• 한국대기환경학회지
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• 제29권6호
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• pp.757-772
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• 2013

In this study, a combination of sorbent tube (ST)-thermal desorption (TD)-gas chromatography (GC)-mass spectrometry (MS) was used for quantitative analysis of liquid phase standards of 10 BVOC ((1) (+)-${\alpha}$-pinene, (2) (+)-${\beta}$-pinene, (3) ${\alpha}$-phellandrene, (4) (+)-3-carene, (5) ${\alpha}$-terpinene, (6) p-cymene, (7) (R)-(+)-limonene, (8) ${\gamma}$- terpinene, (9) myrcene, and (10) camphene). The results of BVOC calibration yielded comparatively stable pattern with response factor (RF) of 23,560~50,363 and coefficient of determination ($R^2$) of 0.9911~0.9973. The method detection limit (MDL) of BVOC was estimated at 0.03~0.06 ng with the reproducibility of 1.30~5.13% (in terms of relative standard error (RSE)). Emissions of BVOC were measured from four types of fruit samples ((1) tangerine (TO), (2) tangerine peel (TX), (3) strawberry (SO), and (4) sepals of strawberry (SX)). The sum of BVOC flux (${\sum}flux$ (BVOC) in ng/hr/g) for each sample was seen on the descending order of (1) TX=291,614, (2) TO=2,190, (3) SO=1,414, and (4) SX=2,093. If the results are compared between the individual components, the highest flux was seen from (R)-(+)-limonene (265,395 ng/hr/g) from TX sample.

• 대한기계학회논문집B
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• 제22권4호
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• pp.489-498
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• 1998

Among the heat/mass exchange units composing an absorption system, the absorber, where the refrigerant vapor is absorbed into the liquid solution is the one least understood. In the present study, the effects of non-absorbable gas on the absorption process of aqueous lithium bromide solution falling film inside a vertical tube were experimentally investigated. In the range of film Reynolds number of 30 ~ 195, heat and mass transfer characteristics were investigated as a function of non-absorbable gas volumetric concentration, 0.2 ~ 20%. An increase of non-absorbable gas volumetric concentration degraded the mass transfer rate dramatically in the absorption process. The reduction of mass transfer rate was significant for the addition of small amount of non-absorbable gas to the pure vapor. At film Reynolds number of 130, an increase of non-absorbable gas concentration from 0.2 to 6.0% resulted in the decrease of mass transfer rate by 36% and 20% of non-absorbable gas by 59%. However the decrease of film Nusselt number with the increase of volumetric concentration of non absorbable gas was relatively smaller than the decrease of Sherwood number. Critical film Reynolds number was identified to exist for the maximum heat and mass transfer regardless of the volumetric concentration of non-absorbable gases.

• 한국산업보건학회지
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• 제9권1호
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• pp.173-186
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• 1999

To utilize diffuse sampling of formaldehyde in air, a new sampler was designed. A glass fiber filter was impegnated with 2,4-dinitrophenylhydrazine(DNP) and phosphoric acid and mounted 37mm cassette. The formaldehyde vapor was sampled in the dynamic chamber and measured by high performance liquid chromatograph and compared with solid sorbent tube. The results were as follows ; 1. The desorption efficiencies of diffusive sampler between 97.0% and 100%. 2. the sampling rate is constant as in $58{\sim}61.8m{\ell}/min$ when sampling times are between 120 and 360 min. 3. There was a significant relationship between concentrations of diffusive samples and active samples with the coefficient of determination(R2) of 0.92. 4. Desorbed amount of formaldehyde diffusive sampler was increased by high relative humidity. 5. Wheth diffusive samplers were stored at room temperature or at refrigerator there was no statistically significant difference in the accuracy of result. 6. When the diffusive samplers, which collected formaldehyde vapor, were exposed to clean air for three hours, there was no significant loss of formaldehyde due to reverse diffusion. In conclusion, this study suggest that developed diffusive samplers will be a reasonable substitute for the solid sorbent tube for sampling formaldehyde and practical comparative study of developed diffusive sampler should be performed at workplaces of manufacturing industry.

• Journal of Microbiology and Biotechnology
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• 제4권4호
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• pp.296-304
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• 1994

Antibiotic substances were produced by Bacillus subtilis YB-70, a potential biocontrol agent found to suppress root-rot of eggplant (Solanum melonggena L) caused by Fusarium solani, in a dextrose glutamate medium and isolated by isoelectric precipitation. Partial purification was performed by column chromatography on silica gel with two solvent systems: chloroform-methanol and methanol-chloroform-water as eluting solvents, This active fraction YBS-1 s contained antifungal activity were soluble in ethanol, methanol, and water, but were not soluble in other solvents including acetone, butanol, ethyl ether, dimethylformamide, propanol, and etc. High performance liquid chromatography and thin layer chromatographic separation of YBS-1s showed that they have been composed of three biological active bands that were named YBS-1A, -1B, and -1C. The substances were stable to heat and resistant to protease. YBS-1s were active against a wide range of plant pathogenic fungi but did not inhibit the growth of bacteria and yeasts. They were not only fungicidal but also fungistatic against chlamydospores of F. solani. The $ED_{50}$ values for the chlamydospore germination and the germ-tube growth of F. solani were $O.725\mu\textrm{m}/ml\;and\;O.562\mu\textrm{m}/ml$, respectively. Microscopic observations proved the substances restricted the growth of phytopathogenic fungus F. solani by spore burst followed by dissolving of its germ-tube, and caused abnormal hyphal swelling after application to chlamydospores or growing hyphae. Cultural filtrate of B; subtilis YB-70 also suppressed the development of root-rot of eggplant in pot tests.

• 설비공학논문집
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• 제18권12호
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• pp.955-963
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• 2006

Nucleate pool boiling heat transfer coefficients (HTCs) were measured with one nonazeotropic mixture of Propane/Isobutane and two azeotropic mixtures of HFC134a/Isobutane and Propane/HFC134a. All data were taken at the liquid pool temperature of $7^{\circ}C$ on a horizontal plain tube with heat fluxes of $10kW/m^2\;to\;80kW/m^2$ with an interval of $10kW/m^2$ in the decreasing order of heat flux. The measurements were made through electrical heating by a cartridge heater. The nonazeotropic mixture of Propane/Isobutane showed a reduction of HTCs as much as 41% from the ideal values. The azeotropic mixtures of HFC134a/Isobutane and Propane/HFC134a showed a reduction of HTCs as much as 44% from the ideal values at compositions other than azeotropic compositions. At azeotropic compositions, however, the HTCs were even higher than the ideal values due to the increase in the vapor pressure. For all mixtures, the reduction in heat transfer was greater with a larger gliding temperature difference. Stephan and $K{\ddot{o}}rner's$ and Jung et al's correlations predicted the HTCs of mixtures with a mean deviation of 11%. The largest mean deviation occurred at the azeotropic compositions of HFC134a/Isobutane and Propane/HFC134a.

• 동력기계공학회지
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• 제18권4호
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• pp.23-28
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• 2014

In order to increase the performance of conventional hot water floor heating system, the bubble jet loop heat pipe for the system was developed. This experiment was conducted under next conditions : Working fluid was R-134a, charging ratio was 50%. A temperature of hot water, room temperature and flow rate were $60^{\circ}C$, $15^{\circ}C$ and 0.5~1.5 kg/min, respectively. The experimental results, show that bubble jet loop heat pipe had a high effective thermal conductivity of $4714kW/m^{\circ}C$ and a sufficient heat flux of $73W/m^2$ to heat the floor to $35^{\circ}C$ in case of the 1.5 kg/min of flow rate. So the bubble jet loop heat pipe has a possibility for appling of the floor heating system. Additionally, the visualization of bubble jet loop heat pipe was performed to understand the operating principle. Bubbles made by the narrow gap between inner tube and outer tube of evaporating part generate pulsation at liquid surface of working fluid. The pulsation had slug flow and wavy flow. So working fluid circulates in the bubble jet loop heat pipe as two phase flow pattern. And large amount of heat is transferred by the latent heat from evaporating part to condensing part.

• 설비공학논문집
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• 제17권12호
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• pp.1113-1122
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• 2005

The experimental heat transfer coefficients have been measured for two-phase convective boiling in two circular microtubes with inner diameters of $430{\mu}m\;and\;792{\mu}m$. While the heat transfer was greatly affected by the heat flux in the low quality region, the mass flux played a role in the high quality region. The smaller microtube had greater heat transfer coefficients. When the heat flux is varied from $20kW/m^2\;to\;30kW/m^2\;at\;G=240kg/m^2s$, the difference between the average heat transfer coefficients of the test tube $A(D_i=430{\mu}m)$ and the test tube $B(D_i=792{\mu}m)$ changes from $32.5\%\;to\;52.1\%$. At $G=370kg/m2^s$, the difference between the average heat transfer coefficients changes from $47.0\%\;to\;53.8\%$. A new correlation for the evaporative heat transfer coefficients in microtubes was developed by considering the following factors; the laminar flow heat transfer coefficient of liquid-phase flow, the enhancement factor of the convective heat transfer, and the nucleate boiling correction factor. The correlation developed in this study predicts the experimental heat transfer coefficients within an absolute average deviation of $8.4\%$.

• 한국정밀공학회지
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• 제28권1호
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• pp.19-23
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• 2011

Recently, focused ion beam (FIB) applications have been investigated for the modification of VLSI circuit, the MEMS processing, and the localized ion doping, A multi aperture FIB system has been introduced as the demands of FIB applications for high speed and large area processing increase. A liquid metal ion source has problems, a large angular divergence and a metal contamination into a substrate. In this study, a gas ion source was introduced to replace a liquid metal ion source. The gas ion source generated inductively coupled plasma (ICP) in a quartz tube (diameter: 45 mm). Ar gas fed into the quartz was ionized by a 2 turned radio frequency antenna. The Ar ions were extracted by 2 extraction grids. The maximum extraction voltage was 10 kV. A numerical simulation was used to optimize the design of extraction grids and to predict an ion trajectory. As a result, the maximum ion current density was 38 $mA/cm^2$ and the spread of ion energy was 1.6 % for the extraction voltage.

• 한국산학기술학회논문지
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• 제10권1호
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• pp.39-45
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• 2009

디스플레이 장치에서 기존의 CRT는 곡면이며 무겁고 큰 부피 때문에 LCD, PDP와 같은 평판디스플레이(FPD)로 대체되고 있다. FPD는 $0.6{\sim}0.8mm$ 두께의 대면적 글래스에 여러 공정을 거친 후에 최종 제품 규격으로 절단하여 제작하기 때문에 글래스의 면적이 크면 클수록 FPD의 생산성이 높다는 밀접한 관계를 갖는다. 따라서 FPD 제조 업계에서는 글래스 면적을 증가시키기 위하여 노력하고 있다. 7세대 글라스($2,220mm\;{\times}\;1,870mm\;{\times}\;0.7mm$)를 대상으로 유한요소해석 및 유동해석을 통하여 이송장치, 배급장치, 수평/경사 변환장치 및 제어장치로 구성된 비접촉 공기부상 이송시스템을 개발하였다. 본 개발에서 확보한 설계기술을 통하여 글라스의 크기가 대형화 되더라도 관련 이송장비를 보다 쉽게 제작하여 적용할 수 있다.

• 대한화학회지
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• 제31권3호
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• pp.236-243
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• 1987

모세관 컬럼의 기체-액체 크로마토그래피로 11종의 유기인제 잔류 농약을 분석하기 위한 최적 분리를 검토 하였으며 시료 도입시 주입방식과 기화관의 종류에 대한 조사도 하였다. 분리 방식(split mode)으로 기화관은 석영솜을 충진한 관에서 봉우리 높이에 대한 재현성이 가장 좋았다. 농약의 최적 분리를 주는 모세관 컬럼은 SE-54보다 SE-30(25m)이었고 온도상승방식은 $200^{\circ}C$에서 $230^{\circ}C$까지$5^{\circ}C/min$로 승온시켜 5분간 유지하고 $270^{\circ}C$까지 $10^{\circ}C/min$로 승온해서 5분간 등온을 유지하였다. 또한 각 농약의 머무른 시간의 상대표준편차는 ${\pm}0.19%$ 이하의 좋은 결과를 보였다.