• Title/Summary/Keyword: Liquid reduction

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Preparation of Spherical Cobalt Fine Powders by New Liquid Reduction Method (새로운 용액환원법에 의한 구형 코발트 미세 분말의 제조)

  • Kim, Dae Weon;Kim, Ji-Hoon;Choi, Yo-Han;Choi, Hee Lack;Yoon, Jin-Ho
    • Journal of Powder Materials
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    • v.22 no.4
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    • pp.260-265
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    • 2015
  • Spherical fine cobalt powders were fabricated by new liquid reduction method. Commercial cobalt sufate heptahydrate was used as raw material. Also ethylene glycol was used as solvent and hydrazine-sodium hypophosphite mixture was used as reduction agent for the new liquid reduction method. A plate shaped cobalt powders with an approximately 300 nm were prepared by a traditional wet ruduction method using distilled water as solvent and hydrazine. Spherical fine cobalt powders with an average size of $1-3{\mu}m$ were synthesized by a new liquid reduction method in 0.3M cobalt sulfate and 1.5M hydrazine-0.6M sodium hypophosphite mixture at 333K.

A study on the drag reduction in a horizontal two phase flow (수평 2상유동에서 마찰저항감소에 관한 연구)

  • Cha, Gyeong-Ok;Kim, Jae-Geun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.20 no.4
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    • pp.1472-1480
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    • 1996
  • The phenomena of drag reduction using small quantities of a linear macromolecules has attracted the attention of experimental investigations. It is well known that drag reduction in single phase liquid flow is affected by polymer materials, molecular weight, polymer concentration, pipe diameter and flow velocity. But the research on drag reduction in two phase flow has not intensively investigated. Drag reduction can be applied to phase change system such as chemical reactor, pool and boiling flow, and to flow with cavitation which occurs pump impellers. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, mean liquid velocity, and turbulent intensity and determine the effects of polymer additives on drag reduction in horizontal two phase flow. Experimental results show higher drag reduction using co-polymer comparing with using polyacrylamide. Mean liquid velocities increase as adding more polymer, and turbulent intensities decrease as the distance for the wall in inversed.

Comparison Study of the Synthesized Silver Nano-particles using Liquid Phase Reduction Method and Alcohol Reduction Process (액상환원법과 알코올환원법으로 제조한 은나노입자특성 비교에 관한 연구)

  • Son, Eun-Jong;Hwang, Young-Gu;Shin, Yu-Shik;Jeong, Sung-Hoon
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.146-153
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    • 2011
  • Silver nano-particles have been synthesized by liquid phase reduction method and alcohol reduction process. Silver nano-particles of the size 30 ~ 40 nm were formed successfully by alcohol reduction process. The formation, structure, morphology and size of silver nano-particles have been studied using FE-SEM, TEM, XRD, UV-visible spectroscopy. In particular high dispersion stability of the synthesized silver nano-particles could be obtained by PVP binding. Antibacterial activity of Ag/PET master batch sample made from its nano-silver particles showed excellent antibacterial activity against S. aureus and E. coli.

A Study on the Drag Reduction with Polymer Additives (고분자물질(高分子物質) 첨가(添加)에 따른 마찰저항감소(摩擦抵抗減少)에 관한 연구(硏究))

  • Kim, J.G.;Cha, K.O.;Choi, H.J.;Kim, C.B.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.8 no.2
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    • pp.198-207
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    • 1996
  • It is well known that drag reduction in single phase liquid flow is affected by polymer material, molecular weight, polymer concentration, pipe diameter, and flow velocity. Drag reduction in two phase flow can be applied to the transport of crude oil, phase change system such as chemical reactor, pool and boiling flow, and to present cavitation which occurs in pump impellers. But the research of drag reduction in two phase flow is not sufficient. The purpose of the present work is to evaluate the drag reduction by measuring pressure drop, void fraction, mean liquid velocity, and turbulent intensity whether polymer is added in the horizontal two phase system or not. Experiment has been conducted in a test section with the inner diameter of 24mm and the length of 1,500mm. The polymer materials used are two kinds of polyacrylamide[PAAM] and co-polymer[A611P]. The polymer concentration was varied with 50, 100 and 200 ppm under the same experimental conditions. Experimental results showed that the drag reduction of co-polymer is higher than that of polyacrylamide. Mean liquid velocities increased as polymer was added, and turbulent intensity decreased inversely near the pipe wall.

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Synthesis of Ag Nanopowder for Low Temperature Heat Treatment Prepared by Liquid Phase Reduction Method (액상환원법에 의한 저온 열처리용 Ag 나노분말의 합성)

  • Lee, Jong-Kook;Choi, Nam-Kyu;Song, Dae-Sung;Yang, Gon-Seung;Seo, Dong-Seok
    • Journal of the Korean Society for Heat Treatment
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    • v.18 no.4
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    • pp.242-246
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    • 2005
  • Silver nanoparticles were synthesized by liquid phase reduction method from aqueous silver nitrate solution and borohybride as a reduction agent. The morphology, particle size and shape were influenced by the reaction conditions such as the concentration of $AgNO_3$, a reduction agent and addition of surfactant. The particle size decreased with decreasing the concentration of silver nitrate and using a borohydride. The obtained Ag particles showed the spherical shape with the range of 10-20 nm.

Electrochemical Reduction of SiO2 Granules to One-Dimensional Si Rods Using Ag-Si Eutectic Alloy

  • Lee, Han Ju;Seo, Won-Chul;Lim, Taeho
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.392-398
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    • 2020
  • Producing solar grade silicon using an inexpensive method is a key factor in lowering silicon solar cell costs; the direct electrochemical reduction of SiO2 in molten salt is one of the more promising candidates for manufacturing this silicon. In this study, SiO2 granules were electrochemically reduced in molten CaCl2 (850℃) using Ag-Si eutectic droplets that catalyze electrochemical reduction and purify the Si product. When Ag is used as the working electrode, the Ag-Si eutectic mixture is formed naturally during SiO2 reduction. However, since the Ag-Si eutectic droplets are liquid at 850℃, they are easily lost during the reduction process. To minimize the loss of liquid Ag-Si eutectic droplets, a cylindrical graphite container working electrode was introduced and Ag was added separately to the working electrode along with the SiO2 granules. The graphite container working electrode successfully prevented the loss of the Ag-Si eutectic droplets during reduction. As a result, the Ag-Si eutectic droplets acted as stable catalysts for the electrochemical reduction of SiO2, thereby producing one-dimensional Si rods through a mechanism similar to that of vapor-liquid-solid growth.

A Study on the Estimation of Water Pollutants Reduction Ratio in Livestock Manure Fertilization (가축분뇨 자원화 처리시 수질오염물질 삭감율 산정 연구)

  • Oa, Seong Wook
    • Journal of Korean Society on Water Environment
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    • v.33 no.6
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    • pp.722-727
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    • 2017
  • Livestock manure is known to be the main cause of non-point pollution in agricultural areas. The pollutant reduction ratio of livestock manure recycling to fertilizers was measured in order to analyze the effect on the water quality of the Total Maximum Daily Load (TMDL) system in Korea. The reduction ratio has been applied by theoretical consideration without a survey, and there is no value for Total Organic Carbon (TOC) newly introducing any organic items. The reduction ratio of each pollutant from this study was revealed as follows: TOC, BOD, T-N and T-P were 0.34, 0.60, 0.37, and 0.42 for individual farm and 0.38, 0.61, 0.45 and 0.44 for entrustment facilities, respectively. The reduction ratio of individual farm was surveyed as TOC 0.63, BOD 0.62, T-N 0.42 and T-P 0.32 for liquid fertilizer, and TOC 0.30, BOD 0.64, T-N 0.40 and T-P 0.48 for compost. The total reduction ratio was derived by multiplying the ratio for liquid fertilizer and compost by the respective load. Compared to the pollutant reduction ratio of the individual farm with entrustment facilities marking the higher in liquid fertilizer and the lower in compost. Through this study, we found the difference of pollutant reduction ratio between a livestock manure recycling process and facilities. Although phosphorus is known as a preservative matter, the treatment efficiency of T-P is analyzed to decrease by chemical precipitation.

A Scheme on Reduction of NPP Liquid Effluent Activity

  • Kim, Wi-Soo;Yang, Yang-Hee;Kim, Hee-Guen
    • Nuclear Engineering and Technology
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    • v.34 no.1
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    • pp.9-21
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    • 2002
  • Recently each domestic NPP has achieved zero release in liquid effluent activity. However, when looking back past experiences in world nuclear power operation, it is thought that another maximum activity reduction in the released liquid effluent just prior to falling it into environment, if possible, will bring a good effect in PA viewpoint. As the intent of applying the safety concept of diversity to conducting the above activity reduction measure, a scheme passing that effluent through the Deposition Bed just before discharging it into ocean environment was divised. Both Zeolite and "the mixed "Anthracite-sand" were derived as the main activity adsorption medium used in the Deposition Bed, and the schematic drawings of this Bed were presented.

Spray Characteristics of a Liquid-fueled Ramjet Engine under High Pressure Air Condition (고압 유동조건에서의 액체 램제트 엔진의 분무특성)

  • Youn, H.J.;Lee, C.W.
    • Journal of ILASS-Korea
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    • v.9 no.2
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    • pp.34-40
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    • 2004
  • In a liquid-fueled ramjet engine, the insufficient mixing and evaporation result in the low combustion efficiency and combustion instability. Improving its characteristics and devising a means of fuel droplets with air may compensate these disadvantages of liquid fuel ramjet engine. The jet penetrations of various fuel injectors were measured to investigate the spray characteristics of a liquid-fueled ramjet engine under high pressure air-stream conditions. The penetrations in high pressure conditions are smaller than the values calculated from Inamura's or Lee's equations, and the jet penetrations in the high pressure conditions have a similar tendency. In the dual orifice injectors, the jet penetrations of rare orifice is rapidly increased due to the reduction of the drag, which is created by the jet column of front orifice. The jet penetration of rare orifice is increased because of the drag reduction created by the jet column of the front orifice. Because of the drag reduction formed by the column of jet, the jet penetration in the rear orifice of dual orifice injector is much larger than the jet penetrations of single orifice injector. As the distances of the orifice are increased, the jet penetrations of the rear orifice decrease.

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Volume Reduction of Radioactive Liquid Waste by Pervaporation Method (투과증발법에 의한 방사성폐액의 감용)

  • Kang, Young-Ho;Kwon, Seon-Gil;Yang, Yeong-Seok;Hwang, Sung-Tai;Chang, In-Soon
    • Applied Chemistry for Engineering
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    • v.3 no.2
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    • pp.327-334
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    • 1992
  • As a promising method for the volume reduction of the low-level liquid waste, the pervaporation process was studied using a cellulose acetate membrane. Experimental results showed that the pervaporation method, usually applied to separation of organic materials, has a good decontamination effect for the volume reduction of liquid waste and the evaporation rate of water in this process was markedly faster than that of natural evaporation method, a wide-used process for the volume reduction of liquid waste. Depending on the feed solution conditions, the pervaporation characteristics were evaluated by the experimental results and the optimum conditions for preparation of the cellulose acetate membrane were established to increase the pervaporation flux through the membrane.

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