• Title/Summary/Keyword: Liquid air

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An Analytical Method of Formaldehyde in Exhaust Gases from Industrial Facilities using a HPLC under Isocratic Conditions (Isocratic 조건하에서 HPLC를 이용한 산업시설 배출가스 중 포름 알데하이드 분석)

  • Kim, Jun-Pyo;Park, Seung-Shik;Bae, Min-Suk
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.4
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    • pp.616-624
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    • 2018
  • In this study, a previous DNPH (2,4-dinitrophenylhydrazine) coupled with high performance liquid chromatography (HPLC) method to measure the concentration of formaldehyde in ambient and source environments has been improved. To improve the disadvantage of the previous HPLC method, an appropriate composition ratio of mobile phase (water: acetonitrile (ACN)) was determined and an isocratic analysis was conducted. Furthermore, limit of detection (LOD), limit of quantitation(LOQ), accuracy, and precision were investigated to verify the reliability of the analytical conditions determined. Finally, samples of exhaust gases from five different industrial facilities were applied to HPLC analytial method proposed to determine their formaldehyde concentrations. The appropriate composition ratio of the mobile phase under the isocratic condition was a mixture of water(40%) and ACN(60%). As the volume fraction of the organic solvent ACN increases, retention time of the formaldehyde peak was reduced. Detection time of formaldehyde peak determined using the proposed isocratic method was reduced from 7 minutes(previous HPLC method) to approximately 3 minutes. LOD, LOQ, accuracy, and precision of the formaldehyde determined using standard solutions were 0.787 ppm, 2.507 ppm, 93.1%, and 0.33%, respectively, all of which are within their recommended ranges. Average concentrations of the formaldehyde in five exhaust gases ranged from 0.054 ppm to 1.159 ppm. The lowest concentration (0.054 ppm) was found at samples from waste gas incinerator in a bisphenol-A manufacturing plant. The highest was observed at samples from the absorption process in manufacturing facilities of chemicals including formaldehyde and hexamine. The analytical time of the formaldehyde in ambient air can be shortened by using the isocratic analytical method under appropriate mobile phase conditions.

Analysis of Measuring Error for Particle Size Analysis by Laser Diffraction Spectrometer (입자크기분석을 위한 레이저회절 분광계의 측정오차 분석)

  • Ha, Sang-An;Son, Heui-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.4
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    • pp.713-722
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    • 2000
  • This study analysed error of measurement and reproducibility for particle size analysis by the laser diffraction spectrometer. Laser diffraction spectrometers has become a very important method of particle size analysis. This measuring method has the advantage of simple operation, good reproducibility and rapid analysis. A feeding and dispersing system have been developed, which allows mass throughputs between 0.1~23 g/min in flowing air and 1.4~35% in flowing liquid. It has been used as a feeder unit for wet and dry particle size analysis from diffraction patterns. Relevant parameters, such as particle shape, particle size, dispersion, flow rate, concentration were analysed for measuring error. And system parameters of instruments for measurement of dynamic processes, eg, measuring time, focal plane, injection pressure drop and dispersion effect by the ultrasonic and mixing of preliminary treatment, were also discussed.

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Disinfection Properties and Variation in the Ozone Concentration in Seawater Generated Using a Low-Temperature Dielectric Barrier Discharge Plasma Reactor (저온 유전체장벽 플라즈마로 생성된 해수중의 오존농도 변동과 살균 특성)

  • Lee, Young Sik;Kim, Yoonbin;Kim, Kwang Seog;Han, Hyung-Gyun
    • Journal of Environmental Science International
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    • v.21 no.10
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    • pp.1181-1186
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    • 2012
  • We studied the ozone concentrations generated by low-temperature dielectric barrier discharge plasma reactor after adding air and phytoplankton to control the ozone concentrations in seawater. We also examined the numbers of bacteria and Vibrio spp. after treatment using the plasma reactor. As the airflow rate was increased, more ozone was removed. Although marked variation in the ozone decrease was observed with and without airflow, the rate of ozone removal did not increase proportionately with the airflow rates. The ozone concentration decreased with increasing organic matter and time. The amount of organic matter seems to be an important factor decreasing the dissolved ozone concentration in liquid. The ozone concentration was 0.07, 0.32, 1.28, and 2.3 mg/L when operating the plasma reactor for 30, 60, 180, and 300 s, respectively; i.e., the ozone concentration increased with the reactor operating time. The initial numbers of bacteria and Vibrio spp. were 800 and 480 CFU/mL, respectively. After operating the plasma reactor at a flow rate of 6 L/min for 30 s, no bacteria or Vibrio spp. were detected. The disinfection effect of this plasma reactor seems to be superior to that of a conventional ozone generator.

Development of Equipment and Process on Dry Ice Blasting (드라이아이스 펠렛 세정 장치 및 공정개발)

  • Park, Jong Soo;Kim, Hotae;Kim, Sun-Geon
    • Clean Technology
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    • v.10 no.3
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    • pp.121-130
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    • 2004
  • Pelletizer of dry ice snow produced by adiabatic expansion of liquid carbon dioxide and their blaster were designed and manufactured. The blaster had a high cleaning power against various contaminants on the surface such as stain, oily dirt, lacquer film and paints with low blasting pressure and low consumption of blasting air. The capacity of hopper for dry ice pellet supply was 12 kg and the mass rate of pellet blasting was controlled in 0 to 1.2 kg/min. The impact of the pellets was independent of standoff distance within a certain limiting distance, and dependent on the impact stress, angle and mass rate of dry ice pellet blasting. On the other hand the cleaning power was influenced by thermal properties and surface roughness of the substrates and decreased in the order of glass, copper, brass, steel and acryl. The power was also affected by hardness and adhesion of the contaminant on the substrate, and decreased in the order of grease, epoxy and paint. The noise was detected during blasting in the range of 85 to 100dBA.

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PVDF/h-BN hybrid membranes and their application in desalination through AGMD

  • Moradi, Rasoul;Shariaty-Niassar, Mojtaba;Pourkhalili, Nazila;Mehrizadeh, Masoud;Niknafs, Hassan
    • Membrane and Water Treatment
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    • v.9 no.4
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    • pp.221-231
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    • 2018
  • A new procedure to produce poly(vinylidene fluoride)/boron nitride hybrid membrane is presented for application in membrane distillation (MD) process. The influence of hexagonal boron nitride (h-BN) incorporation on the performance of the polymeric membranes is studied through the present investigation. For this aim, h-BN nanopowders were successfully synthesized using the simple chemical vapor deposition (CVD) route and subsequent solvent treatments. The resulting h-BN nanosheets were blended with poly(vinylidene fluoride) (PVDF) solution. Then, the prepared composite solution was subjected to phase inversion process to obtain PVDF/h-BN hybrid membranes. Various examinations such as scanning electron microscopy (SEM), wettability, permeation flux, mechanical strength and liquid entry pressure (LEP) measurements are performed to evaluate the prepared membrane. Moreover, Air gap membrane distillation (AGMD) experiments were carried out to investigate the salt rejection performance and the durability of membranes. The results show that our hybrid PVDF/h-BN membrane presents higher water permeation flux (${\sim}18kg/m^2h$) compared to pristine PVDF membrane. In addition, the experimental data confirms that the prepared nanocomposite membrane is hydrophobic (water contact angle: ${\sim}103^{\circ}$), has a porous skin layer (>85%), as well competitive fouling resistance and operational durability. Furthermore, the total salt rejection efficiency was obtained for PVDF/h-BN membrane. The results prove that the novel PVDF/h-BN membrane can be easily synthesized and applied in MD process for salt rejection purposes.

Numerical Investigation of the Effect of IR Heating on Drying Mechanism in a Tumble Dryer (열복사를 적용한 드럼 건조기의 건조 메커니즘 분석 및 성능 예측에 관한 연구)

  • Choi, Chul-Jin;Jang, Jung-Hyun;Kim, Chong-Min;Kim, Man-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.3
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    • pp.219-228
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    • 2010
  • A two-dimensional mathematical model was developed to predict the temperature and moisture-content profiles of a tumble dryer during infrared drying. The model is based on the movements of liquid water and moisture in the object and on the fluid and heat transfer in the drying air. The model was solved by the finite volume analysis for the fluid, temperature, and radiation intensity fields. After deriving the governing equations and developing the two-dimensional tumble dryer models, numerical investigations were carried out to examine the effects of various parameters such as the heater temperature and the heating patterns on the drying mechanism of the tumble dryer. All the results show that the drying time can be reduced by using the IR heater.

Study on Correspondent of Astrology and Jung's Psychological Types -Focused on earth, water, fire and wind(Four major factors)- (천문 점성학과 융의 심리학적 유형과의 연관성 -지수화풍(地水火風) 4대(四大)와의 관계를 중심으로-)

  • Lee, Yong-Chol;Kim, Byung-Soo;Kang, Jung-Soo
    • Journal of Haehwa Medicine
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    • v.18 no.1
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    • pp.117-127
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    • 2009
  • Study on correspondent of eastern and western astrology and Jung's psychological types, we obtain as follow as results. Western astrology is transmitted from China and developed, it influenced on the study of the Four Pillars(四柱學). Comparing assemble, gathering, punishment, destruction, collision, impair of Di-zhi(地支) in the study of Four Pillars with Xing-gong theory(星宮論) in the western astrology, can get the result that the Pillars study has close connection with astronomy and astrology. When we compared Jung's psychological types with astrology, the five elements(五行) and the four major factors, can be summarized like this. (1) intuition-fire sign-wood and fire-fire in the four major factors(四大), (2) sensation-earth sign-earth and metal-earth in the four major factors, (3) thinking-air sign-metal and water-wind in the four major factors, (4) feeling-water sign-water and wood-water in the four major factors. The four major factors of Buddhism is now understood as, earth, water and fire represent the state of solid(earth), liquid(water), gas(fire) and wind can be recognized as energy source help the changes. This is mentioned throughout the books, but only arranging the theory of four major factors.

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A Study on the Sloshing of Cargo Tanks Including Hydroelastic Effects (유탄성을 고려한 탱크내 슬로싱에 대한 연구)

  • Dong-Yeon Lee;Hang-Shoon Choi
    • Journal of the Society of Naval Architects of Korea
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    • v.35 no.4
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    • pp.27-37
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    • 1998
  • The sloshing is very important in a safe transport of the liquid cargo by a ship. With the increasing number of supertanker and LNG carriers, this problem has become increasingly more important. In order to study the magnitude and characteristics of impact pressures due to sloshing, experiments ware performed with a rectangular tank and compared with numerical results. Structural responses of tank wall under impulsive pressures were measured. Structural vibrations induced by the sloshing load were analysed by including hydroelastic erects in terms of added mass and damping. To check the validity of the numerical model, the natural frequencies of plate in air and water were compared with measurements, and a good agreement was found. In the case that a plate vibrates under impulsive loads, the pressure on the flexible plate is larger than that on the rigid plate without hydroelastic effects, which was confirmed experimentally. The frequency of oscillatory pressure as well as accel%pion coincides with the natural frequency of plate in water.

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Design of gas suspension absorber to improve desulfurization efficiency

  • Hwang, Woohyeon;Lee, Kyung-Ok
    • Journal of the Korea Society of Computer and Information
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    • v.25 no.2
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    • pp.189-195
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    • 2020
  • In this study, the inlet duct and guide vane of the gas floating absorption tower were redesigned to improve the desulfurization efficiency so that the exhaust gas can be uniformly introduced into the absorption tower. In order to reduce the sulfur oxide pollutants among the main sources of air pollutants in industrial boilers, the existing equipment is redesigned and solved. For this purpose, change the exhaust gas, the slurry and recycling the adsorbent to improve the removal efficiency of SOx component in the exhaust gas inside the gas floating absorption tower so as to uniformly contact. And the initial design value and CFD value for the pressure loss from the boiler outlet to the gas floating absorption tower outlet are verified. Also, the velocity distribution of the exhaust gas, the concentration distribution of the recycled adsorbent, the liquid slurry behavior, and the pressure loss were compared. The results confirmed that the desulfurization efficiency was improved because the pressure loss from the boiler outlet to the absorption tower outlet was reduced and the deflection of the exhaust gas was minimized.

An Experimental Investigation of the Effect of the Entrance Shape of Sudden Contraction on Single and Two-Phase Pressure Drop in Horizontal Air-Water Flow (공기와 물의 수평유동에 있어 관의 급격한 입구축소 모양이 단상 및 이상유 압력강하에 미치는 영향에 관한 실험적 연구)

  • Chun, Moon-Hyun;Baek, Joo-Seok;Park, Jong-Ryul
    • Nuclear Engineering and Technology
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    • v.21 no.2
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    • pp.123-133
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    • 1989
  • The pressure drops through contractions in horizontal single and two-phase flow were investigated. A total of 167 measurements were made for four different entrance shapes to study the effects of the entrance shape on the pressure drop through a contraction in horizontal single and two-phase flow. From this data, pressure drops were calculated and compared with the pressure drops predicted by analytical models for single and two-phase flow. For single phase How the agreement between the data and predictions is within $\pm$25%, whereas for two-phase flow Hoopes model, which gives a better agreement than the homogeneous model, underpredicts the data as much as 45% In addition, the effects of void fraction and liquid phase mass velocity on the pressure drop through the sudden How channel contraction were investigated for two-phase flow.

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