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Preparation of Si(Al)ON Precursor Using Organoaluminum Imine and Poly (Phenyl Carbosilane), and the Compositional Change of the Film with Different Heat Treatment Condition

  • Lee, Yoonjoo;Shin, Dong-Geun;Kwon, Woo Teck;Kim, Soo Ryong;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.52 no.4
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    • pp.243-247
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    • 2015
  • Si(Al)ON precursor was synthesized by formation of new Si-N bond using organoaluminum imine and liquid type poly(phenyl carbosilane). It was decomposed between $200-600^{\circ}C$, and the ceramic yield was 51% after pyrolysis. 150 - 200 nm in thickness of coating film was obtained by spin coating method. The precursor was easily oxidized during process because it was unstable in air. However the oxygen content was limited to 0.5 - 0.7 to silicon in heat treatment step. Even though the content of nitrogen was decreased by pyrolysis, Al-N and Si-N bonds were formed in ammonia atmosphere, and Si(Al)ON film was formed with 0.2 in content to silicon.

Estimating On-road NOx Emissions of Euro 6 Light-duty Diesel Vehicles (Euro6 소형 경유자동차의 실제 도로 주행 NOx 배출량 평가)

  • Park, Yeon-Jae;Park, Junhong;Lee, Jai-Young
    • Journal of ILASS-Korea
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    • v.21 no.4
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    • pp.207-213
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    • 2016
  • To protect air pollution of urban area from motor vehicles, emission limits for diesel vehicles have been dramatically lowered in short period. But recent studies have shown that on-road NOx emissions of light-duty diesel vehicles are considerably higher than the values measured with laboratory test procedures used for emission certification. To tackle with this issue, Ministry of Environment have a plan to introduce EU RDE-LDV (Real-driving Emission-Light-duty Vehicle) regulation. In this study, 4 Euro 6 diesel vehicles have been tested with the new test procedures published by EU to estimate on-road NOx emissions using PEMS (Portable Emission Measurement System). The results have shown that the requirements of EU RDE-LDV could be met in driving condition of metropolitan area for constitution of test routes and validity of test results. In analysing with Moving Averaging Window method the completeness and normality of test data were validated with the requirement. On-road NOx emissions were quite deviated as test vehicles and higher than the new limit of on-road NOx emission enforced from Sept. 2017, which means that RDE-LDV can effectively reduce NOx emission of diesel vehicles in real driving conditions of Korea.

Air Pollutant Emission Characteristics of a Light Duty Diesel Vehicle Affected by Road Infrastructure Improvement and Traffic flow Changes (도로 기반시설 개선과 교통흐름 변화에 따른 소형 경유자동차의 대기오염물질 배출특성)

  • keel, Jihoon;Lee, Taewoo;Lee, Sangeun;Jung, Sungwoon;Yun, Boseop;Kim, Jeongsoo;Choi, Kwangho
    • Journal of ILASS-Korea
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    • v.21 no.4
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    • pp.214-222
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    • 2016
  • Changes in road infrastructure affect driving patterns and pollutant emission characteristics. we analyzed the changes in driving patterns and pollutant emission characteristics of the driving route via measured driving patterns at year 2009 and 2016. Since 2009, there has been an increase in population and traffic demand, including residential areas and industrial facilities. Traffic conditions were improved such as the opening of the highway Inter-Change to Seoul and the construction of underground driveway. As a result, the average vehicle speed increased. More detail comparisons have made on the changes of the underground driveway section and the crossroad section, which are expected to have significant changes in the transportation infrastructure. The vehicle speed distribution of the underground driveway changed from low speed to high speed, and the increase of the time spent at the high speed and high load caused the increase of NOx emissions. The vehicle speed also increased at the crossroad section, and the consequence NOx and $CO_2$ emissions decreased. It is mainly because the decreased time spent at idle, which results from the proper traffic demand management at this area.

Leidenfrost Points Tuned via Surface Coating and Structures

  • Jeon, Deok-Jin;Lee, Jun-Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.126.1-126.1
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    • 2015
  • A quantitative relationship between Leidenfrost point and surface characteristics such as surface material and roughness is investigated. Based on the relationship, we have fabricated the surfaces with their Leidenfrost points (LFP) tuned by controlling surface coating and structures. As discovered by Leidenfrost, liquids placed on a hot plate levitate on the gas phase-air gap formed by the vaporization of liquids. This phenomenon is called 'Leidenfrost effect'. A change of LFP has attracted many researchers for several years but the ability to tune LFP is still a remaining issue. Many of previous work has progressed for various conditions so the systematic approach and analysis are needed to clearly correlate the LFP and the surface conditions. In this report, we investigate a relation of surface energy and LFP using various coating materials such as Octadecyltrichlorosilane (OTS) and 1H, 1H, 2H, 2H-Perfluorooctyltrichlorosilane (FOTS). Also, we analyze how surface roughness affects LFP via surface micro structuring with ICP-RIE fabrication process. The improved understanding can have potential applications such as the control of liquid droplet behavior at elevated temperatures for efficient cooling system.

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Design and Performance Evaluation of a Faraday Cage and an Aerosol Charger (패러데이 케이지와 에어로졸 하전기의 설계 및 성능평가)

  • Ji, Jun-Ho;Bae, Kwi-Nam;Hwang, Jung-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.3
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    • pp.315-323
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    • 2004
  • An electrical cascade impactor is a multi-stage impaction device to separate airborne particles into aerodynamic size classes using particle charging and electrical detection techniques. A Faraday cage and an aerosol charger, which are basic components of the electrical cascade impactor, were designed and evaluated in this study. The low-level current response of the Faraday cage was investigated with changing particle size and air flow rate by using sodium chloride (NaCl) particles. The response of the prototype Faraday cage was very similar to that of a commercial aerosol electrometer (TSI model 3068) within ${\pm}$5% for singly-charged particles. The response linearity of the prototype Faraday cage could be extended up to flow rate of 30 L/min. For the performance evaluation of the aerosol charger the monodisperse liquid dioctyl sebacate (DOS) particles, with diameters of 0.1∼0.8$\mu\textrm{m}$, were generated using spraying from an atomizer followed by evaporation-condensation process. Typical performance parameters of the aerosol charger such as P$.$n, wall loss, and elementary charges per particle were evaluated. The performance of the prototype aerosol charger was found to be close to that of the aerosol charger used in an electrical low pressure impactor (ELPI, Dekati).

Unsteady spray characteristics of two-holes two-sprays type injectorin PFI gasoline engine (PFI용 2홀 2분무 인젝터의 비정상 분무 특성)

  • Kim, B.J.;Lee, J.H.;Cho, D.J.;Yoon, S.J.
    • Journal of ILASS-Korea
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    • v.10 no.1
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    • pp.43-52
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    • 2005
  • The effect of fuel injection spray on engine performance has been known as one of the major concerns for improving fuel economy and reducing emissions. In general, reducing the spray droplet size could prevent HC emission in gasoline engine. As far as PFI (Port Fuel Injection) gasoline engine is concerned, the mixture of air and fuel may not be uniform under a certain condition, because breakup and production of spray droplets are made in a short distance between the fuel injector and intake valve. This study, by constituting PFI gasoline spray system, was performed to study the transient spray characteristics and dynamic behavior of droplets from 2hole 2spray type injector used in DOHC gasoline engine. Mean droplet size and optical concentration in accordance with various conditions were measured by LDPA and CCD camera. Through this study, the variation of drop size and optical concentration could be used for understanding the behavior of unsteady spray was declared and the existing the small droplets between each pulse spray could be estimated caused to the development of wall film was conformed.

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Analysis of Impingement Lands to Help Diesel Combustion Chamber Using Spray Impaction (분무충돌을 이용하는 디젤연소실 설계를 위한 충돌면 분석)

  • Park, K.
    • Journal of ILASS-Korea
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    • v.1 no.2
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    • pp.24-32
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    • 1996
  • Most of the research of small engines to date focused on developing spark ignition engines occupied much parts. Recently the number of a small direct injection diesel engine applied in small cars has been increased and considered as a next generation power source for passenger cars because of its high efficiency. Therefore the combustion chamber becomes smaller and the fuel injection pressure goes higher, which makes fuel sprays impinged easily on the combustion chamber walls. When strong swirls are not induced, the fuel may not mix with air because of fuel deposition on the wall. As a positive way, the combustion chamber systems which is using spray wall impaction has been introduced and assessed by an experimental or a simulate manner. In these systems the raised lands are positioned in tile chamber for spray impaction in order to break up the fuel drops into much smaller and direct them into desirable direction. This study addresses to the effects of rho position and size of the raised land or glow plug to help the chamber design using spray wall impaction. The characteristics of the spray impinged on various lands are investigated and compared with each other. Then the chamber shapes are discussed with the characteristics and their proper position and size is proposed in any chamber volume.

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The Spray Behavior Analysis and Space Distribution of Mixture in Transient Jet Impinging on Piston Cavity (비정상 충돌 분류의 Cavity형상에 따른 공간 농도 분포 및 거동해석)

  • Lee, S.S.;Kim, K.M.;Kim, B.G.;Chang, S.S.;Ha, J.Y.
    • Journal of ILASS-Korea
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    • v.1 no.2
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    • pp.16-23
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    • 1996
  • In case of a high-speed D.I. diesel engine. the injected fuel spray is unavoidable that the impinging on the wall of piston cavity and in this case the geometry of piston cavity has a great influence on the atomization structure and air flow fields. In the field of combustion and in many other spray applications, there are clear evidence of correlation between spray structure and emission of pollutants. Ordinary, the combustion chamber of driving engine have unsteady turbulent flow be attendant on such as the change of temperature, velocity and pressure. So the analysis of spray behavior is difficult. In this study, a single spray was impinged on each cavity wall at indicated angle in a quiescent atmosphere at room temperature and pressure, as being the simplest case, and 3 types of piston cavity such as Dish, Toroidal and Re-entrant type was tested for analyzing the influence of cavity geometry. And hot wire probe was used for analyze non-steady flow characteristics of impinging spray, and to investigate the behavior of spray, the aspects of concentration c(t), standard deviation $\sigma(t)$ and variation factor (v.f.) was measured with the lapse of time.

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Optimum Design of an Automotive A/C Duct using by CFD (CFD를 이용한 승용차 에어컨 덕트의 최적설계)

  • Kim, T.H.;Jeong, S.J.
    • Journal of ILASS-Korea
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    • v.1 no.3
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    • pp.37-50
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    • 1996
  • Computational fluid dynamics was used to optimize an A/C duct. Three dimensional flow analysis in an automotive A/C duct was performed computationally using various turbulence models and compared numerical predictions such as outlet flow split, surface pressure distribution along the duct to experimental data. Additionally, we studied the effect of location variation of 2nd branch on exit flow ratio and could find optimal location of 2nd branch. The design of an A/C duct was modeled and calculated to enhance the airflow distribution in each outlet using the STAR-CD computational fluid dynamics software. In results, modified $k-\varepsilon$ turbulence model allows a successful prediction of static pressure distribution particulary at around strong curvature but little improvement flow split. In the future, adoption of CFD to design an A/C duct with modified $k-\varepsilon$ model will bring benefits of producing more accurate prediction, and also give designers more detail information much more than now.

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A Numerical Study on the Spray Dryer Characteristic for Manufacture of Deep Sea Water Salt (해양심층수 기능성소금 제조를 위한 분무건조기 특성의 수치해석적 연구)

  • Kim, Hyeon-Ju;Shin, Phil-Kwon;Park, Seong-Je
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2003.10a
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    • pp.24-29
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    • 2003
  • Deep sea water has cold temperature, abundant nutrients and minerals, and good water quality that is pathogen-free and stable. Compared with surface water, deep sea water contains more nutrition salt, such as nitrogen and phosphor. Moreover, if has the good balance of minerals. Because of the ability of the spray drying process to produce a free-flowing power considering of spherical particles with a well-defined size distribution and the rapid drying times for heat-sensitive material, spray drying is attractive for a wide range of applications spray drying is a unique unit operation in which powders are produced from a liquid feed in a single processing step. Key component of the process are atomizer, spray chamber. Design of spray chamber should be based on the atomizer type, the production rate, and the particle size required. Because of the complex processes taking place during spray drying, traditional design method are based on pilot-plant tests and empirical scale-up rules. Modern technique such as CFD have a role to play in design and troubleshooting.

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