• Bulletin of the Korean Chemical Society
• /
• v.27 no.11
• /
• pp.1775-1779
• /
• 2006

A liquid chromatographic chiral stationary phase (CSP) based on (+)-(18-crown-6)-2,3,11,12-tetracarboxilic acid without extra free aminopropyl groups on silica surface has been demonstrated to be quite effective for the resolution of various $\beta$-amino acids. The retention factors ($k_1$) for the resolution of $\beta$-amino acids on the CSP were quite large and the large retention factors might be quite attractive along with the reasonable separation factors ($\alpha$) for preparative scale enantioselective chromatography. The large retention factors on the CSP were found to be reduced effectively by adding ammonium ion to mobile phase without sacrificing the chiral recognition efficiency of the CSP. Consequently, the CSP is also quite applicable for use in analytical enantioselective chromatography.

• Journal of the Society of Naval Architects of Korea
• /
• v.46 no.6
• /
• pp.650-658
• /
• 2009

Two dimensional sloshing phenomena in regularly excited liquid cargo tank are numerically simulated with finite difference method. Navier-Stokes equations and continuity equation are computed for this study. The free-surface is determined every time step satisfying kinematic boundary condition using marker-density method. And the exciting force is treated by adding the acceleration of the tank to source term. The results are compared with other existing experiment results. And the comparison results show a good agreement. The sloshing phenomena in the tank of the 138K LNG carrier in sway motion is simulated with present calculation methods in low filling level. To find the relations between impact pressure and excitation condition, the calculations are performed in various amplitudes and periods. The averaged maximum pressures are compared each other.

• Journal of ILASS-Korea
• /
• v.26 no.1
• /
• pp.1-8
• /
• 2021

Droplet evaporation has been known as a common phenomenon in daily life, and it has been widely used for many applications. In particular, the influence of the different heated substrates on evaporation flux and flow characteristics is essential in understanding heat and mass transfer of evaporating droplets. This study aims to simulate the droplet evaporation process by considering variation of thermal property depending on the substrates and the surface temperature. The commercial program of ANSYS Fluent (V.17.2) is used for simulating the conjugated heat transfer in the solid-liquid-vapor domains. Moreover, we adopt the diffusion-limited model to predict the evaporation flux on the different heated substrates. It is found that the evaporation rate significantly changes with the increase in substrate temperature. The evaporation rate substantially varies with different substrates because of variation of thermal property. Also, the droplet evaporates more rapidly as the surface temperature increases owing to an increase in saturation vapor pressure as well as the free convection effect caused by the density gradient.

• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.35 no.3
• /
• pp.43-52
• /
• 2003

The new principle to measure a sizing degree by a contact angle was developed using an automatic determination of the 3-end point coordinates of the water droplet on a sheet, which could diminish the operator's bias during measurement. A constant amount of water was first placed on a sample sheet by a water dispenser, and then an image of the liquid droplet was captured by a digital camera and then transmitted to a computer. The program measuring for contact angle extracted a liquid contour by Gaussian function combined with a 8-direction chain code. The Euclidean equation was applied to the binary image of the liquid contour in order to measure the diameter of the contour. Finally, the contact angle of the liquid was calculated by using the diameter and the top coordinates. In addition, a surface free energy of the sample sheet and an elapsed time taken up to the complete absorption into the sheet were simultaneously measured with the contact angle.

• Journal of the Korean Society of Safety
• /
• v.19 no.3 s.67
• /
• pp.108-117
• /
• 2004

Dynamic analysis method is Presented for analyzing rectangular liquid storage structures excited by horizontal and vertical ground motions. The irrotational motion of invicid and incompressible ideal fluid in rigid rectangular liquid storage structures subjected to horizontal and vertical ground motions and the motion of fluid induced by structural deformation are expressed by analytic solutions. Analysis methods are obtained by applying analytic solutions of the fluid motion to finite element equation of the structural motion. The fluid-structure interaction effect is reflected into the coupled equation as added fluid mass matrix. The free surface sloshing motion, hydrodynamic pressure acting on the wall and structural behavior due to horizontal and vertical ground motions are obtained by the presented method.

• Proceedings of the Earthquake Engineering Society of Korea Conference
• /
• 1997.04a
• /
• pp.115-127
• /
• 1997

A study to evaluate the seismic response of $\frac{1}{2}$-scaled liquid storage tank constructed in Hualien, is performed. And this study is to identify the liquid-structure-soil interaction by observed earthquake data ans analyzed results. After the calculation of soil impedance for the test site by SASSI code, 3-dimensional seismic response analysis is performed by BEM-FEM-Impedance Method with the consideration of liquid-structure-soil interaction when the tank is excited by real earthquake. The observed acceleration and hydrodynamic pressure are compared with the numerical results. This comparisons show good agreement in predominant frequency and maximum hydrodynamic pressure. And the free surface sloshing motion due to earthquake loadings is computed in time domain.

• International Journal of Aerospace System Engineering
• /
• v.2 no.2
• /
• pp.34-39
• /
• 2015

Experimental studies were conducted on the liquid sloshing characteristics in a spherical tank covered with a flexible membrane. A spherical acrylic tank with 145.2 mm in radius was used as a test tank, and it was half-filled with water. Silicon membranes with 0.2 mm thickness were used as a test membrane with plane or hemispherical types. The test tank was harmonically excited in a vertical direction by an electro-dynamic exciter. In this case, a parametric instability vibration comes up when the excitation frequency is twice the natural frequency. Parametric instability regions of natural modes were measured for three cases, i.e. liquid surface is free, covered with plane membrane and hemi-spherical membrane.

• Journal of the Korean Society for Precision Engineering
• /
• v.30 no.9
• /
• pp.1001-1006
• /
• 2013

Projection-based stereolithography is divided into constrained-surface and free-surface type according to controlling liquid layer. The constrained-surface type has a uniform layer thickness due to the use of a projection window, which covers the pattern generator such as liquid crystal display. However, the adhered resin on the projection window causes trouble and requires great separation force when the cured layer is separated from the window. To minimize the separation force, we developed a system to measure the separation force. The influence of material covering the pattern generator and the resin temperature is investigated in the system. Several structures according to the resin temperature and the velocity of z-axis elevation are compared. As a result, the fabrication condition to minimize the separation force reduces the process time.

• International Journal of Ocean System Engineering
• /
• v.2 no.1
• /
• pp.32-36
• /
• 2012

This paper presents a comparison of potential and viscous computational codes for the water entry problem. A po-tential code was developed which adopted the boundary element method to solve the problem. A nonlinear free surface boundary condition was integrated to find new locations of free surface. The dynamic boundary condition was simplified by taking constant potential values for every time steps. The simplified dynamic boundary condition was applied in the new position of the free surface not at the mean level, which is the usual practice for linearized theory. The commercial code FLUENT was used to solve the water entry problem from the viscosity point of view. The movement of the air-liquid interface is traced by distribution of the volume fraction of water in a computational cell. The pressure coefficients were compared with each other, while experimental results published by other researchers were also examined. The characteristics of each method were discussed to clarify merits and limitations when they were applied to the water entry problems.

• Advances in aircraft and spacecraft science
• /
• v.10 no.5
• /
• pp.439-455
• /
• 2023

Free surface fluid oscillation in prolate spheroidal tanks has been investigated analytically in this study. This paper aims is to investigate the sloshing frequencies in spheroidal prolate tanks and compare them with conventional cylindrical and spherical containers to select the best tank geometry for use in space launch vehicles in which the volume of fuel is very high. Based on this, the analytical method (Fourier series expansion) and potential fluid theory in the spheroidal coordinate system are used to extract and analyze the governing differential equations of motion. Then, according to different aspect ratios and other parameters such as filling levels, the fluid sloshing frequencies in the spheroidal prolate tank are determined and evaluated based on various parameters. The natural frequencies obtained for a particular tank are compared with other literature and show a good agreement with these results. In addition, spheroidal prolate tank frequencies have been compared with sloshing frequencies in cylindrical and spherical containers in different modes. Results show that when the prolate spheroidal tank is nearly full and in the worst case when the tank is half full and the free fluid surface is the highest, the prolate spheroidal natural frequencies are higher than of spherical and cylindrical tanks. Therefore, the use of spheroidal tanks in heavy space launch vehicles, in addition to the optimal use of placement space, significantly reduces the destructive effects of sloshing.