• Title/Summary/Keyword: Liquid laser material

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Microstructural features of Laser Radiated GeSbTe Intermetallic Compounds (레이저 조사시킨 GeSbTe 금속간 화합물의 미세조직)

  • 박정우;김명룡
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.66-72
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    • 1995
  • Microstructural features of laser irradiated bulk target which consists of GeSbTe interrmertallic compounds were examined by analytical microscopy. It was found that in addition to vaporization, a liquid expulsion due to laer-material interatction is main contribution of materials removal in the sintered GaSbTe targets, The morphological change is qualitatively discussed in the present article.

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Development of Yb(HFA-D)$_3$Complexes for Liquid Laser Material (액체 레이저 매질로서의 신물질 Yb(HFA-D)$_3$착물의 개발)

  • 김정호;박용필
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.12
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    • pp.1045-1050
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    • 2000
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(HFA-D)$_3$]complexes were synthesized by the keto-enol tautomerism reaction of Yb(HFA-H$_3$) in methanol-d$_4$in rder to reduct the radiationless transition to the ligands. The luminescence properties of Yb(HFA-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescnce in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(HFA-D)$_3$complex.complex.

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Enhancement of Pulsed-Laser Ablation by Phase Explosion of Liquid (액체의 상폭발 과정에 의한 펄스 레이저 용발률의 증진)

  • Kim, Dong-Sik;Lee, Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.11
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    • pp.1483-1491
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    • 2001
  • Enhancement of pulsed-laser ablation by an artificially deposited liquid film is presented. Measurements of ablation rate, ablation threshold, and surface topography arc performed. Correlation between material ablation and photoacoustic effect is examined by the optical beam deflection method. The dependence of ablation rate on liquid-film thickness and chemical composition is also examined. The results indicate that photomechanical effect in the phase explosion of liquid is responsible for the enhanced ablation. The low critical temperature of liquid induces explosive vaporization with localized photoacoustic excitation in the superheat limit and increases the ablation efficiency. Experiments were carried out utilizing a Q-swiched Nd:YAG laser at near-threshold laser fluences with negligible plasma effect (up to ∼100 MW/cm$^2$).

Microstructure and Liquid Al Erosion Property of Tribaloy T-800 Coating Material Manufactured by Laser Cladding Process (Laser Cladding 공정으로 제조된 Tribaloy T-800 코팅 소재의 미세조직 및 용융 Al 침식 특성)

  • Kim, Kyoung-Wook;Ham, Gi-Su;Park, Sun-Hong;Lee, Kee-Ahn
    • Journal of Powder Materials
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    • v.27 no.3
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    • pp.210-218
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    • 2020
  • A T-800 (Co-Mo-Cr) coating material is fabricated using Co-Mo-Cr powder feedstock and laser cladding. The microstructure and melted Al erosion properties of the laser-cladded T-800 coating material are investigated. The Al erosion properties of the HVOF-sprayed MoB-CoCr and bulk T-800 material are also examined and compared with the laser-cladded T-800 coating material. Co and lave phases (Co2MoCr and Co3Mo2Si) are detected in both the laser-cladded T-800 coating and the bulk T-800 materials. However, the sizes of the lave phases are measured as 7.9 ㎛ and 60.6 ㎛ for the laser-cladded and bulk T-800 materials, respectively. After the Al erosion tests, the erosion layer thicknesses of the three materials are measured as 91.50 ㎛ (HVOF MoB-CoCr coating), 204.83 ㎛ (laser cladded T-800), and 226.33 ㎛ (bulk T-800). In the HVOF MoB-CoCr coating material, coarse cracks and delamination of the coating layer are observed. On the other hand, no cracks or local delamination of the coating layer are detected in the laser T-800 material even after the Al erosion test. Based on the above results, the authors discuss the appropriate material and process that could replace conventional bulk T-800 materials used as molten Al pots.

Development of Laser Material for High Power and High Efficiency (고출력, 고효율 실현을 위한 새로운 레이저매질 개발)

  • 김정호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.15-18
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL)-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$ in methanol-d$_4$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$\sub$8/, PO(OCH$_3$)$_3$ and DMSO-d$\sub$6/. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$\sub$6/ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$\sub$6/ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$ complex.

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Optical Properties of Yb(SOL-D)$_3$ Complex for Laser Material (신 레이저매질 Yb(SOL-D)$_3$착물의 광학적 특성)

  • 김정호;서연호;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.640-643
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    • 2001
  • Perdeuterated hexaflouroacetylacetonato-ytterbium [Yb(SOL-D)$_3$] complexes were synthesized by the keto-enol tautomerism reaction of Yb(SOL-H)$_3$in methanol-d$_4$in order to reduce the radiationless transition to the ligands. The luminescence properties of Yb(SOL-D)$_3$complex were measured in the following anhydrous deuterated organic solvents ; Methanol-d$_4$, THF-d$_{8}$, PO(O$CH_3$)$_3$and DMSO-d$_{6}$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-d$_{6}$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of Yb(SOL-D)$_3$complex.complex.

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Optical Properties of $Yb(HFA-D)_{3}$ Complex for Laser Material (레이저 매질로서의 $Yb(HFA-D)_{3}$ 착물의 광학적 특성)

  • 김정호;박용필
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.129-132
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    • 2000
  • Perdeuterated hexafluoroacetylacetonato -ytterbium [$Yb (HFA -D)$_3$_3$] complexes were synthesized by the koto-enol tautomerism reaction of $Yb(HFA-H)_3$ in methanol-$d_4$, in order to reduce the radiationless transition to the ligands. The luminescence properties of $Yb(HFA-D)_3$ complex were measured in the following anhydrous deuterated organic solvents : Acetone-$d_6$, Methanol-$d_4$, THF-$d_8$, $PO(OC$H_3$)_3$ and DMSO-$d_6$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-$d_6$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-d$_{6}$ might be the most appropriate solvent for the liquid laser material of $Yb(HFA-D)_3$ complex.x.

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The effect of laser energy on the preparation of iron oxide by a pulsed laser ablation in ethanol

  • Maneeratanasarn, P.;Khai, T.V.;Choi, B.G.;Shim, K.B.
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.134-138
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    • 2012
  • Recently the preparation magnetic nanoparticles by a pulsed laser ablation in liquid has gained much attention because it is easy to control experimental parameters. Iron oxide magnetic nanoparticles have been prepared by a pulsed laser ablation of ${\alpha}-Fe_2O_3$ target in ethanol at different magnitude of laser energy of 1, 20, 40 and 80 mJ/pulse. It revealed that particle size increases with increasing laser energy. It could be concluded that 40 mJ/pulse is an optimum laser energy for the preparation of iron oxide nanoparticles with uniform size distribution. The nanoparticles are homogeneously dispersed in ethanol and their stability maintained for several months.

Optical Properties of $Yb(HFA-D)_3$ Complex for Laser Material (레이저 매질로서의 $Yb(HFA-D)_3$ 착물의 광학적 특성)

  • 김정호;박용필
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.129-132
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    • 2000
  • Perdeuterated hexaflouroacetyIacetonato-ytterbium $[Yb(HFA-D)_3]$ complexes were synthesized by the keto-en01 tautomerism reaction of $Yb(HFA-D)_3$ in methanol-$d_4$ in order to reduce the radiationless transition to the ligands. The luminescence properties of $Yb(HFA-D)_3$ complex were measured in the following anhydrous deuterated organic solvents ; Acetone-$d_6$, Methanol -$d_4$, THF-$d_6$, PO$(OHC_3)_3$ and DMSO-$d_6$. The intensity, lifetime and quantum efficiency of the luminescence in DMSO-$d_6$ were superior to those in other deuterated solvents. It was suggested that the anhydrous DMSO-$d_6$ might be the most appropriate solvent for the liquid laser material of $Yb(HFA-D)_3$ complex.

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Keyhole-structure and Stability in Laser-beam Penetration Into an Absorbing Liquid (Water) (레이저 빔의 흡수 액체 내 침투에 의해 생성된 키홀 구조와 안정성)

  • 김동식;장덕석
    • Laser Solutions
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    • v.4 no.2
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    • pp.13-19
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    • 2001
  • When a high-power laser beam is irradiated on the surface of material, it is well known that a cavity, called a keyhole induced by the pressure action of the vapor plume, is generated in the molten material. This paper describes the interaction between a pulsed CO$_2$ laser beam and water. The laser-beam is used to generate and maintain a conical depression in the water surface similar to the keyhole created during laser penetration welding. Experimental results show that the depth of laser-beam penetration is limited by hydrodynamic instability. The instability of the surface cavity can be understood by the capillary instability of a hollow jet. Theoretical computation of the steady keyhole shape has been performed. modifying the model suggested by Andrews et al. (1976). The model predicts the qualitative behavior of the keyhole but significantly underestimates the average diameter.

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