• Title/Summary/Keyword: Liquid Resin

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A Study on Ion Exchange Characteristics with Composition and Concentration of Electrolyte, Ratio of Ion Exchange Resin (전해질 성분 및 농도, 이온교환 수지 비율에 따른 이온교환 특성 연구)

  • Ahn Hyun-Kyoung;Rhee In-Hyoung;Yoon Hyoung-Jun;Jeong Hyun-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.4
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    • pp.727-732
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    • 2006
  • The object of this study was to investigate the influence of composition and concentration of electrolyte, ratio of cation to anion exchange resin of mixed ion exchange column in the performance of ion exchange. Also this work examined the removal capability of suspended solids by ion exchange resin and the effect of particule on the characteristics of ion exchange. Breakthrough time was extended as the amount of ions and particles present in liquid was decreased. The case of anion, the breakthrough sequence is $Cl^{-}, but the case of cation, the breakthrough sequence is $Na^{+}. As for the ratio of cation to anion exchange resin of 1:2, the breakthrough time was prolonged compared with that of 1:1 and 1:3. For the electrolyte of equal concentration containing suspended solid, breakthrough time was contracted less than 20%. It results in the increase in the removal capacity of cation exchange resin. For the higher ratio of cation exchange resin, suspended solids are shorten the cation's breakthrough time so that the runtime of ion exchange resin tower is increased.

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Sequential separation of 90Sr, 241Am, 239,240Pu and 238Pu by radioanalytical techniques (방사능 분석기술을 이용한 90Sr, 239,240Pu, 238Pu, 241Am 축차분리)

  • Lee, Myung Ho;Park, Kyoung Kyun;Kim, Jong-Yun;Park, Yeong Jae;Kim, Won Ho
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.469-474
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    • 2005
  • This paper presents a quantitative method of sequential separation of $^{90}Sr$, $^{241}Am$ and Pu radionuclides with an anion exchange resin and a Sr-Spec resin. The Pu isotopes were purified with an anion exchange resin. The americium and strontium fractions were separated from the matrix elements with an oxalate co-precipitation method. Americium fraction was separated from the strontium fraction with iron co-precipitation method and purified from lanthanides with anion exchange resin. Strontium-90 was purified from other hindrance elements with the Sr-Spec resin after oxalate co-precipitation. The measurement of Pu and Am isotopes was carried out by an ${\alpha}$-spectrometer. Strontium-90 was measured by a liquid scintillation counter. The radiochemical procedure of $^{90}Sr$, $^{241}Am$ and Pu radionuclides investigated in this study has been validated by application to IAEA-Reference soils.

Moisture Absorption Properties of Organic-Inorganic Nano Composites According to the Change of Epoxy Resins for Next Generation Semiconductor Packaging Materials (차세대 반도체용 유-무기 나노 복합재료의 에폭시 수지변화에 따른 흡습특성)

  • Kim, Whan Gun;Kim, Dong Min
    • Journal of the Semiconductor & Display Technology
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    • v.12 no.1
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    • pp.23-28
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    • 2013
  • Epoxy resins are widely used in microelectronics packaging such as printed circuit board and encapsulating for semiconductor manufacturing. Water can diffuse into and through the epoxy matrix systems and moisture absorption at boarding interfaces of matrix resin systems can lead to a hydrolysis at the interfaces resulting in delamination of encapsulating materials. In the study, the changes of diffusion coefficient and moisture content ratio of epoxy resin systems with nano-sized fillers according to the change of liquid type epoxy resins were investigated. RE-304S, RE-310S, RE-810NM and HP-4032D as a epoxy resin, Kayahard AA as a hardener, and 1B2MI as a catalyst were used in these epoxy resin systems. After curing, moisture content ratios were measured with time under the 85 and 85% relative humidity condition using a thermo-hydrostat. The maximum moisture absorption ratio and diffusion coefficient of EMC decrease with the filler content. It can be seen that these decreases are due to the increase of filler surface area and the decrease of moisture through channel with the content of nano-sized filler.

A Study on Structures and Properties of Liquid Crystal-UV Curable Resin Composite Materials (액정-UV경화 이크릴레이트 수지 복합재료의 구조와 물성에 관한 연구)

  • 김종원
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.59-69
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    • 2000
  • The characteristics of liquid crystal polymer composite(LCPC) films are possessed of large-area and flexible display, polarizer free, high contrast, wide angle of visual filed and high responsiveness. It is well known that the LCPC films consisting of a continuous LC phase embeded in a three-dimentional network of polymer matrix are formed by photopolymerization-induced phase separation. In this study, we have investigated the point that both liquid crystals and polymer having different properties have to coexiste as composed films. The purpose of this study has been the development of new application with liquid crystals and UV-curable monomers. In the results abtained on the miscibility of nematic liquid crystal and UV-curable resins, difunctional monomer HX-620 turned out to shows the best. From the results abtained on structures, electro-optical properties and dynamic visocoelasticity for LCPC films, the best mixing ratio of monomer to LC mixture were 3/7(photoinitiator; 4wt%) by weight, and this ratio has been provided the most thermal stability for LCPC films. In the results abtained on structure and discoloration properties of LCPC films, it has been demonstrated that consiste of a 8:2 mixture of chiral nematic liquid crystal and HX-620 has the greatest domain and it was the best discoloration.

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Performance Evaluation of C/SiC Composites (C/SiC 복합재료의 내열성능 평가)

  • Kim, Yun-Chul
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.185-188
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    • 2007
  • The main objective of this research effort was to develope the performance of C/SiC composites manufactured by LSI (Liquid Silicon Infiltration) method for solid and liquid rocket propulsion system and ensure the performance analysis technique. The various carbon preform were manufactured by filament winding, tape rolling, involute layup and stack molding process. For the best performance of thermal and mechanical properties, many process conditions were tested and selected by varying preform, the content of SiC, temperature, impregnation resin and chemical vapour reaction. In conclusion, the high performance and reliability of C/SiC composite were proved for solid and liquid rocket propulsion system. And the performance analysis technique related to mathematical ablation model was originated.

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Micro-morphological Features of Liquid Urea-Formaldehyde Resins during Curing Process at Different Levels of Hardener and Curing Time Assessed by Transmission Electron Microscopy

  • Nuryawan, Arif;Park, Byung-Dae
    • Current Research on Agriculture and Life Sciences
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    • v.32 no.3
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    • pp.125-130
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    • 2014
  • This study used transmission electron microscopy (TEM) to investigate the micro-morphological features of two formaldehyde to urea (F/U) mole ratio liquid urea-formaldehyde (UF) resins with three hardener levels as a function of the curing time. The micro-morphological features of the liquid UF resins were characterized after different curing times. As a result, the TEM examination revealed the presence of globular/nodular structures in both liquid UF resins, while spherical particles were only visible in the low F/U mole ratio resins. The high F/U mole ratio liquid UF resins also showed extensive particle coalescence after adding the hardener, along with the appearance of complex filamentous networks. When the resins were cured with a higher amount of hardener and longer curing time, the spherical particles disappeared. For the low mole UF resins, the particles tended to coalesce with a higher amount of hardener and longer curing time, although discrete spherical particles were still observed in some regions. This is the first report on the distinct features of the crystal structures in low F/U mole ratio UF resins cured with 5% hardener and after 0.5 h of curing time. In conclusion, the present results indicate that the crystal structures of low F/U mole ratio UF resins are formed during the curing process.

Prediction of Viscosity in Liquid Epoxy Resin Mixed with Micro/Nano Hybrid Silica (액상 에폭시 수지와 마이크로/나노 하이브리드 실리카 혼합물의 점도 예측)

  • Huang, Guang-Chun;Lee, Chung-Hee;Lee, Jong-Keun
    • Korean Journal of Materials Research
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    • v.21 no.2
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    • pp.100-105
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    • 2011
  • The relative viscosity was measured at different filler loadings for a cycloaliphatic epoxy resin and hexahydro-4-methylphthalic anhydride hardener system filled with micro/nano hybrid silica. Various empirical models were fitted to the experimental data and a fitting parameter such as critical filler fractions (${\phi}_{max}$) was estimated. Among the models, the Zhang-Evans model gave the best fit to the viscosity data. For all the silica loadings used, ln (relative viscosity) varied linearly with filler loadings. Using the Zhang-Evans model and the linearity characteristics of the viscosity change, simple methods to predict the relative viscosity below ${\phi}_{max}$ are presented in this work. The predicted viscosity values from the two methods at hybrid silica fractions of $\phi$ = 0.086 and 0.1506 were confirmed for a micro:nano = 1:1 hybrid filler. As a result, the difference between measured and predicted values was less than 11%, indicating that the proposed predicting methods are in good agreement with the experiment.

Green Adhesives Using Tannin and Cashew Nut Shell Liquid for Environment-friendly Furniture Materials

  • Lee, Jeong-Hun;Jeon, Ji-Soo;Kim, Su-Min
    • Journal of the Korea Furniture Society
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    • v.22 no.3
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    • pp.219-229
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    • 2011
  • Sick building syndrome symptoms that are experienced by building occupants may be caused by toxic substances such as formaldehyde and VOCs, which are known to be emitted from building materials and wood composite products such as wood-based panel, furniture, engineered flooring and construction adhesive. In Korea, the use of wood composite products for indoor environments has increased over the last decade. Recently, wood composite products have been installed in approximately 95% of newly constructed residential buildings. The use of these products has resulted in problems related to human health, and consequently a realization about the importance of indoor air quality. In addition, consumer demand is increasing for natural materials because conventional building materials and wood composite products are made by adding urea-formaldehyde resin or they contain formaldehyde-based resin. More recently, many efforts have been made to reduce formaldehyde emission from building materials that laid in the indoor environment. Especially, if conventional formaldehyde-based adhesives are replaced with green adhesives for residential spaces, it is possible to reduce most of the emission amounts of formaldehyde in indoor environments. In line with this expectation, many researches are being conducted using natural materials such as tannin and cashew nut shell liquid (CNSL). This study discussed the affects and possibilities of green adhesives to reduce formaldehyde emission in indoor environments.

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BOND STRENGTH BETWEEN COBALT-CHROMIUM ALLOY AND DENTURE BASE RESIN ACCORDING TO ADHESIVE PRIMERS (금속표면처리제에 따른 코발트-크롬 합금과 의치상용 레진의 결합강도)

  • Park, Jong-Il;Kwon, Ju-Hong;Lee, Hae-Hyeung;Cho, Hay-Won
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.2
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    • pp.160-168
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    • 2000
  • This study evaluated the effects of four adhesive metal primers on the shear bond strength of a heat curing denture base resin(Lucitone 199) to cobalt-chromium alloy(Biosil-f). The adhesive metal primers were Cesead Opaque Primer, Metal Primer, MR Bond, and Super-Bond liquid. The metal surface primed or nonprimed was filled with the heat-curing methyl methacrylate resin. The specimens were stored in water at $37^{\circ}C$ for 24 hours and the alternately immersed in water bath at $5^{\circ}C\;and\;55^{\circ}C$ for up to 2,000 thermal cycles. Shear bond strengths were measured using UTM at a crosshead speed of 0.5mm/min. Failure surface were examined under magnifying glasses. All the primers examined improved the shear bond strength between denture base resin and cobalt-chromium alloy compared with nonprimed specimens before thermal cycling. The bond strength of Cesead Opaque Primer was greatest. And after 2,000 thermal cycles, the bond strengths between resin and cobalt-chromium alloy were decreased but the difference between thermal cycling 0 and 2,000 at Cesead Opaque primer and Metal Primer were not significant. This study indicated that Cesead Opaque Primer & Metal Primer is effective primers to obtain higher bond strength between heat cured denture base resin and cobalt-chromium alloy.

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A Study on the Purification Process of Methyl Fructoside by Liquid Chromatography (액체 크로마토그래피에 의한 메틸프룩토시드의 분리공정 연구)

  • 허주형;유인상김해성
    • KSBB Journal
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    • v.11 no.5
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    • pp.529-535
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    • 1996
  • Methyl frucloside was purified from the aqueous sugar/methyl fructoside solution by liquid chromatography using Amberlite IRA-900, strong anion-exchange resin. The optimum operating conditions, resolution and productivity of methyl fructoside were discussed to evaluate the practical feasibility of the proposed chromatographic separation process of methyl fructoside which is useful as a new starting material for sugar ester synthesis. The linear chromatography model with HETP was well applied to the chromatographic separation process of methyl fructoside and the theoretical solution successfully predicted the elution chromatogram of methyl fructoside and sucrose at different superficial linear velocity of eluent for rectangular feed with different loading volume of packed bed. The optimum operating conditions were found to be 75% with the loading volume of packed bed at 1.13 cm/min of the superficial linear velocity at $60^{\circ}C$, and gave the productivity of methyl fructoside of 7 mg/g-resin/h with the resolution of 1.1.

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