• 제목/요약/키워드: Liquid air

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Surface Composition and Molecular Diffusion on the Stability of Foams Formed from Protein/Surfactant Mixtures (단백질/계면활성제 혼합계에서 기포안정성에 대한 계면조성과 분자확산)

  • Park, Sun-Yeong;Kim, Myung-Soo;Jeong, Noh-Hee;Nam, Ki-Dae
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.3
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    • pp.158-166
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    • 2000
  • A conductimetric study of foam formed from mixture of the protein, ${\beta}-lactoglobulin$, and the nonioinc surfactant, SML, revealed that their stability was reduced at concentrations of SML in the range $3{\sim}10mM$. The interaction of SML with ${\beta}-lactoglobulin$ was investigated by fluorimetry and a dissociation constant of $0.2{\mu}M$ was calculated for the complex. Surface tension studies confirmed the presence of interaction between the two components and provided evidence for the progressive displacement of ${\beta}-lactogloblin$ from the air/water interface with increasing SML concentration. Experiments using air-suspended microscopic thin liquid films revealed transitions in the chainage characteristics and thickness of the film at SML concentrations below that which resulted in destabilization of the foam. However, measurements of surface mobility of fluorescent-labeled ${\beta}-lactoglobulin$ by a photobleaching method identified that a transition to a mobile system occurred at a SML concentration which correlated with the onset of instability in the disperse phase. The results would indicate that maintenance of the viscoelastic properties of the surface is paramount importance in determining the stability of interfaces comprising mixtures of protein and surfactant.

A Study on the Change of Condensable Particulate Matter by the SO2 Concentration among Combustion Gases (연소 배출가스 중 SO2 농도에 따른 응축성먼지 변화에 관한 연구)

  • Yu, JeongHun;Lim, SeulGi;Song, Jihan;Lee, DoYoung;Yu, MyeongSang;Kim, JongHo
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.5
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    • pp.651-658
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    • 2018
  • Particulate matter (PM) emitted from fossil fuel-combustion facilities can be classified as either filterable or condensable PM. The U.S. Environmental Protection Agency (EPA) defined condensable PM as material that is in the phase of vapor at the stack temperature of the sampling location which condenses, reacts upon cooling and dilution in the ambient air to form solid or liquid in a few second after the discharge from the stack. Condensable PM passed through the filter media and it is typically ignored. But condensable PM was defined as a component of primary PM. This study investigates the change of condensable PM according to the variation in the sulfur dioxide of combustion gas. Domestic oil boilers were used as the source of emission ($SO_2$) and the level of $SO_2$ concentration (0, 50, 80, and 120 ppm) was adjusted by diluting general light oil and marine gas oil (MGO) that contains sulfur less than 0.5%. Condensable PM was measured as 2.72, 6.10, 8.38, and $13.34mg/m^3$ when $SO_2$ concentration in combustion gas were 0, 50, 80, and 120 ppm respectively. The condensable PM tended to increase as the concentration of $SO_2$ increased. Some of the gaseous air pollutants emitted from the stack should be considered precursors of condensable PM. The gas phase pollutants which converted into condensable PM should reduced for condensable PM control.

A Study of Ice-Formation Phenomena on Freezing of Flowing Water in a Stenotic Tube

  • Suh, Jeong-Se;Kim, Moo-Geun;Ro, Sung-Tack;Yim, Chang-Soon
    • International Journal of Air-Conditioning and Refrigeration
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    • v.7
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    • pp.1-10
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    • 1999
  • In this study, a numerical analysis is made on the ice-formation for laminar water flow inside a stenotic tube. The study takes into account the interaction between the laminar flow and the stenotic port in the circular tube. The purpose of the present numerical investigation is to assess the effect of a stenotic shape on the instantaneous shape of the flow passage during freezing upstream/downstream of the stenotic channel. In the solution strategy, the present study is substantially distinguished from the existing works in that the complete set of governing equations in both the solid and liquid regions are resolved. In a channel flow between parallel plates, the agreement between the of predictions and the available experimental data is very good. Numerical analyses are performed for parametric variations of the position and heights of stenotic shape and flow rate. The results show that the stenotic shape has the great effect on the thickness of the solidification layer inside the tube. As the height of a stenosis grows and the length of a stenosis decreases, the ice layer thickness near the stenotic port is thinner, due to backward flow caused by the sudden expansion of a water tunnel. It is found that the flow passage has a slight uniform taper up to the stenotic channel, at which a sudden expansion is observed. It is also shown that the ice layer becomes more fat in accordance with its Reynolds number.

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Application of Analytical Instrument Method for Determining Level of Malodorous Sulfur Compounds. (악취성분중 황화합물에 대한 기기분석법의 적용)

  • 유병태;최종욱;조기찬;이충언;김건흥
    • Journal of environmental and Sanitary engineering
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    • v.14 no.4
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    • pp.117-123
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    • 1999
  • The analytical instrument method was applied to analyze malodorous sulfur compounds emitted from industrial fields. Six factories and two sites which release malodorous substances into ambient air were selected to determine the level of hydrogen sulfide($H_2S$), methylmercaptan(MeSH), dimethyl sulfide($Me_2S$), and dimethyl disulfide($Me_2S_2$) using automated thermal desorption system (STD400) and GC-FPD in summer and fall seasons of 1999. The Air sampler for ATD400 uses a small pump to draw sample and a mass flow controller to adjust sample amount without using a dilution apparatus. The trap temperature of ATD400 reached to $-80^{\circ}$ by supplying liquid nitrogen and $H_2S$ can be analyzed under this condition. The recovery rates of $H_2S$, MeSH, $Me_2S$, and $Me_2S_2$ of odorous sulfur compounds standard were shown 98.2%, 93.6%, 98.2%, 99.4% respectively. The concentrations of $Me_2S$ at outside boundary of G market, L factory, and J factory were 0.018ppm, 0.021ppm, 0.032ppm in summer, respectively. The concentration of $H_2S$ at Nanjido landfill was 1.167ppm in summer, but that of $H_2S$ was not detected in fall because of soil covering. The concentration of H2S and $Me_2S_2$ at inside of Chonggye stream were 0.564ppm and 1.045ppm in summer, while those of H2S and Me2S2 were 0.285ppm and 0.465ppm in fall, respectively.

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Treatment Characteristics and Application of DAF Process for Effective Solid Separation in BNR Municipal Wastewater Treatment System (BNR 하수처리시스템에서 효과적 고형물 분리를 위한 DAF 공정의 적용과 처리특성)

  • Kwak, Dong-Heui;Rhu, Dae-Hwan
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.3
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    • pp.267-276
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    • 2010
  • Many plants have been improved to adapt the target of the biological treatment processes changed from organics to nutrients since the water quality criteria of effluent was reinforced and included T-N and T-P for the municipal wastewater treatment plant. To meet the criteria of T-N and T-P, the conventional biological reactor such as aeration tank in activated sludge system is changed to the BNR (biological nutrient removal) processes, which are typically divided into three units as anaerobic, anoxic and oxic tank. Therefore, the solid separation process should be redesigned to fit the BNR processes in case of the application of the DAF (dissolved air flotation) process as an alternatives because the solid-liquid separation characteristics of microbial flocs produced in the BNR processes are also different from that of activated sludge system as well. The results of this study revealed that the microbial floc of the anaerobic tank was the hardest to be separated among the three steps of the unit tanks for the BNR processes. On the contrary, the oxic tank was best for the removal efficiency of nutrients as well as suspended solid. In addition, the removal efficiency of nutrients was much improved under the chemical coagulation treatment though coagulation was not indispensable with a respect to the solid separation. On the other hand, in spited that the separation time for the microbial floc from the BNR processes were similar to the typical particles like clay flocs, over $2.32{\times}10^3$ ppm of air volume concentration was required to keep back the break-up of the bubble-floc agglomerates.

A study on Behavior of Turbulent Transient Jets with Butane and Propane (Butane 및 propane의 비정상 난류 제트 특성에 관한 연구)

  • Lee, Beom-Ho;Song, Hak-Hyun;Cho, Seung-Hwan;Hong, Sung-Tae;Lee, Dae-Yup;Lee, Tae-Woo
    • Journal of ILASS-Korea
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    • v.15 no.2
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    • pp.74-82
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    • 2010
  • In order to understand the behavior of transient gaseous injection used in an LPG (Liquefied Petroleum Gas) engine, turbulent incompressible transient jets with butane and propane were measured and analyzed at pressures of 1.5 bar and 2.0 bar with injector diameters of 3 mm and 5 mm. Mie-scattering method with a tracer was used, and images were processed to investigate the behavior of butane and propane jets. Distances from the nozzle to transition region were measured as $L_e/d_{inj}$=4.35~19.4, where $L_e$ and $d_{inj}$ indicate respectively a distance from nozzle to transition point and nozzle diameter. Slits and tubes around jet at near-field were introduced to measure the effect of entrainment and the diameter of jet, which revealed that the entrainment of surrounding air is significant for developing jet diameter. When the entrainment is restricted, the behavior of jet became deviating from the baseline. It was found that the virtual origin located outside of a nozzle towards jet tip within the conditions of this work, and its location was estimated as $x_o/d_{inj}$=0.56~7.25, where $x_o$ is a distance from nozzle to virtual origin.

Correlations of Oil Concentration Prediction during In-line Flow of $CO_2/Oil$ Mixtures (유동중인 $CO_2$냉매와 오일 혼합물의 농도 예측을 위한 상관식)

  • Park, Keun-Seo;Kang, Byung-Ha;Park, Kyoung-Kuhn;Kim, Suk-Hyun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.19 no.10
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    • pp.718-725
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    • 2007
  • In the general vapor-compression refrigeration system, refrigeration lubricant circulates in refrigeration system with refrigerant. Knowledge of the amount of circulating lubricant is very important to exactly calculate capacity of the refrigeration system. An experimental study was conducted to estimate the oil concentration of a flowing $CO_2/Oil$ mixtures. POE and PAG oil are considered as test lubricants in this study. Performance tests were conducted under simulated liquid conditions for $CO_2/POE$ oil mixture in oil concentration of 0 to 10 weight-percent and $CO_2/PAG$ oil mixture in oil concentration of 0 to 6 weight-percent in the temperature ranges of $-5^{\circ}C\;to\;15^{\circ}C$. The results obtained indicate specific gravity of $CO_2/Oil$ mixture is increased as oil concentration is increased and as temperature of mixture is decreased. Oil concentration correlation of $CO_2/POE$ oil mixture and $CO_2/PAG$ oil mixture is suggested, based on the measurement of specific gravity and temperature. This correlation enable to predict the oil concentration without extraction of the mixture and can be applied for $CO_2/POE$ mixtures and $CO_2/PAG$ mixtures.

UO2 Kernel Particle Preparation for HTGR Nuclear Fuel (고온가스로용 핵연료 UO2 Kernel 입자제조)

  • Jeong, Kyung-Chai;Kim, Yeon-Ku;Oh, Seung-Chul;Cho, Moon-Sung
    • Journal of the Korean Ceramic Society
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    • v.44 no.8
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    • pp.437-444
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    • 2007
  • The broth solution was prepared by the mixing of an uranyl nitrate, THFA, PVA, and water. The uranium concentration of the broth solution was $0.5{\sim}0.8$ mole-U/L and the viscosity of it was $30{\sim}80cSt$. The droplets of this broth solution were farmed in air and ammonia by the vibrating nozzle with the frequency of 100 Hz at the amplitude of $100{\sim}130V$. The diameter of the droplet was about $1900{\mu}m$ from using the nozzle diameter of 1 mm. The diameter of the aged gel was about $1400{\mu}m$ after aging in ammonia solution at $60{\sim}80^{\circ}C$, and the dried gel with the diameter of about $900{\mu}m$ was obtained after drying at room temperature or partially vacuum condition. The diameter of the calcined $UO_3$ microsphere after calcination at $600^{\circ}C$ appeared about $800{\mu}m$ in air atmosphere. Although the droplets of the same sizes were formed, the calcined microspheres of different sizes were manufactured in the case of the broth solutions of the different uranium concentration. The droplets of the desired diameters were obtained by the change of the nozzle diameters and the broth flow rates.

A Prediction Model for TVOC and HCHO Emission of Paint Materials (페인트에서 방출되는 TVOC 및 HCHO 방출량 예측모델)

  • Kim, Hyung-Soo;Lee, Kyung-Hoi
    • KIEAE Journal
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    • v.3 no.1
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    • pp.13-20
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    • 2003
  • It is highly recognized that there is need for protection against indoor air pollution, as we realize environmental pollution is growing, For example, in an indoor environment, a person spends more than 80 percent of their time inside the building. Thus, concern about indoor decoration materials is growing, since they cause pollution in the rooms of an apartment, as well as in offices. As the indoor decoration materials become more diverse and lusurious, so the effect of VOCs(Volatile Organic Compounds) and HCHO(Formaldehy) is growing. The indoor decoration materials cause the Sick Building Syndrome, such as headaches, dizziness, or lack of concentraion, and they in turn cause serious deterioration in people's health. In this study, I probed the status of the indoor air pollution and carried on an investigation and analysis about the prevention technique. In doing so, I performed experimental tests and an assessment of the indoor decoration materials of an apartment. I also examined elements of the emitted and the emission. Finally, I examined the character of emissions, by changing environmental conditions, such as the temperature, humidity, and ventilation. With respect to VOCs tests, I applied the method of solid state adsorption using the adsorptive tube, based on the measurement of the American EPA TO-17, ASTM 5116-97, and the measurement of the Japanese Wall Decoration Industrial Association. The tested sample was analyzed by High Performance Liquid Chromatography, after going through the process of dissolvent extraction. As subjects of the test, Paint were selected. The process of this test is as follows; first, I figured out the character of the emission, by measuring the emitted concentration of VOCs and HOHC from the indoor decoration materials of an apartment. Second, I made a small-scale chamber and the test was processed in the chamber in order to suggest an environment-friendly prediction modlel development.

Characterization of Forest Fire Emissions and Their Possible Toxicological Impacts on Human Health

  • Kibet, Joshua;Bosire, Josephate;Kinyanjui, Thomas;Lang'at, Moses;Rono, Nicholas
    • Journal of Forest and Environmental Science
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    • v.33 no.2
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    • pp.113-121
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    • 2017
  • In flight particulate matter particularly emissions generated by incomplete combustion processes has become a subject of global concern due to the health problems and environmental impacts associated with them. This has compelled most countries to set standards for coarse and fine particles due to their conspicuous impacts on environment and public health. This contribution therefore explores forest fire emissions and how its particulates affects air quality, damage to vegetation, water bodies and biological functions as architects for lung diseases and other degenerative illnesses such as oxidative stress and aging. Soot was collected from simulated forest fire using a clean glass surface and carefully transferred into amber vials for analysis. Volatile components of soot were collected over 10 mL dichloromethane and analyzed using a QTOF Premier-Water Corp Liquid Chromatography hyphenated to a mass selective detector (MSD), and Gas Chromatograph coupled to a mass spectrometer (GC-MS). To characterize the size and surface morphology of soot, a scanning electron microscope (SEM) was used. The characterization of molecular volatiles from simulated forest fire emissions revealed long chain compounds including octadec-9-enoic acid, octadec-6-enoic acid, cyclotetracosane, cyclotetradecane, and a few aromatic hydrocarbons (benzene and naphthalene). Special classes of organics (dibenzo-p-dioxin and 2H-benzopyran) were also detected as minor products. Dibenzo-p-dioxin for instance in chlorinated form is one of the deadliest environmental organic toxins. The average particulate size of emissions using SEM was found to be $11.51{\pm}4.91{\mu}m$. This study has shown that most of the emissions from simulated forest fire fall within $PM_{10}$ particulate size. The molecular by-products of forest fire and particulate emissions may be toxic to both human and natural ecosystems, and are possible precursors for various respiratory ailments and cancers. The burning of a forest by natural disasters or man-made fires results in the destruction of natural habitats and serious air pollution.