• 제목/요약/키워드: Liquid air

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노후 운행경유차의 NOx 배출특성분석 및 조기폐차대책을 통한 삭감 방안 검토 (Evaluation of Accelerated Retirement Program for In-use Diesel Vehicles based on their NOx Emission Characteristics)

  • 길지훈;임윤성;김형준;노현구;윤보섭;이상은;이태우;김정수;최광호
    • 한국분무공학회지
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    • 제22권3호
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    • pp.122-128
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    • 2017
  • Currently, the proportion of diesel vehicles in all automobile has grown significantly over the past few years. Air pollutant also grew up and became a social problem. In particular, the issue of NOx emissions caused by NOx high emission in real driving has become a global issue. Despite the fact that the regulatory and reduction project of the new vehicle is actively carried out, there are no existence regulations of In-use diesel vehicle's NOx emission. Therefore, the emission characteristics of the in-use diesel vehicles were investigated to seek ways to reduce NOx emissions in this study. The test targets were used in 237 close inspection of exhaust gases and model year varied from 1996 to 2011. However, the classification of emissions by emission standards differed considerably from NOx emissions. This means that the selection method for early retirement targets should be converted from model year to amount of emissions. If the current early retirement program was applied to the existing system, pre-Euro 3 was 22.530 g/km and Euro 4 was 21.810 g/km to NOx reduction. However, when the vehicle was changed to high emission target vehicle, NOx reduction increase maximum 84.705 kg/yr. According to the study results, an effective reduction in NOx emissions can be achieved if an earlier target in expanded to Euro 4 vehicles.

Waste Reuse in Sugar Industries

  • Ansari, Abdul Khalique
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.122-131
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    • 2001
  • Pakistan being the 6$^{th}$ largest sugar producer has over 75 sugar mills with annual production capacity of about 2.4 million tons during 1996-97. The contribution of Sindh with 27 sugar mills is recorded over 50% of the total sugar production. The majority of the mills in Pakistan use the Defecation-Remelt-Phosphitation (DRP; 24 mills), Defecation-Remelt-Carbonation (DRC; 21 mills) and Defecation-Remelt Carbonation and Sulphitation (DRCS; 11 mills) process. Seven of the 75 sugar mills in Pakistan also produce industrial alcohol from molasses, a by- product of sugar manufacturing process. These sugar industries also produce fly ash, which have been found to contain unburned carbon and reach as far as four-kilo meter area with the wind direction, threatening the community health of people living around, besides posing other aesthetic problems. The untreated wastewater, in many cases, finds its way to open surface drains causing serious threat to livestock, flora and fauna. One study showed that fly ash emitted from the chimneys contain particle size ranging from 38 ${\mu}{\textrm}{m}$ to 1000 ${\mu}{\textrm}{m}$. About 50 per cent of each fly ash samples were above 300 ${\mu}{\textrm}{m}$ in size and were mostly unburned Carbon particles, which produced 85% weight loss on burning in air atmosphere at 1000${\mu}{\textrm}{m}$. This fly ash (mostly carbon) was the main cause of many health and aesthetic problems in the sugar mill vicinity. The environmental challenge for the local sugar mills is associated with liquid waste gaseous emission and solid waste. This paper discusses various waste recycling technologies and practices in sugar industries of Pakistan. The application of EM technology and Biogas technology has proved very successful in reusing the sugar industry wastewater and mud, which otherwise were going waste.

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회전된 엇갈린 격자를 이용한 탄성파 모델링에의 CPML 경계조건 적용 (Application of Convolutional Perfectly Matched Layer Method to Numerical Elastic Modeling Using Rotated Staggered Grid)

  • 조창수;이희일
    • 지구물리와물리탐사
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    • 제12권2호
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    • pp.183-191
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    • 2009
  • 탄성파 수치 모형 계산에 있어서 널리 사용되는 엇갈린 격자 방법이 아니라 회전된 엇갈린 격자 방법을 사용하여 탄성파 수치 모사를 수행하였다. 표준 엇갈린 격자 방법에서는 특별한 자유 경계조건을 적용하여야 하는 단점이 있지만 회전된 격자 방법에서는 물성으로 진공 또는 공기층을 부여함으로써 자유 경계조건을 실현가능하다는 것을 확인할 수 있었다. 파동전파에 있어서 유한 경계 조건에서 발생하는 인공 반사파를 제거하기 위해 PML (Perfectly Matched Layer)의 파동식 분해라는 단점을 극복할 수 있고 좋은 성능을 보이는 CPML (Convolutional Perfectly Matched Layer)법을 회전된 엇갈린 격자법(RSG: Rotatged Staggered Grid)에 적용하였다. 회전된 격자 유한 차분법에서 CPML의 고주파수 흡수 특성과 에너지 흡수율 조사, Cerjan법의 감쇠를 비교한 결과 흡수경계조건으로 좋은 성능을 확인하였다. 유체와 고체의 모형에 대한 경계에 대하여서도 매우 효과적으로 경계면에서 발생하는 반사파를 제거할 수 있음을 알 수 있었다.

Qualitative and quantitative analysis of furosine in fresh and processed ginsengs

  • Li, Yali;Liu, Xiaoxu;Meng, Lulu;Wang, Yingping
    • Journal of Ginseng Research
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    • 제42권1호
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    • pp.21-26
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    • 2018
  • Background: Furosine (${\varepsilon}$-N-2-furoylmethyl-L-lysine, FML) is an amino acid derivative, which is considered to be an important indicator of the extent of damage (deteriorating the quality of amino acid and proteins due to a blockage of lysine and a decrease in the digestibility of proteins) during the early stages of the Maillard reaction. In addition, FML has been proven to be harmful because it is closely related to a variety of diseases such as diabetes. The qualitative analysis of FML in fresh and processed ginsengs was confirmed using HPLC-MS. Methods: An ion-pair reversed-phase LC method was used for the quantitative analysis of FML in various ginseng samples. Results: The contents of FML in the ginseng samples were 3.35-42.28 g/kg protein. The lowest value was observed in the freshly collected ginseng samples, and the highest value was found in the black ginseng concentrate. Heat treatment and honey addition significantly increased the FML content from 3.35 g/kg protein to 42.28 g/kg protein. Conclusion: These results indicate that FML is a promising indicator to estimate the heat treatment degree and honey addition level during the manufacture of ginseng products. The FML content is also an important parameter to identity the quality of ginseng products. In addition, the generation and regulation of potentially harmful Maillard reaction products-FML in ginseng processing was also investigated, providing a solid theoretical foundation and valuable reference for safe ginseng processing.

Urinary Trans, Trans-Muconic Acid is Not a Reliable Biomarker for Low-level Environmental and Occupational Benzene Exposures

  • Jalai, Amir;Ramezani, Zahra;Ebrahim, Karim
    • Safety and Health at Work
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    • 제8권2호
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    • pp.220-225
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    • 2017
  • Background: Benzene is a known occupational and environmental pollutant. Its urinary metabolite trans, trans-muconic acid (tt-MA) has been introduced by some environmental and occupational health regulatory associations as a biological index for the assessment of benzene exposure; however, recently, doubts have been raised about the specificity of tt-MA for low-level benzene exposures. In the present study, we investigated the association between urinary levels of tt-MA and inhalational exposure to benzene in different exposure groups. Methods: Benzene exposure was assessed by personal air sampling. Collected benzene on charcoal tube was extracted by carbon disulfide and determined by a gas chromatograph (gas chromatography with a flame ionization detector). Urinary tt-MA was extracted by a strong anion-exchange column and determined with high-performance liquid chromatography-UV. Results: Urinary levels of tt-MA in intensive benzene exposure groups (chemical workers and police officers) were significantly higher than other groups (urban and rural residents), but its levels in the last two groups with significant different exposure levels (mean = 0.081 ppm and 0.019 ppm, respectively) showed no significant difference (mean = $388{\mu}g/g$ creatinine and $282{\mu}g/g$, respectively; p < 0.05). Before work shift, urine samples of workers and police officers showed a high amount of tt-MA and its levels in rural residents' samples were not zero. Conclusion: Our results suggest that tt-MA may not be a reliable biomarker for monitoring low-level (below 0.5 ppm) benzene exposures.

Exposure and Risk Assessment of Operators to Insecticide Acetamiprid during Treatment on Apple Orchard

  • Kim, Eunhye;Moon, Joon-Kwan;Lee, Hyeri;Kim, Suhee;Hwang, Yon-Jin;Kim, Byung-Joon;Lee, Jinbeum;Lee, Dong-Hyuk;Kim, Jeong-Han
    • 원예과학기술지
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    • 제31권2호
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    • pp.239-245
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    • 2013
  • Occupational exposure and risk assessment were conducted to evaluate the safety of operators when insecticide acetamiprid was applied to apple orchard using a speed sprayer. Dermal patches, cotton gloves, socks, and masks were used to monitor the dermal exposure, and personal air pump with solid sorbent was used to measure the potential inhalation exposure. In validation to analytical methods, the limit of detection and limit of quantitation were 0.25 ng and 1 ng, respectively. Good reproducibility (coefficient variation < 4%), linearity (coefficient determination > 0.999), and recovery (85.3-118.2%) were obtained. Trapping efficiency of solid sorbent was 96.4% while breakthrough did not occur. Only hand exposure was measured on the gloves during mixing/loading to give $33-1,132{\mu}g$. Exposure amount of operator 3 among 4 workers was noticeably high. The total volumes of spray liquid for operators were $535-1,235mL{\cdot}h^{-1}$, corresponding to 0.03-0.08% of the applied spray solution. Highest contaminated parts of body were thighs, chest, and lower legs. The inhalation exposure ratio to the total application amount was significantly low. However, wind seemed to affect the inhalation exposure of operator. For risk assessment, margin of safety was calculated by the application of cloth and dermal penetration rate to obtain values of much larger than 1 in all cases. Therefore, health risk of operators during treatment of acetamiprid in apple orchard could be of least possibility.

Si 첨가강의 Descaling 특성에 미치는 강조성 및 가열온도의 영향 (Effects of Composition and Temperature on the Descaling Characteristics in Si Containing Steel)

  • 최진원;권순주
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2004년도 제5회 압연심포지엄 신 시장 개척을 위한 압연기술
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    • pp.277-284
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    • 2004
  • Low carbon steels containing Si of up to $1.2\;wt\%$ were oxidized in air at 1373 K and 1523 K, i.e. below and above the eutectic temperature of FeO and $Fe_2SiO_4$. The influence of a impurity element, S on behavior of scale formation during oxidation was investigated by using $M\"{o}chssbauer$ spectroscopy and EDS. This allowed establishment of an interface oxidation model of Si-added steel depending on temperature and an impurity element. A compound of FeO and FeS was formed in the scale/matrix interface of low carbon steels containing S of up to $0.03\;wt\%$ oxidized above 1213 K of the eutectic temperature. This was flat formed between $Fe_2SiO_4$ nodules along the scale/matrix interface without selective oxidation. It is due to low viscosity and high wettability of the compound of FeO and FeS in liquid. Conventional metallographic examinations revealed that roughness of the scale/matrix interface in Si-added steels became flat as the content of S increased. It was independent of oxidizing temperature and Si content. Effects of oxidizing temperature and an impurity element content on descaling characteristics in Si-added steels were evaluated by using a hydraulic descaling simulator. Good descaling characteristics was attributable to this flatness of the scale/matrix interface.

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APPLICATION OF 3D TERRAIN MODEL FOR INDUSTRY DISASTER ASSESSMENT

  • Kim, Hyung-Seok;Cho, Hyoung-Ki;Chang, Eun-Mi;Kim, In-Hyun;Kim, In-Won
    • 대한원격탐사학회:학술대회논문집
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    • 대한원격탐사학회 2008년도 International Symposium on Remote Sensing
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    • pp.3-5
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    • 2008
  • An increase in oil and gas plants caused by development of process industry have brought into the increase in use of flammable and toxic materials in the complex process under high temperature and pressure. There is always possibility of fire and explosion of dangerous chemicals, which exist as raw materials, intermediates, and finished goods whether used or stored in the industrial plants. Since there is the need of efforts on disaster damage reduction or mitigation process, we have been conducting a research to relate explosion model on the background of real 3D terrain model. By predicting the extent of damage caused by recent disasters, we will be able to improve efficiency of recovery and, sure, to take preventive measure and emergency counterplan in response to unprepared disaster. For disaster damage prediction, it is general to conduct quantitative risk assessment, using engineering model for environmental description of the target area. There are different engineering models, according to type of disaster, to be used for industry disaster such as UVCE (Unconfined Vapour Cloud Explosion), BLEVE (Boiling Liquid Evaporation Vapour Explosion), Fireball and so on, among them, we estimate explosion damage through UVCE model which is used in the event of explosion of high frequency and severe damage. When flammable gas in a tank is released to the air, firing it brings about explosion, then we can assess the effect of explosion. As 3D terrain information data is utilized to predict and estimate the extent of damage for each human and material. 3D terrain data with synthetic environment (SEDRIS) gives us more accurate damage prediction for industrial disaster and this research will show appropriate prediction results.

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토양 내 PCE 제거과정에서 가스 분배추적자기법을 이용한 공기노출 PCE의 잔류량 검출 (Measurement of Gas-Accessible PCE Saturation in Unsaturated Soil using Gas Tracers during the Removal of PCE)

  • 김헌기;권한준;송영수
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제16권5호
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    • pp.42-52
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    • 2011
  • In this laboratory study, the changes in gas-exposed perchloroethene (PCE) saturation in sand during a PCE removal process were measured using gaseous tracers. The flux of fresh air through a glass column packed with PCEcontaminated, partially water-saturated sand drove the removal of PCE from the column. During the removal of PCE, methane, n-pentane, difluoromethane and chloroform were used as the non-reactive, PCE-partitioning, water-partitioning, and PCE and water-partitioning tracers, respectively. N-pentane was used to detect the PCE fraction exposed to the mobile gas. At water saturation of 0.11, only 65% of the PCE was found to be exposed to the mobile gas prior to the removal of PCE, as calculated from the n-pentane retardation factor. More PCE than that detected by n-pentane was depleted from the column due to volatilization through the aqueous phase. However, the ratio of gas-exposed to total PCE decreased on the removal of PCE, implying gas-exposed PCE was preferentially removed by vaporization. These results suggest that the water-insoluble, PCE-partitioning tracer (n-pentane in this study), along with other tracers, can be used to investigate the changes in fluid (including nonaqueous phase liquid) saturation and the removal mechanism during the remediation process.

불포화지반에 대한 열-수리-역학 거동의 수식화 (Formulation of Fully Coupled THM Behavior in Unsaturated Soil)

  • 신호성
    • 한국지반공학회논문집
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    • 제27권3호
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    • pp.75-83
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    • 2011
  • 일반적인 불포화지반의 거동뿐만 아니라, 열과 관련된 분야, 지반환경 분야 등 다양한 분야에서 불포화 다공질 재료의 열적-수리적-역학적으로 결합된 문제들이 대두되면서 이러한 문제들을 해석하기 위한 수치도구 개발의 필요성이 대두되고 있다. 본 논문에서는 거시적 접근법(macroscopic approach)에 근거하여 불포화지반에 대한 열-수리-역학거동의 수식화를 하였다. 흙, 물, 공기에 대한 질량보존의 법칙, 에너지 보존법칙, 그리고 하중평형 조건식으로부터 결합된(coupled) 4개의 지배방정식을 유도하였다. Galerkin 간략화와 시간적분으로부터 주 변수인 변위(u), 가스압($P_g$), 유체압($P_1$), 온도(T)를 Newton의 반복과정을 이용하여 구하는 유한요소 프로그램(FEM)을 작성하였다. 개발된 프로그램을 이용하여 다공질재료에서 2상 흐름 문제 중 일차원 배수실험(u-$P_g-P_1$), 온도 압밀(u-$P_1$-T), 그리고 지표면 온도변화에 의한 말뚝의 주변지반에 대한 영향(u-$P_1$-T)에 대하여 수치해석을 수행하고 논의하였다.