-oil Mixture over Ni-based Bimetallic Catalysts)

  • 이성찬;;우희철
    • 청정기술
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    • 제27권1호
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    • pp.69-78
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    • 2021
  • 팜유(palm oil)와 캐슈넛 껍질액(cashew nut shell liquid, CNSL)과 같은 식물유는 한국에서 수송용 바이오-디젤 혹은 발전용 바이오-중유의 주요 원료로서 사용되고 있다. 그러나, 이들은 탄화수소의 이중결합에 의한 높은 불포화도와 더불어 카르복실산에 기인한 높은 산소의 함량으로 인하여 연료유로서의 적용 범위에 한계가 있다. 이러한 관점에서, 본 연구는 팜유와 CNSL이 1/1 v/v%으로 이루어진 혼합 바이오오일에 포함된 불포화탄화수소를 포화시키고 산소 성분을 제거하기 위한 수소화처리 반응을 단일금속촉매(Ni과 Cu)와 이원금속촉매(Ni-Zn, Ni-Fe, Ni-Cu Ni-Co, Ni-Pd와 Ni-Pt) 들을 적용하여 완화된 반응조건(온도 250 ~ 400 ℃, 압력 5 ~ 80 bar와 LHSV 1 h-1) 하에서 수행하였다. Ni 활성성분에 대한 귀금속과 전이금속의 첨가는 수소화반응(HYD)과 탈산소반응(HDO)의 두 반응에 대한 활성을 증가시키는 시너지 효과를 보였다. 가장 활성이 뛰어난 유망한 촉매는 Ni-Cu/��-Al2O3으로서 Ni/Cu의 원소비가 9/1 ~ 1/4의 넓은 범위에서 HYD반응과 HDO반응에 대한 전환율이 각각 90 ~ 93%와 95 ~ 99%을 보였다. 이와 같이 Ni/Cu의 원소 비율이 넓은 범위에서 일정한 촉매반응활성을 보임에 따라 전형적인 구조비민감성 반응임을 알 수 있다. 그리고, 수소화처리 반응에 의해 정제된 혼합 바이오오일은 원료 혼합 바이오오일에 비해 요오드가, 산가 및 동점도가 크게 낮아졌으며, 고위발열량은 약 10% 증가되었다.

초음파검사 시 기존 초음파젤과 비교한 손소독제의 유용성 연구 (A Study on the Effectiveness of Hand Sanitizer compared to Conventional Ultrasound Gel during Ultrasound Examination)

  • 서선열;이진옥;김영란
    • 한국방사선학회논문지
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    • 제17권6호
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    • pp.957-964
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    • 2023
  • 본 연구는 시중에 판매되고 있는 다양한 성분과 제형의 손 소독제들을 전파 매질로 활용하여 초음파 검사를 진행한 후 획득한 영상을 평가·비교하여 기존의 초음파 젤의 대체 가능성을 확인하고자 하였다. 연구 방법으로는 점도가 낮은 liquid type을 제외한 gel type, cream type, foam type의 제형의 제품들을 선정해 에탄올 62% gel type 1개와 cream type 1개, 벤잘코늄 염화물 0.066% cream type 1개와 foam type 1개를 각각 초음파 매질로 사용하여, 축방향 & 측방향 분해능, 투과심도, probe와 phantom 사이의 공기층 형성유무에 관한 영상 평가를 진행하였다. 그 결과, 축방향 & 측방향 분해능 평가와 투과심도 평가에서 4개 실험군 모두 평가 기준에 적합한 결과가 나왔다. 그러나 foam type의 경우 분해능과 투과심도의 평가 기준에는 적합하지만 영상 평가 시 관찰 중심부를 제외한 양 측면부에서 어두운 음영으로 나타났다. 해당 실험을 통해 foam type을 제외한 나머지 3종의 손 소독제는 초음파 젤을 대체할 수 있을 것으로 사료된다.

팽창률이 일정한 노즐을 사용한 AIR-KNIFE 유동에 관한 연구 (A STUDY ON THE FLOW CHARACTERISTICS OF AIR-KNIFE USING A CONSTANT EXPANSION RATE NOZZLE)

  • 이동원;강남철;김근영;권영두;권순범
    • 한국전산유체공학회지
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    • 제13권4호
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    • pp.1-7
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    • 2008
  • In the process of continuous hot-dip galvanizing, it is well known that the gas wiping through an air knife system is most effective because of its uniformity in coating thickness, possibility of thin coating, workability in high speed, and simplicity of control. However, gas wiping used in the galvanizing process brings about a problem of splashing at the strip edge above a certain high speed of process. It is also known that the problem of edge splashing is more harmful than that at the mid strip surface. For a given liquid(of a certain viscosity and surface tension), the onset of splashing mainly depends upon the strip velocity, the gas-jet pressure, and the nozzle's stand-off distance. In these connections in the present study, we proposed three kinds of air knife system having nozzles of constant expansion rate, and compared the jet structures issuing from newly proposed nozzle systems with the result by a conventional one. In numerical analysis, the governing equations are consisted of two-dimensional time dependent Navier-Stokes equations, and the standard k-${\varepsilon}$ turbulence model is employed to solve turbulence stress and so on. As the result, it is found that we had better use the constant expansion-rate nozzle which can be interpreted from the point view of the energy saving for the same coating thickness. Also, we better reduce the size of separation bubble and enhance the cutting ability at the strip surface, by using an air-knife having constant expansion-rate nozzle.

LPLi 시스템에서 외장형 펌프의 연료조성 및 온도에 따른 성능특성 연구 (Performance Characteristics with Various Fuel Composition and Temperature for an External Type Fuel Pump in LPLi System)

  • 남덕우;윤준규;임종한
    • Journal of Advanced Marine Engineering and Technology
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    • 제35권5호
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    • pp.566-575
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    • 2011
  • LPG 연료공급방식은 배출가스를 저감시킬 수 있는 유용한 시스템으로 연구가 지속적으로 진행되고 있다. LPG는 경유와 휘발유보다 높은 증기압과 낮은 점도와 표면장력을 유지하므로 고무류와 화학 반응에 따른 연료펌프의 기계적인 손상으로 내구성이 저하되고 있는 실정이다. 본 연구에서는 이러한 문제점을 해결하기 위해 LPLi 시스템에서 유지보수의 편리함과 가격경쟁을 위해 개발된 외장형 펌프를 사용하여 LPG 연료의 조성 및 온도에 따른 특성을 평가하고자 실험을 하였다. 그 결과로서, 내장형 펌프와 외장형 펌프의 성능차이는 거의 없으며 프로판 함유율이 높고, 연료온도가 높아짐에 따라 유량은 많아지나 펌프효율은 거의 차이가 없었다. 또한 LPG 자동차 연료공급장치의 특성상 연료조성 및 온도변화에 따른 차압도 거의 일정하게 나타내었다.

포천시 초등학생의 주관적 구강건강인식 및 구강보건 행태와 우식경험영구치지수와의 관련성 (An analysis of the associated factors which influence DMFT index of the primary school children's in Pocheon city)

  • 김영남;송윤신;최은정;김영수;최은미
    • 한국치위생학회지
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    • 제11권1호
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    • pp.113-126
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    • 2011
  • Objectives : We supposed that identifying the influencing factors on DMFT index in the primary school children in Pocheon be indispensible for the primary school children's oral health program establishment in Pocheon. So, to prepare the basic materials for the primary school children's oral health program establishment in Pocheon, we analyzed the associated factors which could have an influence on the primary school children's DMFT index in Pocheon. Methods : We selected 3,676 primary school children in Pocheon, whose age were from 6 to 11, and surveyed those children by a questionnaire and the oral examination based on WHO's oral health survey method. Data were analyzed with a $x^2$-test and multiple regression analysis using SPSS $15.0^{(R)}$. Results : The results of oral survey in the primary school children in Pocheon revealed as follows: DMFT index, National Health Oral health survey of 2006 people nationwide in the results when compared to younger grade children and older grade in the low and the higher. Subjective oral health awareness, high of viscosity junk food snacks, fruit, gender, dental visits and humidity, oral health education classes, including the variable of attitude was 6(p<0.05). Their higher awareness of dental health, oral health education classes ever the more positive attitude to DMFT index was statistically significant(p<0.05). Solid in the habit of eating junk food snacks to the students of a liquid relative to student intake was higher DMFT index indices(p<0.05). Conclusions : We could reason that one's oral health recognition and behavior should have a relationship with his(her) DMFT index.

다양한 배관 경사각도 및 중력조건에서의 층상류 유동양식 예측 (The Prediction of Stratified Flow Pattern in a Variable Tube Inclinations and Gravity Conditions)

  • 최부홍
    • 해양환경안전학회지
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    • 제14권4호
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    • pp.339-345
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    • 2008
  • 기름과 가스 수송 라인 및 선박 내에 설비된 유체 기계들에 관련된 파이프 내에 층상류 흐름이 존재할 수 있다. 이 때문에 수평 혹은 작은 경사 파이프 내에 발생할 수 있는 층상류 흐름을 예측하기 위한 많은 이론과 상관식이 제시되었다. 기존 연구들은 각 상의 물성, 점성, 밀도 및 파이프의 기하학적 형상 등이 층상류 흐름에 주는 효과에 관한 것이 대부분이고, 중력의 크기 및 파이프의 큰 경사 기울기에 관한 연구성과는 매우 드문 실정이다. 따라서 본 연구에는 중력크기 및 파이프 경사도 변화가 층상류 발생 조건에 미치는 영향에 대해 이론적 연구가 수행되었다. 또한 본 해석을 통하여 0.17g 및 0.33g 조건에서는 비록 수직상향 흐름일지라도 매우 낮은 액체상의 유량조건에서는 층상류 흐름이 존재할 수 있음을 알 수 있었다.

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제단백 Porphyran의 성분 및 유동 특성 (Chemical Composition and Rheological Properties of Deproteinated Porphyran)

  • 구재근;박병춘;김병기;김현애;유정희;김선영
    • 한국수산과학회지
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    • 제40권1호
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    • pp.1-7
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    • 2007
  • The chemical and rheological properties of deproteinated porphyrans from laver Porphyra yezoensis were investigated to obtain basic data for the production of food materials with biological functionality. Deproteinated porphyran was prepared by acid extraction (pH 4.0, $80^{\circ}C$, 4 hr) and successive hydrolysis with 0.5% Alcalase and 0.5% Flavourzyme. The porphyran constituted 10.7% of the dry laver and consisted of 0.6% protein, 14.8% ester sulfate, 3.2% 6-O-methyl galactose, 16.0% 3,6-anhydro-L-galactose, and 67.3% galactose. The effects of concentration and temperature on the apparent viscosity were examined by applying the power law and Arrhenius equations. The porphyran solution showed the typical behavior of a pseudoplastic liquid and the flow behavior index decreased with increasing concentration. The activation energy of the deproteinated porphyran solution at a 1,000 L/s shear rate also increased from $1.4954{\times}10^{4}\;to\;1.9544{\times}10^{4}\;J/kg$ mol with the concentration.

고온가스로용 핵연료 UO2 Kernel 입자제조 ( UO2 Kernel Particle Preparation for HTGR Nuclear Fuel)

  • 정경채;김연구;오승철;조문성
    • 한국세라믹학회지
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    • 제44권8호
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    • pp.437-444
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    • 2007
  • The broth solution was prepared by the mixing of an uranyl nitrate, THFA, PVA, and water. The uranium concentration of the broth solution was $0.5{\sim}0.8$ mole-U/L and the viscosity of it was $30{\sim}80cSt$. The droplets of this broth solution were farmed in air and ammonia by the vibrating nozzle with the frequency of 100 Hz at the amplitude of $100{\sim}130V$. The diameter of the droplet was about $1900{\mu}m$ from using the nozzle diameter of 1 mm. The diameter of the aged gel was about $1400{\mu}m$ after aging in ammonia solution at $60{\sim}80^{\circ}C$, and the dried gel with the diameter of about $900{\mu}m$ was obtained after drying at room temperature or partially vacuum condition. The diameter of the calcined $UO_3$ microsphere after calcination at $600^{\circ}C$ appeared about $800{\mu}m$ in air atmosphere. Although the droplets of the same sizes were formed, the calcined microspheres of different sizes were manufactured in the case of the broth solutions of the different uranium concentration. The droplets of the desired diameters were obtained by the change of the nozzle diameters and the broth flow rates.

레벨셋 기법을 이용한 전기습윤 현상의 동적 거동에 대한 해석 및 물성 보간 방법에 대한 고찰 (ANALYSIS OF ELECTROWETTING DYNAMICS WITH LEVEL SET METHOD AND ASSESSMENT OF PROPERTY INTERPOLATION METHODS)

  • 박준권;강관형
    • 한국전산유체공학회:학술대회논문집
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    • 한국전산유체공학회 2010년 춘계학술대회논문집
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    • pp.551-555
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    • 2010
  • Electrowetting is a versatile tool to handle tiny droplets and forms a backbone of digital microfluidics. Numerical analysis is necessary to fully understand the dynamics of electrowetting, especially in designing electrowetting-based devices, such as liquid lenses and reflective displays. We developed a numerical method to analyze the general contact-line problems, incorporating dynamic contact angle models. The method is based on the conservative level set method to capture the interface of two fluids without loss of mass. We applied the method to the analysis of spreading process of a sessile droplet for step input voltages and oscillation of the droplet for alternating input voltages in electrowetting. The result was compared with experimental data. It is shown that contact line friction significantly affects the contact line motion and the oscillation amplitude. The pinning process of contact line was well represented by including the hysteresis effect in the contact angle models. In level set method, in the mean time, material properties are made to change smoothly across an interface of two materials with different properties by introducing an interpolation or smoothing scheme. So far, the weighted arithmetic mean (WAM) method has been exclusively adopted in level set method, without complete assessment for its validity. We viscosity, thermal conductivity, electrical conductivity, and permittivity, can be an alternative. I.e., the WHM gives more accurate results than the WAM method in certain circumstances. The interpolation scheme should be selected considering various characteristics including type of property, ratio of property of two fluids, geometry of interface, and so on.

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감물을 이용한 천염염색과 염직물 특성 (Natural Dyeing and Dyed Fabrics Properties with Persimmon Juice)

  • 한미란;이정숙
    • 한국의류산업학회지
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    • 제12권2호
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    • pp.224-232
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    • 2010
  • The natural dyeing of fabrics with persimmon juice(astringent persimmon, sweet persimmon, astringent and sweet persimmon mix) was investigated. After dyeing of cotton and silk fabrics with persimmon juice, we evaluated the dyeability of persimmon juice, the observation of fabric surface with high magnification video microscope, physical properties and color fastness with the conditions of repeating times of dyeing and variables of mordants. The results obtained from this study were as follows: The fabrics dyed with astringent persimmon have shown the highest color difference, while the fabrics dyed with sweet persimmon and the fabrics dyed with astringent and sweet persimmon mix have shown similar color differences. With the increase of repeating times of dyeing, the brightness of fabric decreased. However, $a^*$ value increased gradually, so that it became dark brown color. The $a^*$ and $b^*$ values of dyed fabrics with Fe-mordant have dropped significantly, so that they have shown achromatic colors. But the fabrics treated with other mordants have shown yellowish brown colors. On the surface of the fabrics, threads were bonded together by the viscosity of persimmon juice. Regardless of the types of persimmon juice, stiffness was increased after dying, while crease resistance was decreased. The water repellency of silk fabrics were improved than cotton fabrics after dyeing with sweet persimmon juice, but in case of cotton, it hasn't changed. Washing fastness was improved with the EM(Effective Microorganism)-fermented liquid treatment, and rubbing fastness of two fabrics was better in dry condition than in wet condition.