• Title/Summary/Keyword: Liquid metals

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Using Liquid Aluminum Chloride to Reduce Heavy Metals from Animal Wastes (액상염화알루미늄을 이용한 축산 폐기물 속의 중금속 저감 효과)

  • Kim, Chang-Mann;Choi, Jung-Hoon;Choi, In-Hag
    • Journal of Environmental Science International
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    • v.21 no.3
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    • pp.377-382
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    • 2012
  • Recent research has demonstrated that treating poultry litter with alum (aluminum sulfate) and aluminum chloride can remove environmental threats (ammonia, soluble phosphorus and odor) posed by litter. However, scientific information available on heavy metal in poultry litter with liquid aluminum chloride is still lacked. The purpose of this study was to investigate the effects of applying liquid aluminum chloride to rice hulls on heavy metals and to provide basic information to producers. Six hundred 0-d-old broiler were assigned to 4 treatments (control, 100 g, 200 g and 300 g of liquid $AlCl_3$/kg of rice hulls, respectively) with 3 replicates of 50 birds. The experimental period lasted for 6 weeks. Liquid $AlCl_3$ was sprayed on the rice hulls surface using a small hand pump. Total Al contents increased (P<0.05) with the increasing levels of liquid $AlCl_3$ levels over time in comparison with control groups. Total Cu and Pb were lowered in all liquid $AlCl_3$ treatments compared with the controls during 6 weeks. Significant differences in all treatments were found for total Cu contents at 2, 3 and 5 weeks and total Pb at 0, 1, 2 and 3 weeks. Total Zn contents decreased with time when compared with controls. However, no significant differences in total Zn contents were observed among all treatments. In light of environmental managements, spraying liquid $AlCl_3$ to rice hulls indicated the significant advantages in reducing heavy metals as well as improving poultry industrial competitiveness.

Partition Function of Electrons in Liquid Metals

  • Zhang, Hwe-Ik
    • Nuclear Engineering and Technology
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    • v.5 no.2
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    • pp.77-82
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    • 1973
  • A method of obtaining the partition function for a system of electrons is developed by defining a new density matrix, in which the Fermi statistics is explicitly incorporated. The corresponding Bloch equation is formulated and a practical method of solving the equation is obtained for weak potential. This theory is applied to structurally disordered ststems which might be reasonable models for liquid metals.

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Monitoring of Heavy Metals in Agricultural Soils from Consecutive Applications of Commercial Liquid Pig Manure (돈분액비 연용 농경지 중 중금속 함량 모니터링)

  • Go, Woo-Ri;Kim, Ji-Young;Yoo, Ji-Hyock;Lee, Ji-Ho;Kunhikrishnan, Anitha;Lee, Jeong-Mi;Kim, Kye-Hoon;Kim, Doo-Ho;Kim, Won-Il
    • Korean Journal of Environmental Agriculture
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    • v.31 no.3
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    • pp.217-223
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    • 2012
  • BACKGROUND: Increase of heavy metals in agricultural ecosystem has become a social issue nationwide as it is related to public health. This study was performed to find out the status and long-term trends with consecutive application with the commercial liquid pig manure in the agricultural fields. METHODS AND RESULTS: Heavy metals including arsenic, cadmium, copper, lead, nickel, and zinc were analyzed in the 41 samples of paddy fields and 54 samples of upland fields consecutively applied with commercial liquid pig manure for 0 to 16 years. Heavy metal accumulation were not increased statistically at the both paddy and upland fields as the consecutive application year of commercial liquid pig manure were increased. However, some of surveyed upland soils exceeded the criteria of cadmium, copper, and zinc designated by the Soil Environmental Conservation Act in Korea. CONCLUSION: Therefore, analysis of heavy metals, specially copper and zinc, in agricultural fields is absolutely necessary before liquid pig manure application to the fields. In addition, heavy metal accumulation in agricultural fields following to the long-term application of liquid pig manure will be monitored periodically considering with bioavailability of copper and zinc to the crops as an essential nutrients.

A Study on Mechanical Properties and Fracture Behaviors of In-situ Liquid Mixing Processed FeAl/TiC Intermetallic Matrix Composite (In-situ Liquid Mixing 방법으로 제조된 FeAl/TiC 금속간화합물 복합재료의 기계적 특성과 파괴양상에 관한 연구)

  • Chung, Euihoon;Park, Ikmin;Park, Yongho
    • Korean Journal of Metals and Materials
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    • v.48 no.7
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    • pp.683-689
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    • 2010
  • In this study, FeAl based intermetallic matrix composites reinforced with in-situ synthesized TiC particles were fabricated by an in-situ liquid mixing process. The microstructures, mechanical properties and fracture behaviors of the in-situ liquid mixing processed composite were investigated and compared with the vacuum suction casting processed composite. The results showed that the in-situ formed TiC particles exhibited fine and uniform dispersion in the liquid mixing processed composite, while significant grain boundary clustering and coarsening of TiC particles were obtained by the vacuum suction process. It was also shown in both types of composites that the hardness and bending strength were increased with the increase of the TiC volume fractions. Through the study of fractography in the bending test, it was considered that the TiC particles prohibited brittle intergranular fracture of FeAl intermetallic matrix by crack deflections. Because of the uniformly distributed fine TiC particles, the bending strength of the liquid mixing processed composite was superior to that of the casting processed composite.

Extraction behaviors of platinum group metals in simulated high-level liquid waste by a hydrophobic ionic liquid bearing an amino moiety

  • Wu, Hao;Kim, Seong-Yun;Takahashi, Tadayuki;Oosugi, Haruka;Ito, Tatsuya;Kanie, Kiyoshi
    • Nuclear Engineering and Technology
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    • v.53 no.4
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    • pp.1218-1223
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    • 2021
  • A hydrophobic ionic liquid including an amino moiety ([DiOcAPmim][NTf2]) was synthesized. Its extraction behaviors towards Pd(II), Ru(III), Rh(III) were investigated in nitric acid aqueous solution as a function of contact time, effect of concentration of nitric acid, effect of temperature, and effect of co-existing metal ions. The extraction kinetics of Pd(II) was fairly fast and extraction equilibrium can be attained within only 5 min under the [HNO3] = 2.05 M. When [HNO3]< 1 M, the extraction percentage of Pd(II), Ru(III), Rh(III) were all above 80%. When [HNO3] reached 2 M, all of the extraction percentage decreased and in an order of Pd(II)>Ru(III)>Rh(III). When [HNO3]> 2 M, the extraction performance gradually recovered. The effect of temperature can slightly affect the extraction performance of Pd(II). Furthermore, in simulated high-level liquid waste, [DiOcAPmim][NTf2] showed a better preference towards Pd(II) under the interference of various other co-existing metal ions.

Development of Insert Metals for the Transient Liquid Phase Bonding in the Directional Solidified Ni Base Super Alloy GTD 111 (일방향응고 니켈기 초내열합금 GTD111에서 천이 액상확산 접합용 삽입금속의 개발에 관한 연구)

  • Lee, Bong-Keun;Oh, In-Seok;Kim, Gil-Moo;Kang, Chung-Yun
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.242-247
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    • 2009
  • On the Transient Liquid Phase Bonding (TLPB) phenomenon with the MBF-50 insert metal at narrow gap (under 100), it takes long time for the bonding and the homogenizing. Typically, isothermal solidification is controlled by the diffusion of depressed element of B and Si. However, the amount of B and Si in the MBF-50 filler metal is large. This is reason of the long bonding time. Also, the MBF-50 filler metal did not contained Al and Ti which are ${\gamma}^{\prime}$ phases former. This is reason of the long homogenizing time. From the bonding phenomenon with the MBF-50 insert metal, we search main factors on the bonding mechanism and select several insert-metals for using the wide-gap TLPB. New insert-metals contained Al and Ti which are ${\gamma}^{\prime}$ phases former and decrease the B then the MBF-50. When the new insert-metal was used on the TLPB, the bonding time was decreased about 1/10 times and homogenizing heat treatment was no needed. In spite of the without homogenizing, the volume fraction of ${\gamma}^{\prime}$ phases in the boned interlayer was equal to homogenizing heat treated specimen which was TLPB with the MBF-50. Finally, the new insert metal named WG1 for the wide-gap TLPB is more efficient then the MBF-50 filler metal without decreasing the bonding characteristic.

The Effect of Base Metal Grain Boundary on Isothermal Solidification Phenomena during TLP Bonding of Ni Base Superalloys (액상확산접합한 Ni기 초내열합금의 등온응고거동에 미치는 모재결정입계의 영향)

  • 김대업
    • Journal of Welding and Joining
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    • v.19 no.3
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    • pp.325-333
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    • 2001
  • The effect of base metal grain size on isothermal solidification behavior of Ni-base superalloy, CMSX-2 during transient liquid phase (TLP) bonding was investigated employing MBF-80 insert metal. TLP-bonding of single crystal. coarse-grained and fine-grained CMSX-2 was carried out at 1373∼1548k for various holding time in vacuum. The eutectic width diminished linearly with the square root of holding time during isothermal solidification process for single crystal, coarse-grained and fine-grained base metals. The completion time for isothermal solidification decreased in the order ; single crystal, coarse-grained and fine-grained base metals. The difference of isothermal solidification rates produced when bonding the different base metals could be explained quantitatively by the effect of base metal grain boundaries on the apparent average diffusion coefficient of boron in CMSX-2.

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Infiltration Processing of Ceramic-Metal Composites: The Role of Wettability, Reaction, and Capillary Flow

  • Asthana Rajiv;Singh Mrityunjay;Sobczak Natalia
    • Journal of the Korean Ceramic Society
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    • v.42 no.11 s.282
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    • pp.703-717
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    • 2005
  • The infiltration of ceramics by liquid metals to fabricate ceramic-metal composites is discussed. In particular, the complexity of infiltrating ceramics by liquid metals at high temperatures due to interfacial reactions, metal oxidation, pore modulation and closure, and transient capillary forces has been highlighted. The role of these factors is discussed in the context of reactive infiltration with examples from ceramic/metal composites of practical interest. In addition to flow through porous ceramics, reactive penetration of dense ceramics via chemical dissolution and reaction is also discussed.